地幔岩流体包裹体的稀土元素初步研究

地幔流体REE的研究有助于了解地幔区域化学不均一性、地幔的富集与亏损等地幔地球化学特征。当前对地幔流体的REE研究，主要是通过对比富CO2包裹体与贫CO2包裹体的地幔岩或地幔矿物的测试分析来间接获得信息。本尝试运用电感耦合等离子体质谱（ICP-MS）和热爆方法，直接测定了长白山地区的地幔捕虏体中流体-熔体包裹体REE含量。初步研究显示流体-熔体包裹体中富含REE，尤其LREE相对富集；REE组成曲线右倾，Eu弱正异常，与地幔岩的寄主玄武岩REE组成特征相似，反映源区地幔岩的交代特征。     

TWO TYPES OF XENOLITH—MANTLE XENOLITH AND CRUSTAL XENOLITH FOUND IN THE CENOZOIC VOLCANIC ROCKS FROM HOH XIL, NORTHERN TIBET PLATEAU

TWO TYPES OF XENOLITH—MANTLE XENOLITH AND CRUSTAL XENOLITH FOUND IN THE CENOZOIC VOLCANIC ROCKS FROM HOH XIL, NORTHERN TIBET PLATEAU1　YangJingsui,XuZhiqin ,BaiWenji,etal.CenozoicvolcanismontheQinghai Tibetplateauanditsgenesis[J].ContinentalGeodynamics ,1997(2 ) :1～ 11. 2　XuZhiqin ,JiangMei,etal.Mantlediapirandinwardintracontinentalsubduction :AdiscussiononthemechanismofupliftoftheQinghai TibetPlateau[A].MacfarlaneA ,Sorkabi,RB ,…     

Mantle Xenoliths from the Southeastern Slave Craton: Evidence for Chemical Zonation in a Thick, Cold Lithosphere

We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=600–1300°C and P= 25–80 kbar in a thick(at least 220–250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 91–93·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton     

扬子地台西缘新生代富碱斑岩中的深源包体及其意义

在扬子地台西缘的碱性正长斑岩中发现由镁铝榴石聚晶,榴辉岩,榴闪岩,麻粒岩等组成的下地壳包体。推测杨子地台下部存在麻粒岩—榴辉岩高级变质相系的基底地层,它们可能是比早元古代大红山群更老的基底地层,也可能是构造机制造成的高级相转变。广泛分布在杨子地台西缘的喜山期富碱斑岩的原始岩浆可能有统一的形成机制,岩浆源区在壳幔边界,深部壳幔物质混染。随着杨子板块向西俯冲,岩浆源区深度加大,其原始岩浆的碱质也随之增加,所以西部的斑岩更偏基富碱。斑岩体的分布西界已到达澜沧江附近,这也可能是扬子板块地壳消失的边界。     

吉林蛟河地幔橄榄岩捕虏体的Sr-Nd-Hf-Os同位素特征与岩石圈地幔时代

吉林省蛟河市境内大石河新生代玄武岩中含有丰富的地幔橄榄岩包体,详细的岩石学与矿物学研究显示,这些包体的主要岩石类型为尖晶石二辉橄榄岩-方辉橄榄岩,未发现石榴石橄榄岩.岩相学及地球化学资料显示它们都是经历过熔体抽取而形成的岩石圈地幔残留.矿物平衡温度计算发现,本区的这些地幔橄榄岩包体来自地下40～60km深度,且下部以二辉橄榄岩为主,而上部以贫单斜辉石的二辉橄榄岩和方辉橄榄岩为主,显示明显的岩石圈地幔分层现象.Sr-Nd-Hf同位素资料反映这些地幔包体均表现为亏损性质,而Re-Os同位素资料确定上述岩石圈地幔形成于中元古代,明显老于上覆地壳的新元古宙时代,反映壳幔年龄上的解耦.因此我们推测,该区曾经历过华北克拉通类似的早期岩石圈地幔的整体丢失事件,然后形成于其它地区的中元古宙岩石圈地幔在本区增生.     

地球深部包体与成矿关系——一个有意义的研究方向

结合在实际工作中的体会,提出和讨论了“地球深部包体与成矿关系”这一有意义的研究方向及其先导性科学问题。地球深部包体中镍、金、钼、钨等成矿元素的含量是不均一的,镍和金在地幔岩包体中含量最高,钼在玄武岩及镁铁质麻粒岩包体中最高,而钨在长英质麻粒岩和花岗岩类包体中含量最高。这些反映岩石圈和软流圈以及岩石圈的不同层次中镍、金、钼、钨等成矿元素的含量不均一,分别提供了地壳中镍、金、钼、钨矿床的初始物质来源。这一认识可能给镍、金、钼、钨等金属矿床和矿床集中区的战略预测提供一些新思路。     

Melt–peridotite interaction in the shallow lithospheric mantle of the North China Craton: evidence from melt inclusions in the quartz-bearing orthopyroxene-rich websterite from Hannuoba

To better understand the origin, migration, and evolution of melts in the lithospheric mantle and their roles on the destruction of the North China Craton (NCC), we conducted a petrological and geochemical study on a quartz-bearing orthopyroxene-rich websterite xenolith from Hannuoba, the NCC, and its hosted melt and fluid inclusions. Both clinopyroxene and orthopyroxene in the xenolith contain lots of primary and secondary inclusions. High-temperature microthermometry of melt inclusions combined with Raman spectroscopy analyses of coexisting fluid inclusions shows that the entrapment temperature of the densest inclusions was ~1215°C and the pressure ~11.47 kbar, corresponding to a depth of ~38 km, i.e. within the stability of the spinel lherzolite. Intermediate pressure inclusions probably reflect progressive fluid entrapment over a range of depths during ascent, whereas the low-pressure inclusions (P < 2 kbar) may represent decrepitated primary inclusions. In situ laser-ablation ICP-MS analyses of major and trace elements on individual melt inclusions show that the compositions of these silicate melt inclusions in clinopyroxene and orthopyroxene are rich in SiO₂, Al₂O₃, and alkalis but poor in TiO₂ and strongly enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), with negative anomalies of high-field strength elements (HFSEs). These characteristics suggest that the silica-rich melts could be derived from the partial melting of subducted oceanic slab. Therefore, this kind of quartz-bearing orthopyroxene-rich websterite may be produced by interaction between the slab-derived melts with the mantle peridotite. This study provides direct evidence for the origin, migration, and evolution of melts in the lithospheric mantle, which may play an important role in the destruction of the NCC.     

吉林汪清和龙岗新生代岩石圈地幔的含水性和元素地球化学特征

首次报道了来自东北地区岩石圈地幔水含量的数据。通过对吉林龙岗和汪清新生代玄武岩中的橄榄岩包体矿物进行电子探针(EMP)和激光熔蚀等离子体质谱(LA-ICPMS)的分析,得到了矿物的主量元素和微量元素的数据,结果显示这些橄榄岩是原始地幔经历了不同程度部分熔融的残余,大部分样品的熔融程度可能<10%。橄榄岩样品在后期还经历了地幔交代作用,大部分样品受到硅酸岩熔体的交代,少部分样品受到碳酸岩熔体的交代。显微傅里叶变换红外光谱(FTIR)的分析结果显示,橄榄岩样品中的单斜辉石、斜方辉石均含有以结构羟基形式存在的水,而橄榄石中没有明显的羟基吸收峰。龙岗样品中单斜辉石的水含量为(48~464)×10^-6(H₂O, 质量分数),斜方辉石水含量为(28~104)×10^-6;汪清样品中单斜辉石的水含量为(34~403)×10^-6,斜方辉石的水含量为(13~89)×10^-6;所有样品全岩水含量为(8~92)×10^-6。样品的水含量可以代表龙岗和汪清地区岩石圈地幔的水含量信息,并且水含量变化范围较大,造成这种变化的原因可能是由于地幔源区初始水含量的不均一,以及部分熔融和地幔交代作用叠加的结果。     

大兴安岭岩石圈地幔特征——哈拉哈河-绰尔河橄榄岩捕虏体的证据

大兴安岭哈拉哈河-绰尔河第四纪火山岩中含有尖晶石相和石榴石相橄榄岩捕虏体.本文报道的尖晶石相橄榄岩包括方辉橄榄岩和二辉橄榄岩两类,前者分布数量略高于后者.方辉橄榄岩多数具有较高的平衡温度(1072～1193℃),矿物化学成分变化大,含有高Mg橄榄石和高Cr#尖晶石,这些特征一致表明是古老岩石圈地幔残余的样品.而二辉橄榄岩显示相对均一的矿物化学成分和很宽的平衡温度变化范围(636～1178℃),代表了明显受到改造的岩石圈地幔,可能反映岩石圈地幔的不同深度和局部经历了软流圈与岩石圈相互作用.通过与华北克拉通的对比,发现地处兴蒙造山带的大兴安岭岩石圈地幔中仍保留有相当量的古老岩石圈地幔残余,区别于遭受强烈改造和破坏的华北克拉通东部地区的岩石圈地幔.     

青藏高原北羌塘新生代火山岩中的麻粒岩捕虏体

北羌塘枕头崖地区新生代火山岩主要岩石类型为安山岩和英安岩类。其中,安山岩在一定程度上显示了埃达克质火山岩的特征,如高Sr(>1000×10-6)、Sr/Y>50以及低Yb(<2×10-6),表明其应源于榴辉岩相的青藏高原加厚陆壳中下部(>45km深度)。而英安岩类富集LILE,如Rb、Ba、Th、U和K等,亏损HFSE,如Ti、Nb、Ta和Sr等,尤其是Sr显著亏损,表明其应源于斜长石稳定的麻粒岩相源区。该区新生代安山岩和英安岩中麻粒岩捕虏体可分为两种类型,即二辉石麻粒岩和单斜辉石麻粒岩。二辉石麻粒岩平衡温度为783~818℃,单斜辉石麻粒岩形成压力在0·845~0·858GPa之间,来源深度约为27·9~28·3km,表明它们是来自青藏高原加厚陆壳中部的岩石样品,代表了本区英安岩类火山岩的源区物质组成。