大别山南山岭石榴橄榄岩成因的岩石学研究

大别山罗田穹隆东南侧的南山岭石榴橄榄岩岩体面积小(173×133m~2),由贵橄榄石(75%)。透辉石(10%)和镁铝石榴石(15%)组成。本文通过岩石学及地球化学研究,并与大别山的碧溪岭、毛屋、饶拔寨、芝麻坊岩体以及其他地区的基性岩浆杂岩体(如红格岩体、元宝山岩体、柴北缘岩体)、残留地幔块体(五大连池、鹤壁、山旺)等不同成因的超镁铁岩进行对比后认为,该岩体属于火成成因,是镁铁-超镁铁杂岩体的一部分。表现在:橄榄岩呈块状构造,矿物分布均匀未见定向排列,镜下呈现典型的火成结构;FeO~T含量高(21.36%),Mg~#(0.77)低,Mg Ni/Fe Mn(3.06)<7,V(175.5×10~(-6))含量高于地幔块体成因的橄榄岩;REE总量偏低,LREE弱富集,(La/Yb)_N=3.1,低于饶拔寨、芝麻坊等残留地幔块体成因的橄榄岩。南山岭橄榄岩在微量元素蛛网图中,具有Ba、U、Pb、Zr、Eu的正异常和Nb的负异常,石榴橄榄岩全岩以及透辉石单矿物都具有高~(87)Sr/86 Sr(0.7088,0.7086)和低ε_(Nd)(t)(-6.55～-6.01)的特征,尽管南山岭与碧溪岭岩体距离很近而且都属于火成成因,但岩石的结构构造、变质变形的印记、REE配分形式和同位素特征都有区别,表明二者的源区及演化经历不同,相比之下,南山岭岩浆源区地壳组分的作用更为明显。在ε_(Nd)(t)-(~(87)Sr/~(86)Sr)_t图解中南山岭橄榄岩的投点十分靠近大别山北麓120～130Ma侵位的祝家铺辉石岩-辉长岩岩体群的投点分布范围,暗示可能有与罗田穹窿西北侧祝家铺岩体群的岩浆活动相对应。     

橄榄岩中尖晶石的氧同位素继承性与晶体结构转变

根据激光探针分析含尖晶石橄榄石中矿物的氧同位素组成,反应增量法计算矿物对氧同位素分馏曲线,得到正尖晶石－矿物对氧同位素温度高于含尖晶石橄榄岩的相平衡温度,而用反尖晶石－矿物的对计算的氧同位素温度则很接近含尖晶石橄榄岩的相平衡温度,较为合理,因此地幔橄榄岩中镁铝尖晶石的氧同位素组成继承了其母体反尖晶石特征,即与橄榄石,单斜辉石和斜方辉石平衡的是反结构尖晶石,在其发生相变作用变成正结构尖晶石时未发生氧     

内蒙古集宁新生代玄武岩中橄榄岩包体矿物化学特征及其地幔演化意义

在无水"干"体系的四矿物相橄榄岩中,单斜辉石由于熔点低而通常记录着丰富的部分熔融作用和地幔交代作用信息。在详细岩相学特征和组成矿物主元素分析基础上,重点对内蒙古集宁玄武岩中橄榄岩包体的单斜辉石进行了激光原位微量元素研究。通过与新生代时华北具古老克拉通地幔特征(如鹤壁)和具新生岩石圈地幔特征(如山旺)的橄榄岩对比,讨论了新生代时集宁地区陆下岩石圈地幔性质及其形成和演化机制。集宁地区岩石圈地幔是相当于原始地幔经过较低程度的部分熔融抽取形成的,除个别样品的部分熔融程度5%外,多数样品为5%～10%。橄榄岩的平衡温度与橄榄石Mg#关系表明新生代时集宁地区的陆下岩石圈地幔是不均一的,无明显分层现象,表现为饱满与过渡型地幔的共存。这种主体饱满并兼有过渡型地幔的不均一现象,可能是软流圈物质对古老地幔进行不均匀侵蚀、改造和置换作用的结果。     

A conceptual hydrogeological model of ophiolitic aquifers (serpentinised peridotite): The test example of Mt. Prinzera (Northern Italy)

The main aim of this study is the experimental analysis of the hydrogeological behaviour of the Mt. Prinzera ultramafic massif in the northern Apennines, Italy. The analysed multidisciplinary database has been acquired through (a) geologic and structural survey; (b) geomorphologic survey; (c) hydrogeological monitoring; (d) physico‐chemical analyses; and (e) isotopic analyses. The ultramafic medium is made of several lithological units, tectonically overlapped. Between them, a low‐permeability, discontinuous unit has been identified. This unit behaves as an aquitard and causes a perched groundwater to temporary flow within the upper medium, close to the surface. This perched groundwater flows out along several structurally controlled depressions, and then several high‐altitude temporary springs can be observed during recharge, together with several perennial basal (i.e., low altitude) springs, caused by the compartmentalisation of the system because of high‐angle tectonic discontinuities.     

Clinopyroxene REE Geochemistry of the Red Hills Peridotite, New Zealand: Interpretation of Magmatic Processes in the Upper Mantle and in the Moho Transition Zone

The Red Hills peridotite in the Dun Mountain ophiolite of SouthIsland, New Zealand, is assumed to have been produced in a paleo-mid-oceanridge tectonic setting. The peridotite is composed mostly ofharzburgite and dunite, which represent residual mantle andthe Moho transition zone (MTZ), respectively. Dunite channelswithin harzburgite blocks of various scales represent the MTZcomponent. Plagioclase- and clinopyroxene-bearing dunites occursporadically within common dunites. These dunites representproducts of melt–wall-rock interaction. Chondrite-normalizedrare earth element (REE) patterns of MTZ clinopyroxenes showa wide compositional range. Clinopyroxenes in plagioclase dunitesare extremely depleted in light REE (LREE) ([Lu/La]_N >100),and are comparable with clinopyroxenes in abyssal peridotitesfrom normal mid-ocean ridges. Interstitial clinopyroxenes inthe common dunite have flatter patterns ([Lu/La]_N 2) comparablewith those for dunite in the Oman ophiolite. Clinopyroxenesin the lower part of the residual mantle harzburgites are evenmore strongly depleted in LREE ([Lu/La]_N = 100–1000) thanare mid-ocean ridge peridotites, and rival the most depletedabyssal clinopyroxenes reported from the Bouvet hotspot. Incontrast, those in the uppermost residual mantle harzburgiteand harzburgite blocks in the MTZ are less LREE depleted ([Lu/La]_N= 10–100), and are similar to those in plagioclase dunite.Clinopyroxenes in the clinopyroxene dunite in the MTZ are similarto those reported from mid-ocean ridge basalt (MORB) cumulates,and clinopyroxenes in the gabbroic rocks have compositions similarto those reported from MORB. Strong LREE and middle REE (MREE)depletion in clinopyroxenes in the harzburgite suggests thatthe harzburgites are residues of two-stage fractional melting,which operated initially in the garnet field, and subsequentlycontinued in the spinel lherzolite field. The early stage meltingproduced the depleted harzburgite. The later stage melting wasresponsible for the gabbroic rocks and dunite. Strongly LREE–MREE-depletedclinopyroxene in the lower harzburgite and HREE-enriched clinopyroxenein the upper harzburgite and plagioclase dunite were formedby later reactive melt migration occurring in the harzburgite. KEY WORDS: clinopyroxene REE geochemistry; Dun Mountain ophiolite; Moho transition zone; orogenic peridotite; Red Hills     

内蒙古北山地区芨芨台子-小黄山蛇绿岩构造属性及与成矿关系: 来自阿民乌素地幔橄榄岩印证

阿民乌素地幔橄榄岩属芨芨台子-小黄山蛇绿岩带一部分,该构造带南北两侧地质体无明显差异,不具分界断裂的构造特征。本文对阿民乌素地幔橄榄岩与月牙山地幔橄榄岩进行岩石化学、地球化学对比分析,为芨芨台子-小黄山蛇绿岩构造属性提供新依据,并对阿民乌素蛇绿岩成矿潜力进行分析研究。笔者所在团队在地幔橄榄岩上部的辉长岩中获得LA-ICP-MS锆石U-Pb同位素年龄值为462.5±3.2 Ma,属中奥陶世。其上发育奥陶纪-志留纪公婆泉组岛弧拉斑玄武岩。该期地幔橄榄岩轻重稀土之比LR/HR＝1.63~3.68, (La/Sm)N＝1.70~6.92,(Gd/Yb)N＝0.36~0.52,表明岩石轻稀土略富集,稀土配分曲线呈不规则“U”型,估算其为原始地幔橄榄岩经过10%~20%部分熔融的残留物。原始地幔标准化蛛网图富集高场强元素U、Zr、Hf、Yb和大离子亲石元素Rb、Sr,亏损高场强元素Nb、Ti和大离子亲石元素Ba。与月牙山地幔橄榄岩标准化蛛网图对比,最大区别在于阿民乌素地幔橄榄岩明显亏损高场强元素Ti。初步研究认为阿民乌素地幔橄榄岩属SSZ型、高压型蛇绿岩,是岛弧裂谷的产物。该橄榄岩具有形成大型铬铁矿的成矿构造背景,是寻找蛇绿岩型铬铁矿的有利部位。     

An Early Palaeozoic HP/HT granulite–garnet peridotite association in the south Altyn Tagh, NW China: P–T history and U-Pb geochronology

High‐pressure kyanite‐bearing felsic granulites in the Bashiwake area of the south Altyn Tagh (SAT) subduction–collision complex enclose mafic granulites and garnet peridotite‐hosted sapphirine‐bearing metabasites. The predominant felsic granulites are garnet + quartz + ternary feldspar (now perthite) rocks containing kyanite, plagioclase, biotite, rutile, spinel, corundum, and minor zircon and apatite. The quartz‐bearing mafic granulites contain a peak pressure assemblage of garnet + clinopyroxene + ternary feldspar (now mesoperthite) + quartz + rutile. The sapphirine‐bearing metabasites occur as mafic layers in garnet peridotite. Petrographical data suggest a peak assemblage of garnet + clinopyroxene + kyanite + rutile. Early kyanite is inferred from a symplectite of sapphirine + corundum + plagioclase ± spinel, interpreted to have formed during decompression. Garnet peridotite contains an assemblage of garnet + olivine + orthopyroxene + clinopyroxene. Thermobarometry indicates that all rock types experienced peak P–T conditions of 18.5–27.3 kbar and 870–1050 °C. A medium–high pressure granulite facies overprint (780–820 °C, 9.5–12 kbar) is defined by the formation of secondary clinopyroxene ± orthopyroxene + plagioclase at the expense of garnet and early clinopyroxene in the mafic granulites, as well as by growth of spinel and plagioclase at the expense of garnet and kyanite in the felsic granulite. SHRIMP II zircon U‐Pb geochronology yields ages of 493 ± 7 Ma (mean of 11) from the felsic granulite, 497 ± 11 Ma (mean of 11) from sapphirine‐bearing metabasite and 501 ± 16 Ma (mean of 10) from garnet peridotite. Rounded zircon morphology, cathodoluminescence (CL) sector zoning, and inclusions of peak metamorphic minerals indicate these ages reflect HP/HT metamorphism. Similar ages determined for eclogites from the western segment of the SAT suggest that the same continental subduction/collision event may be responsible for HP metamorphism in both areas.     

The Role of Lithospheric Mantle Heterogeneity in the Generation of Plio-Pleistocene Alkali Basaltic Suites from NW Harrat Ash Shaam (Israel)

Plio-Pleistocene volcanism in the Golan and Galilee (northeasternIsrael) shows systematic variability with time and location:alkali basalts were erupted in the south during the Early Pliocene,whereas enriched basanitic lavas erupted in the north duringthe Late Pliocene (Galilee) and Pleistocene (Golan). The basaltsshow positive correlations in plots of ratios of highly to moderatelyincompatible elements versus the concentration of the highlyincompatible element (e.g. Nb/Zr vs Nb, La/Sm vs La) and indiagrams of REE/HFSE (rare earth elements/high field strengthelements) vs REE concentration (e.g. La/Nb vs La). Some of thesecorrelations are not linear but upward convex. ⁸⁷Sr/⁸⁶Sr ratiosvary between 0·7031 and 0·7034 and correlate negativelywith incompatible element concentrations and positively withRb/Sr ratios. We interpret these observations as an indicationthat the main control on magma composition is binary mixingof melts derived from two end-member mantle source components.Based on the high Sr/Ba ratios and negative Rb anomalies inprimitive mantle normalized trace element diagrams and the moderateslopes of MREE–HREE (middle REE–heavy REE) in chondrite-normalizeddiagrams, we suggest that the source for the alkali basalticend-member was a garnet-bearing amphibole peridotite that hadexperienced partial dehydration. The very high incompatibleelement concentrations, low K content, very low Rb contentsand steep MREE–HREE patterns in the basanites are attributedto derivation from amphibole- and garnet-bearing pyroxeniteveins. It is suggested that the veins were produced via partialmelting of amphibole peridotites, followed by complete solidificationand dehydration that effectively removed Rb and K. The requirementfor the presence of amphibole limits both sources to lithosphericdepths. The spatial geochemical variability of the basalts indicatesthat the lithosphere beneath the region is heterogeneous, composedof vein-rich and vein-poor domains. The relatively uniform ¹⁴³Nd/¹⁴⁴Nd(Nd = 4·0–5·2) suggests that the two mantlesources were formed by dehydration and partial melting of anoriginally isotopically uniform reservoir, probably as a resultof a Paleozoic thermal event. KEY WORDS: basanites; lithospheric heterogeneity; magma mixing; amphibole peridotite; pyroxenites     

Formation and alteration of plagiogranites in an ultramafic-hosted detachment fault at the Mid-Atlantic Ridge (ODP Leg 209)

We examined small-scale shear zones in drillcore samples of abyssal peridotites from the Mid-Atlantic Ridge. These shear zones are associated with veins consisting of chlorite + actinolite/tremolite assemblages, with accessory phases zircon and apatite, and they are interpreted as altered plagiogranite melt impregnations, which originate from hydrous partial melting of gabbroic intrusion in an oceanic detachment fault. Ti-in-zircon thermometry yields temperatures around 820°C for the crystallization of the evolved melt. Reaction path modeling indicates that the alteration assemblage includes serpentine of the adjacent altered peridotites. Based on the model results, we propose that formation of chlorite occurred at higher temperatures than serpentinization, thus leading to strain localization around former plagiogranites during alteration. The detachment fault represents a major pathway for fluids through the oceanic crust, as evidenced by extremely low δ¹⁸O of altered plagiogranite veins (+3.0–4.2‰) and adjacent serpentinites (+ 2.6–3.7‰). The uniform oxygen isotope data indicate that fluid flow in the detachment fault system affected veins and adjacent host serpentinites likewise. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

东海地区高压-超高压变质带中变质橄榄岩及其原岩和成因类型的判别——以PP1孔和PP3孔为例

本文在总结全球地幔橄榄岩岩石学和地球化学特征的基础上,首次提出了一个用于判别HPUHP变质带中变质橄榄岩原岩及其成因类型的判别图解。该图主要由镁铁总量MgO+（%）和一个参数m+f/si比值构成。另用Al2O3和CaO分别与MgO+（%）制成两个辅助图解,以示方辉橄榄岩和二辉橄榄岩之间在Al2O3和CaO含量上的分界。通过原岩判别结果和研究表明,PP3孔和PP1孔两者在变质组合、原岩成因类型、地球化学和变质条件方面存在一系列的重大差异。分别代表来自两种极端的地球化学类型和两种不同大地构造环境的UHP变质体。PP3钻孔以Ol+Gt+Cpx+Opx+Sp为变质矿物共生组合的含石榴石纯橄岩,其原岩系来自地幔残余成因的方辉橄榄岩遭受UHP变质作用的产物,它以成分高度均一,富Mg（Mg’=92）,极端亏损不相容元素REE（∑REE<1×10-6可称为超亏损型）为特征。在变质相中仍保留原岩的残余矿物铬尖晶石（Sp）,其成分显示蛇绿岩地幔橄榄岩的成分趋势。并出现以Gt和Sp共存相为特征的变质相。据实验结果（klemme,2004）表明该共存相的稳定域的PT条件CrSp可达7Gpa,T1400℃,即形成于200km的地幔深度。综合研究显示该孔变质橄榄岩原岩（方辉橄榄岩）具有大洋岩石圈地幔残余成因的某些印记,而不是同深度原生地幔岩相转变的产物。PP1孔变质橄榄岩是由无水矿物相（Ol+Opx+Cpx+Gt）+含水矿物相（Phl±Chu）组成的石榴石橄榄岩杂岩,其原岩来自两种不同成因的超镁铁岩系列：一为具地幔成因的方辉橄榄岩二辉橄榄岩系列（可能相当于地幔楔中的Al型橄榄岩）,另一部分（少数）来自具岩浆成因的超镁铁岩系列（纯橄岩—异剥橄榄岩—辉石岩组合,可能相当于A2型橄榄岩）。该套变质橄榄岩,以成分高度不均一,极端富集REE（∑REE平均>20×10-6可称为超富集型）和大离子亲石元素（K、Ba、Rb）为特征。这种异常现象并不反映其原岩原有的地球化学特征,它可能是由于在俯冲过程中受到陆壳物质的污染,或壳幔相互作用所致。据该孔变质相中缺乏Sp相,而以Gt为标志的变质相的事实,推断其形成的压力条件应>7Gpa, 即形成的深度应大于200km。上述研究表明在苏鲁UHP变质带中,不仅有来自大陆地幔楔中的地幔残余的UHP变质体,而且首次提出有可能来自大陆俯冲前锋具大洋岩石圈地幔性质的（蛇绿岩型地幔残片）变质体存在,这对揭示该区UHP变质带的形成和演化过程提供了新的信息。