Alpine olivine- and titanian clinohumite-bearing assemblages in the Erro-Tobbio peridotite (Voltri Massif, NW Italy)

The microstructures in the Erro-Tobbio peridotite indicate several stages of recrystallization of olivine + titanian clinohumite-bearing assemblages. The development of these assemblages is closely associated with serpentinite mylonites, in which they occur in shear bands and foliations and are inferred to have grown synkinematically, in veins, and as post-kinematic radial aggregates. In the peridotite wall-rock adjacent to these mylonites, the same assemblages have recrystallized statically at the expense of original olivine and pyroxenes, mesh-textured chrysolite and antigorite veins. In addition, the olivine-bearing assemblage occurs in widespread vein systems. The brittle deformation of the peridotite resulting in the development of these vein systems is closely related to ductile deformation of metagabbroic dykes in the peridotite. Although early metasomatism resulted in extensive rodingitization of the gabbros, some dykes show an eclogitic assemblage of Na-clinopyroxene + garnet + chloritoid + chlorite ± talc. These observations, the microstructures and the mineral chemistry all suggest that the assemblages in the ultramafic rocks and metagabbros developed during a prograde evolution towards high pressures (>13–16 kbar, 450–550° C), and during subsequent decompression. This metamorphic evolution is considered to be related to Late Cretaceous intraoceanic subduction in the Alps-Apennine system and closure of the Piedmont-Ligurian basin.     

新疆西准噶尔地区两类蛇绿岩中橄榄岩的矿物学研究

两类蛇绿岩中变质橄榄岩的矿物表现出的共同特征是:从二辉橄榄岩→斜辉橄榄岩→斜辉辉橄岩→纯橄岩→铬铁矿石,其橄榄石、斜方辉石和单斜辉石的Mg/(Mg+Fe)(矿物牌号)依次升高,表现出富Mg贫Fe的演化趋势;铬尖晶石的Cr/(Cr+Al)亦同时升高,表现为富Cr贫Al的演化特征。 变质橄榄岩中的矿物均是原始上地幔岩部分熔融的残余物。在部分熔融过程中,橄榄石与铬尖晶石是生成相矿物,而斜方与单斜辉石则是消失相矿物,正是通过两种辉石的不断消失,岩石才从二辉橄榄岩依次转化为纯橄岩,并造成纯橄岩与铬铁矿的紧密伴生。在此过程中,矿物成分时刻都在变化,造岩矿物向富Mg贫Fe,金属矿物向富Cr贫Al方向调整,这与实际测定结果是一致的。     

金在地幔矿物中的赋存形式及其赋存介质转化的可能模式:以中国北方一些地幔橄榄岩包体为例

采集中国北方玄武岩中橄榄岩包体样品21件。测定了其中的主元素、微量元素、稀土元素(REE)和Au等的含量。橄榄岩包体中的Au含量与CaO含量的相关性表明,其中的Au可能主要赋存于单斜辉石中,反映Au含量可能与地幔演化及熔融程度有关;橄榄岩包体后期受地幔流体交代作用的影响,Au转而以硫化物形式存在,这一过程是在橄榄岩包体原有Au的物质基础上进行的。     

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).     

The longevity of subcontinental lithospheric mantle beneath Jiangsu-Anhui Region

The basalt-borne peridotite xenoliths from Jiangsu-Anhui provinces were analyzed for whole rock Os isotopic compositions in two laboratories of USTC, China and CRPG, France, respectively. The¹⁸⁷Os/¹⁸⁸Os ratio of the sample set ranges from 0.119 to 0.129 (25 samples, USTC) and from 0.117 to 0.131 (17 samples, CRPG). The Os isotopic compositions of most samples are less than 0.129 and depleted relatively to the primitive mantle, showing a good correlation with the major element compositions. With the¹⁸⁷Os/¹⁸⁸Os-Al₂O₃ alumichron, the samples yield a model age of 2.5 ± 0.1 Ga (data of USTC) and 1.9 ± 0.1 Ga (data of CRPG), late Archean to early Pro-terozoic. The two samples with the lowest¹⁸⁷Os/¹⁸⁸Os ratio (0.119 and 0.117) have the T_RD (Re depleted age) of 1.1 Ga (USTC) and 1.4 Ga (CRPG), mid-Proterozoic. The Os isotope model age shows that the peridotite xenoliths from Cenozoic alkali basalt in Jiangsu-Anhui provinces have an old formation age (early- to mid- Proterozoic). They are not newly produced mantle after the Phanerozoic replacement of the lithosphere mantle, but residual fractions of Proterozoic mantle.     

Petrochemical Investigation of the Antique Ophiolite (Philippines): Implications on Volcanogenic Massive Sulfide and Podiform Chromitite Deposits

Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog f_O2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites.     

Mantle process beneath Philippine Sea back-arc spreading ridges: A synthesis of peridotite petrology and tectonics

Abstract In order to obtain a general view of the mantle process beneath a back‐arc basin spreading ridge, the diversity of peridotite petrology and tectonic occurrences in two back‐arc basin spreading ridges from the Philippine Sea were examined: the Parece Vela Rift and the Mariana Trough. The Parece Vela Basin spreading ridge (Parece Vela Rift) was a physically fast/intermediate‐spreading ridge, although many tectono‐magmatic features resemble those of slow‐ to ultraslow‐spreading ridges. Two unusual features of the Parece Vela Rift further demonstrate the uniqueness of the ridge: full‐axial development of oceanic core complexes and exposure of mantle peridotite at segment midpoints. The Parece Vela Rift yields a lithological assemblage of residual but still fertile lherzolite/harzburgite, plagioclase‐bearing harzburgite and dunite; similar assemblages are reported from the equatorial Mid‐Atlantic Ridge at the Romanche Fracture Zone and the ultraslow‐spreading ridges from the Indian and Arctic Oceans. The tectono‐magmatic characteristics of the Parece Vela Rift suggest that diffuse porous melt flow and pervasive melt–mantle interaction were the important mantle processes there. Globally, this ‘porous melt flow‐type’ mantle process is likely to occur beneath a segment midpoint of the ridge having a thick lithosphere, typically an ultraslow‐spreading ridge. In contrast, the Mariana Trough is a typical slow‐spreading ridge, exposing mantle peridotite at segment ends. The Mariana Trough yields a lithological assemblage of residual harzburgite and veined harzburgite, a common assemblage among the global abyssal peridotite suite. The tectono‐magmatic characteristics of the Mariana Trough suggest that channeled melt/fluid flow and limited melt–mantle interaction are the important mantle processes there, because of the colder wall‐rock peridotite in the segment end. This ‘channeled melt flow‐type’ mantle process is likely to occur in the shallow lithospheric mantle at the segment ends of any spreading ridges.     

Petrography and Geochemistry of Peridotite Xenoliths from Hannuoba and Significance for Lithospheric Mantle Evolution

Mantle-derived xenoliths and xenocrysts in Pale-ozoic diamondiferous ki mberlites in Mengyin (Shan-dong Province) and Fuxian (Liaoning Province) showthe presence of a cold,thick lithospheric mantle be-neath the North China craton ( NCC) in the MiddleOrdovician ( Griffin et al ., 1998 ; Menzies et al .,1993 ;Fan and Menzies ,1992) . However ,studies onmantle peridotites captured in the Tertiary to Neo-gene basalts of the NCC have revealed the existenceof a thin, hot and fertile lithosph…     

Metasomatism and sulfide mobility in lithospheric mantle beneath eastern Australia: Implications for mantle Re–Os chronology

Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.

Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition.     

大陆科学钻探先导孔（CCSD—P1）橄榄岩地幔属性及动力学意义

早中生代的扬子大陆向华北大陆的深俯冲碰撞作用以及中、新生代的华北东部岩石圈减薄作用是国际大陆动力学问题研究的两个热点。然而，把它们有机联系起来，探讨深部岩石圈演化动力学过程的研究还很少。报道了中国大陆科学钻探先导孔（CCSD-PP1）橄榄岩的矿物岩石化学分析结果。这些橄榄岩亏损玄武质组分（如低w（CaO＋Al2O3）、高Mg^#等），并经历了中元古代来自软流圈的碳酸岩熔体的交代作用和早中生代的超高压再平衡过程。结合已发表的华北捕虏体橄榄岩资料，对这一橄榄岩的原始地幔属性进行了分析。发现CCSD-PP1橄榄岩与华北古老岩石圈地幔组成相似，是早中生代来自华北岩石圈的构造侵入体。早中生代华北岩石圈的伸展减薄与苏鲁超高压变质岩石的折返提供了早期软流圈物质上涌的构造体制。