论地穹区“三位一体”金的构造成矿及其有序性

本文以笔者所提出的构造矿源层(前寒武系变质岩区)+燕山期岩体(岩浆岩或火山岩)+断裂交汇部位(构造扩容空间)的金银-多金属构造成矿的模式(或谓“三位一体”构造成矿模式),对中国主要金矿的构造成矿、成矿控矿系列(构造成矿区、构造成矿带、构造成矿田、矿床和矿体的成矿定位)作了进一步的论述。指出了具有前寒武系变质岩的地穹区及其边缘断裂带为金的构造成矿富集区,并指出了金矿构造成矿的有序性规律及找矿远景区。     

中条山同善天窗铜矿类型及找矿新认识

在总结同善构造—剥蚀窗内成矿地质条件的前提下 ,运用成矿系列理论 ,把区内具有多种表现形式的变基性火山岩型、变砂岩型、大理岩型三大类铜矿分成了八种亚类 ,认为诸类铜矿与区内广泛发育的新太古代基性岩存在着成生联系 ,铜矿的形成经历了一个复杂的过程。早期的海底火山喷发带来的铁、铜、硫等成矿物质 ,经过最初的海水富集、火山活动末期的热液作用富集以及后来区域变质叠加富集进而形成了这一系列矿床。同时提出了新的找矿思路、找矿方法及找矿靶区。     

华北陆块北缘西段中元古代与裂谷作用有关的铁、稀土、多金属矿床特征及成因

华北陆块北缘西段狼山—白云鄂博裂谷系中元古代形成的大型多金属矿床 ,是我国重要的铁、稀土、铜、铅、锌矿产地。矿床为产于沉积岩中热水沉积型多金属矿床。其形成受地层、构造控制 ,与裂谷作用有着密切的关系。裂谷系内外分支的地质环境及矿床矿种不同 ,导致矿床特征及成因具有一定差异。白云鄂博铁、稀土矿床为钾、钠、磷等含量较高的热水沉积型 ,霍各乞铜、铅、锌多金属矿床为与中基性火山岩有关的过渡热水沉积型 ,东升庙和甲生盘等铅、锌多金属矿床为热水沉积型。文中将对上述矿床分别进行论述。     

长江中下游成矿带陆内斑岩型矿床的成岩成矿作用

陆内环境斑岩型矿床的发现对斑岩成矿理论的完善具有重要意义。长江中下游成矿带作为中国东部重要的陆内成矿带之一,成矿带内发育多个重要的斑岩型矿床,如铜山口Cu-Mo矿床、鸡冠嘴Cu-Au矿床、白云山Cu矿、城门山Cu-Mo矿床、武山Cu-Mo矿床、丰山洞Cu-Au矿床、丁家山Cu矿、洋鸡山Au矿、沙溪Cu-Au矿床、冬瓜山Cu-Au矿床、舒家店Cu矿床和安基山Cu矿床等。本文选取成矿带内典型的、具有代表性的斑岩型矿床,对其地质特征(地层、构造、含矿斑岩、脉体特征和围岩蚀变)、成岩成矿年代、成矿岩体的岩石化学和成岩成矿地球化学等方面的研究资料和成果进行了系统总结,讨论和试图阐明长江中下游成矿带陆内斑岩型矿床的成岩成矿作用与成矿模式。研究显示,长江中下游成矿带形成于燕山期陆内造山过程,成矿斑岩岩浆活动和成矿作用主要发生于149~105Ma之间,进一步可以分为早、中、晚三阶段:149~135Ma、133~125Ma和123~105Ma,三阶段岩浆活动和成矿作用主要发生于成矿带中的断隆区,早阶段(149~135Ma)和晚阶段(123~105Ma)多为斑岩-矽卡岩型矿化,中阶段(133~125Ma)矿化为典型的斑岩型矿化。长江中下游成矿带内斑岩型矿床的含矿斑岩为高钾钙碱性-钙碱性系列岩石,大部分具有埃达克岩的地球化学特征,可能为源自富集地幔的岩浆和加厚下地壳部分熔融的岩浆混合的产物,源自富集地幔的基性岩浆对成矿具有至关重要的作用,它的混入使得混合岩浆富水、硫和金属(Cu、Au)等。进一步通过与岩浆弧环境的斑岩型矿床对比研究发现,长江中下游成矿带斑岩型矿床一般不发育高级泥化岩帽(advanced argillic liithocaps)以及浅部的高-中硫矿化蚀变系统,含矿岩浆源区性质和成矿物质来源等与岩浆弧环境的斑岩型矿床明显不同。     

Geochronology of Gold Deposits and Its Implication for Metallogenesis in the Fengxian-Lixian Area, Qinling Orogenic Belt, China

Abstract: A series of super large‐scale and large‐scale Pb and Zn, and Au deposits are distributed in the Qinling orogenic belt, China. Gold deposits were generally ascribed to Carlin‐type originated from circular meteoric water. Visible and coarse‐grained gold (up to over 3mm in grain size) was recently identified in some gold deposits in the Fengxian‐Lixian area, Qinling. Au‐bearing quartz lodes related to magmatism were discovered in the Xiaogouli gold deposit. Two types of Au‐bearing quartz veins, i.e., NW‐trending quartz veins and NE‐trending quartz veins cutting strata are widely present in the Baguamiao gold deposit. Both are spatially associated with each other. The former is generally snake–like, S‐shape or zigzag, which was resulted from plastic deformation by ductile shearing, being generally cut by the latter. The latter is generally linear with widely developed bleaching alteration zones in its adjacent wall rocks, which symbolizes the superimposition of brittle deformation and filling and metasomatism of magmatic hydrothermal solution in ductile shear zones after uplifting of the shear zones near the surface. The NW‐trending quartz veins contain Au of lower than 3ppm. The NE‐trending quartz veins contain Au of more than 3 ppm, so that NE‐trending quartz veins and the adjoining altered rocks are important ores. The NW‐trending Au–bearing quartz vein was dated as 210.61.26 to 232.581.59 Ma by ⁴⁰Ar–³⁹Ar method, i.e., late Indosinian epoch (Triassic). The NE‐trending Au–bearing quartz vein was dated as 131.910.89 to 197.451.13 Ma by ⁴⁰Ar–³⁹Ar method, i.e., Yanshanian epoch (Jurassic). The ⁴⁰Ar–³⁹Ar age of the NW‐trending Au–bearing quartz veins represents the age of the ductile shear formation. The isotope data of the NE‐trending quartz veins indicate that gold mineralization was closely related to Indosinian and Yanshanian granite intrusives not only in time and space, but also in origin.     

狼山-渣尔泰山成矿带铁铜铅锌多金属硫化物矿床特征研究

狼山-渣尔泰山多金属成矿带位于华北地台北缘西段的中元古代被动陆缘裂陷槽内,其产出的多处大型-超大型铜、铅、锌、铁多金属硫化物矿床的矿床特征具相似性和可对比性。通过分析该成矿带的区域地质背景、含矿建造特征及其产出的典型矿床（东升庙、炭窑口、霍各乞、甲生盘）的矿床地质特征,得出该成矿带内铜铅锌铁多金属硫化物矿床的以下特征：①盆地控矿特征十分明显;②成矿过程中伴有与成矿作用关系密切的同生断裂活动和同沉积期火山活动;③成矿元素具分带性和规律性组合的特征;④各典型矿床具鲜明的“时控”、“层控”和“岩控”特点;⑤成矿作用具有间歇性和多期演化成矿的特征;⑥含矿建造具有典型地球化学剖面结构序列特征;⑦矿体的产状与含矿岩系一致,且相应类型的矿石对应相应的容矿岩性。     

大兴安岭北部主要金属矿床成矿系列和区域矿床成矿谱系

文章以大兴安岭北部内生金属矿床、海相火山岩型硫铁矿矿床和砂金矿床为研究对象,按照矿床成矿系列的学术思想将其划分为7个矿床成矿系列,即:多宝山地区与加里东期中酸性火山_侵入活动有关的铜、钼矿床成矿系列,呼玛地区与华力西期辉长岩和花岗岩有关的铁、钛、金矿床成矿系列,伊尔施_黑河地区与华力西期花岗岩和海相火山岩有关的铁、铜、锌、硫铁矿矿床成矿系列,牙克石地区与华力西期海相中基性火山岩有关的铁、锌、硫铁矿矿床成矿系列,得尔布干地区与印支期_燕山期中酸性火山_侵入活动有关的铅、锌、银、铜、钼、金矿床成矿系列,伊尔施_呼玛地区与燕山期中酸性火山_侵入活动有关的金、铁、锌、铜、钼、钨矿床成矿系列和黑龙江流域与第四纪冲积沉积作用有关的砂金矿床成矿系列。大兴安岭北部区域矿床成矿谱系表明,从奥陶纪到新生代该区不同构造单元经历了7个主要的构造演化及成矿时期,依次出现奥陶纪岛弧环境的斑岩型矿床、泥盆纪陆块边缘拉张环境的岩浆型和热液脉型矿床、泥盆纪—石炭纪俯冲_碰撞环境的海相火山岩型和矽卡岩型矿床、石炭纪弧后盆地环境的海相火山岩型矿床、晚三叠世—早白垩世俯冲_碰撞_后碰撞环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床、早侏罗世—早白垩世俯冲环境的斑岩型、热液脉型、浅成低温热液型和矽卡岩型矿床和新生代地壳差异运动带砂金矿床。大兴安岭北部优势矿种为铜、钼、金、银、铅、锌,主攻矿床类型为斑岩型、热液脉型、低硫化浅成低温热液型、冲积型和海相火山岩型。     

湘中金、锑矿床区域控矿特征研究

湘中是湖南省重要的金、锑矿产地之一。断裂构造及岩浆热事件分析结果表明：该区断裂构造及岩浆热事件对金、锑矿的分布起着重要的控制作用。断裂构造体系分维值大的地区,金、锑矿产出较多,矿床规模也较大。岩体之岩凸或岩凹等热力集中场所,是金矿产出的有利部位;锑矿床皆分布于高古地温区。区域地层岩石中微量元素分析结果显示,前泥盆系浅变质碎屑岩是主要的矿源层。     

云南会泽HZT 型铅锌矿床蚀变白云岩特征及岩石-地球化学找矿标志

蚀变白云岩是会泽超大型铅锌矿床的赋矿围岩。通过矿区调研和近矿围岩典型剖面精细测量,矿区蚀变中-粗晶白云岩从颜色上可分为4种类型:肉红中粗晶白云岩、米黄色针孔状粗晶白云岩、灰白孔洞状粗晶白云岩、纯白色粗晶白云岩;前三者与矿体产出关系密切,从远矿到近矿依次为:肉红中粗晶白云岩→米黄色针孔状粗晶白云岩→灰白孔洞状粗晶白云岩→铅锌矿石;总结了3个带主要矿物组合、组构特征,认为3个带在白云石重结晶程度、显微构造、黄铁矿、晶洞充填物及裂隙等具明显差异,据此可作为辨识赋矿白云岩的重要标志。同时,对比了摆佐组白云岩(矿化粗晶白云岩、粗晶白云岩、白云石化灰岩)主量元素变化特征,分析了近矿蚀变白云岩主量元素及其比值与矿体距离的相关性,以及CaO与其他主量元素相关性,确定了热液蚀变参数有SiO2、MgO/CaO、K2O/CaO、Al2O3/TFe等,为找矿预测提供理论依据。     

Genesis of the Kamioka Skarn Deposits: An Important Role of Clinopyroxene Skarn and Graphite-bearing Limestone in Precipitating Sulfide Ore

Abstract: A genetical relationship between skarn formation and mineralization is investigated for the Kamioka skarn deposits which are the largest Zn-Pb producer in Japan. In the Mozumi deposit, one of main deposits in the Kamioka mining area as well as Tochibora and Maruyama, clinopyroxene skarn was generally subjected to later replacement by garnet or magnetite–calcite–quartz during the Zn-Pb mineralization. The replacement of hedenbergitic clinopyroxene by andraditic garnet resulted in the formation of diopsidic clinopyroxene relicts. With the progress of replacement, the S/So value (So: an estimated area occupied by an original clinopyroxene grain in a thin section, S: a total area of relict clinopyroxene fragments) which is an index of the degree of replacement decreases from 0. 7 to 0. 1, and the hedenbergite mole percent of relict clinopyroxene decreases drastically from about 65 to less than 40. A close association of andraditic garnet and sphalerite suggests that heden-bergitic clinopyroxene skarn played an important role to reduce the relatively oxic ore-forming fluid enriched in Zn²⁺ and SO4^2– and to precipitate sphalerite from the fluid. Ferrous iron in the hedenbergitic clinopyroxene skarn was oxidized to form andraditic garnet. Besides this garnet formation, the mineral assemblage of magnetite–calcite–quartz replaced the clinopyroxene skarn at the time of mineralization. In both cases, the reduction of relatively oxic ore-forming fluid by hedenbergitic clinopy-roxene skarn at the later stage brought about the precipitation of sulfide minerals. In contrast, these types of later replacement are not found in the Tochibora deposit. Instead, graphite-bearing crystalline limestone and relatively fresh clinopyroxene skarn are common. Mineralized clinopyroxene skarn has high graphite carbon contents relative to barren one, suggesting that the amount of graphite in the skarn was an important controlling factor for mineralization. It is very likely that the graphite played a role of reducing agent during the mineralization in the Tochibora deposit.