内蒙古西乌旗地区大石寨组火山岩时代及地球化学特征

西乌旗地区大石寨组火山岩以流纹岩为主,LA-ICP-MS锆石U-Pb同位素测定结果及全岩主量、微量和稀土元素分析结果表明,本区流纹岩的年龄为280.3Ma±1.4Ma,形成于早二叠世;大石寨组火山岩属高钾过铝质钙碱性火山岩,其中SiO2、K2O、Al2O3含量均较高。稀土元素配分曲线总体向右缓倾斜,轻稀土元素相对于重稀土元素富集,Eu呈明显的负异常,重稀土元素亏损不明显。Rb、Th、U、K等大离子亲石元素富集明显,Ba表现为弱亏损,高场强元素具有明显的Ta、Sr、P及Ti亏损,Zr、Hf相对富集。研究认为,该地区流纹岩可能是由玄武岩、安山岩等中基性火山岩分离结晶作用形成的,且形成的构造环境为大陆边缘弧。     

吐哈盆地大南湖地区层间氧化带特征及铀找矿前景

利用前人钻孔资料并结合野外调查,研究了找矿目的层西山窑组沉积环境、岩相古地理特征、砂体厚度及空间展布;对比各岩层的后生氧化程度,确定了层间氧化带的分布范围和空间展布形态。通过对目的层砂岩岩石学和岩石化学特征的研究,初步查明了本区砂岩孔隙度、密度与其结构构造密切相关,以及氧化带中次生矿物变化和化学元素如Fe、CO2、C有、S、U、Th、Se、Mo、V等含量变化与地下水的氧化作用有关,符合水成铀矿床的变化规律。在此基础上,圈定出氧化砂体,其底板埋深小于300m、厚度达50-100m、氧化带前锋长达60km。并在氧化带前锋发现铀矿化、硒矿化多处,初步显示该区具有良好的找矿前景。     

赣东北婺源-德兴地区新元古代浅变质火山岩的地球化学和锆石U-Pb年龄

赣东北婺源-德兴地区新元古代地层中浅变质火山岩主要由变质玄武岩、英安岩和流纹岩组成.全岩地球化学分析表明浅变质玄武岩具有拉斑玄武岩的地球化学特征,起源于尖晶石辉橄岩低度部分熔融,英安岩岩浆起源于壳源杂砂岩部分熔融,流纹岩可能为英安质岩浆结晶分异的产物.LA-ICP-MS锆石U-Pb同位素定年揭示婺源浅变质英安岩形成于861±8Ma,德兴张村西浅变质流纹岩形成于860±3Ma,铜厂铜矿矿区凝灰质板岩形成于860±6Ma,均为早新元古代Tonian期.同时这些定年样品中保存了2.8 ～2.5Ga、2.0～1.7Ga和～1.0Ga的继承或捕获锆石记录.结合浅变质玄武岩和英安质火山岩的地球化学特征和成因,这套岩石最有可能形成于新元古代早期安第斯型活动大陆边缘弧后盆地构造背景.     

藏东喜马拉雅期A型花岗岩岩石化学特征

藏东喜马拉雅期Ａ型花岗岩主要分布于玉龙斑岩铜（钼） 矿带西侧。众多碱钙性小斑岩体构成一个走向ＮＮＷ的花岗岩带。主要岩性有碱长石英正长岩、石英正长岩和碱长正长岩。岩浆主要来源于上地幔。侵位时代为喜马拉雅期（ＫＡｒ 年龄值为３６～４５ Ｍａ） ,侵位时的构造环境为造山后板内走滑变形环境。     

湖南铜山岭花岗岩体的地球化学特征及锆石SHRIMP定年

铜山岭花岗岩具有贫硅、富铁镁钙、弱到中等铕负异常和K2O/Na2O(1的特点,属高钾钙碱性岩石;花岗岩的ISr值(0.71060~0.71124)和εSr(t)值(77.6~81.0)相对较小,δ18O值(8.62‰~9.67‰)较低;TDM年龄(1226~1536Ma)偏小,εNd(t)值(-7.1~-5.2)相对较高;花岗岩中发育壳幔混合的镁铁质微粒包体。这些特征表明该岩体具有壳幔混合花岗岩的性质。岩体SHRIMP锆石U-Pb年龄为149±4Ma,属于燕山中期晚阶段构造岩浆活动的产物。     

赣南—粤北白垩纪火山杂岩岩石学及岩石化学特征

赣南－粤北白垩纪火山杂岩以合水组和优胜组为代表,其中合水组为一套夹玄武岩的沉积岩的组合岩,优胜组为一套酸性火山岩的组合岩。本文在讨论白垩纪火山杂岩岩石学和石化学特征的基础上,对火山杂岩的构造环境成因机制作了分析。     

Geochemical constraints on the tectonic setting of basaltic host rocks to the Windy Craggy Cu-Co-Au massive sulphide deposit,northwestern British Columbia

Windy Craggy is an approximately 300 Mt Cu-Co-Au volcanogenic massive sulphide (VMS) deposit in northwestern British Columbia, Canada. The Windy Craggy deposit is hosted by the Middle Tats Volcanics (MTV), a Late Triassic volcano-sedimentary sequence of intercalated mafic pillowed to massive volcanic flows and sills and calcareous argillite that are part of the Alexander terrane. The host footwall and hangingwall flows and sills are predominantly alkalic basalts (Nb/Y > 0.70). MTV alkali basalts at Windy Craggy are enriched in light rare earth elements (LREEs) >100X chondrite compared to chondrite, have steep REE patterns [(La/Yb)_cn = 7.1–25.4], and generally lack the Ta and Nb depletions relative to primitive mantle (e.g. [Nb/Th]_pm = 0.68–1.94) characteristic of arc environments, although most have [Nb/La]_pm < 1. By contrast, volcanic rocks away from the deposit (and regionally; Lower Tats Volcanics, LTV) as well as late dikes that cross-cut all lithologies including metamorphic and deformational fabrics are sub-alkalic tholeiitic to calc-alkaline basalts and basaltic andesites that are less enriched in the LREEs (10–100X chondrite), have less steep REE patterns [(La/Yb)_cn = 0.41–10.6], and show well-developed Ta and Nb depletions (arc signatures; [Nb/Th]_pm = 0.20–0.79), consistent with formation in an oceanic arc environment. The co-occurrence of tholeiitic/calc-alkaline arc rocks with alkalic rocks indicates that the LTV (former) and MTV (latter) formed from melts that were influenced to varying degrees by subducted oceanic crust, and likely formed within a back-arc basin setting formed on a rifted oceanic arc. There is no geochemical or isotopic evidence for major involvement of continental crust. The LTV basalts likely were produced by progressive depletion in the source by partial melting of mantle overlying the subducting oceanic crust. The presence of the MTV alkalic Windy Craggy rocks overlying the LTV is consistent with the presence of a slab-window, perhaps related to subduction of a spreading centre, which allowed more enriched magmas to reach the surface with only minimal interaction with subduction-modified mantle. The presence of this slab-window might have provided the mechanism for the generation of anomalously high heat flow close to the seafloor, which initiated and sustained vigorous, long-lived hydrothermal activity necessary for the precipitation of large accumulations of massive sulphide. To our knowledge, this is the first example of a large VMS deposit associated with a slab-window.     

大别山金鸡寨花岗岩体岩石化学特征及侵位机制初步探讨

】大别山金鸡寨花岗岩体位于大别山碰撞造山带东端,紧邻郯庐断裂,是由碱长石英正长岩和碱长花岗岩组成。这两种岩石的组成矿物均为碱性长石、石英、斜长石、角闪石、黑云母、磁铁矿及副矿物榍石、磷灰石,但矿物含量不同。它们的岩石化学特征也不相同：（１）碱长石英正长岩中常量元素的平均含量（ｗｔ％）ＳｉＯ２为６７．１１％,Ａｌ２Ｏ３为１７％,Ｎａ２Ｏ＋Ｋ２Ｏ为１０．９７％,其中Ｋ２Ｏ＞Ｎａ２Ｏ,微量、稀土元素均较富集,但高场强元素、轻稀土含量及ＬＲＥＥ／ＨＲＥＥ均大于碱长花岗岩中的相应数值。（２）碱长花岗岩中常量元素的平均含量（ｗｔ％）ＳｉＯ２为７５．１３％,Ａｌ２Ｏ３为１３％,Ｎａ２Ｏ＋Ｋ２Ｏ为８．２３％,其中Ｋ２Ｏ＞Ｎａ２Ｏ,微量、稀土元素含量较高,但大离子亲石元素、重稀土元素含量则大于碱长石英正长岩中的含量。根据野外调查、岩石学特征及常量、微量、稀土元素研究表明,这两种岩石是同一岩浆不同演化阶段的产物,是于造山后形成的Ａ型花岗岩,其形成经历了部分熔融和结晶分异两个阶段,源岩可能来自于北大别变质杂岩。金鸡寨岩体的侵位是以“半汽球”膨胀机制进行的,并与龙井关断裂密切相关。     

福建永定大坪花岗斑岩体的铌钽富集特征研究

福建大坪花岗斑岩体位于永定县城南部的大石凹—蓝地火山喷发盆地,具斑状结构,基质呈霏细结构、细-微粒结构。文章运用电子探针(EMPA)和激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS)等技术,对大坪岩体ZK10001钻孔中不同深度的岩石样品进行了矿物和岩石化学分析。分析结果表明,大坪岩体岩性为黑鳞云母碱长花岗斑岩,属于过铝质钙碱性花岗岩,具有较高的分异演化程度,Nb2O5和Ta2O5含量达到了花岗岩型稀有金属矿床的工业品位。铌钽矿物主要与黄玉、萤石的集合体呈稀疏浸染状、星点状产于基质间隙内,其次以星点状存在于石英和长石斑晶中。矿石矿物赋存特征与宜春钽铌矿床类似,可能具有一定的可选性和经济价值。大坪岩体的铌钽富集特征不同于斑岩型铜、钼矿床,与花岗岩型铌钽矿床也存在较大的差别,铌钽的富集过程经历了深部斑晶阶段和浅部基质阶段两阶段岩浆结晶分异作用,F等挥发分促进了铌钽在结晶残余岩浆中富集,在基质间隙间沉淀。大坪矿化岩体的发现暗示斑岩型铌钽矿床存在的可能性。     

安徽月山岩体岩石地球化学特征及成因

月山矿田是长江中、下游地区典型的夕卡岩-热液脉型铁、铜、金多金属矿田。月山岩体与金属矿床成因密切相关。通过对月山岩体系统的岩石学、岩石化学和微量元素地球化学特征研究,认为月山岩体是在区域拉张环境下,由亏损地幔低程度部分熔融形成的硅酸不饱和高钾碱性玄武岩浆经AFC机制形成的。