High-pressure partial melting of gabbro and its role in the Hawaiian magma source

We have conducted high-pressure experiments on a natural oceanic gabbro composition (Gb108). Our aim was to test recent proposals that Sr-enrichment in rare primitive melt inclusions from Mauna Loa, Hawaii, may have resulted from melting of garnet pyroxenite formed in the magma source regions by reaction of peridotite with siliceous, Sr-enriched partial melts of eclogite of gabbroic composition. Gb108 is a natural, Sr-enriched olivine gabbro, which has a strong positive Sr anomaly superimposed on an overall depleted incompatible trace element pattern, reflecting its origin as a plagioclase-rich cumulate. At high pressures it crystallises as a coesite eclogite assemblage, with the solidus between 1,300 and 1,350°C at 3.5 GPa and 1,450 and 1,500°C at 4.5 GPa. Clinopyroxenes contain 4–9% Ca-eskolaite component, which varies systematically with pressure and temperature. Garnets are almandine and grossular-rich. Low degree partial melts are highly siliceous in composition, resembling dacites. Coesite is eliminated between 50 and 100°C above the solidus. The whole-rock Sr-enrichment is primarily hosted by clinopyroxene. This phase dominates the mode (>75 wt%) at all investigated PT conditions, and is the major contributor to partial melts of this eclogite composition. Hence the partial melts have trace element patterns sub-parallel to those of clinopyroxene with ≈10× greater overall abundances and with strong positive Sr anomalies. Recent studies of primitive Hawaiian volcanics have suggested the incorporation into their source regions of eclogite, formerly gabbroic material recycled through the mantle at subduction zones. The models suggest that formerly gabbroic material, present as eclogite in the Hawaiian plume, partially melted earlier than surrounding peridotite (i.e. at higher pressure) because of the lower solidus temperature of eclogite compared with peridotite. This produced highly siliceous melts which reacted with surrounding peridotite producing hybrid pyroxene + garnet lithologies. The Sr-enriched nature of the formerly plagioclase-rich gabbro was present in the siliceous partial melts, as demonstrated by these experiments, and was transferred to the reactive pyroxenite. These in turn partially melted, producing Sr-enriched picritic liquids which mixed with normal picritic partial melts of peridotite before eruption. On rare occasions these mixed, relatively Sr-rich melts were trapped as melt inclusions in primitive olivine phenocrysts. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Partial melting in the Inzie Head gneisses: the role of water and a petrogenetic grid in KFMASH applicable to anatectic pelitic migmatites

A sequence of prograde isograds is recognized within the Dalradian Inzie Head gneisses where pelitic compositions have undergone variable degrees of partial melting via incongruent melting reactions consuming biotite. Three leucosome types are identified. At the lowest grades, granitic leucosomes containing porphyroblasts of cordierite (CRD‐melt) are abundant. At intermediate grades, CRD‐melt mingles with garnetiferous leucosomes (GT‐melt). At the highest grades, CRD‐melt coexists with orthopyroxene‐bearing leucosomes (OPX‐melt), while garnet is conspicuously absent. The prograde metamorphic field gradient is constrained to pressures of 2–3 kbar below the CRD‐melt isograd, and no greater than 4.5 kbar at the highest grade around Inzie Head. A petrogenetic grid, calculated using thermocalc , is presented for the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) system for the phases orthopyroxene, garnet, cordierite, biotite, sillimanite, H₂O and melt with quartz and K‐feldspar in excess. For the implied field gradient, the reaction sequence predicted by the grid is consistent with the successive prograde development of each leucosome type. Compatibility diagrams suggest that, as anatexis proceeded, bulk compositions may have been displaced towards higher MgO content by the removal of (relatively) ferroan granitic leucosome. An isobaric (P = 4 kbar) T–a_H2O diagram shows that premigmatization fluids must have been water‐rich (a_H2O > 0.85) and suggests that, following the formation of small volumes of CRD‐melt, the system became fluid‐absent and melting reactions buffered a_H2O to lower values as temperatures rose. GT‐ and OPX‐melt formed by fluid‐absent melting reactions, but a maximum of 7–11% CRD‐melt fraction can be generated under fluid‐absent conditions, much less than the large volumes observed in the field. There is strong evidence that the CRD‐melt leucosomes could not have been derived by buoyantly aided upwards migration from levels beneath the migmatites. Their formation therefore required a significant influx of H₂O‐rich fluid, but in a quantity insufficient to have exhausted the buffering capacity of the solid assemblage plus melt. Fluid : rock ratios cannot have exceeded 1 : 30. The fluid was channelled through a regionally extensive shear zone network following melt‐induced failure. Such an influx of fluid at such depths has obvious consequences for localized crustal magma production and possibly for cordierite‐bearing granitoids in general.     

中国东部新生代火山岩的地质特征及火山作用发育的某些共同规律

中国东部从黑龙江到海南岛的广大范围内新生代玄武岩广泛发育。根据构造关系笔者把本区划分为三个部分：北、中和南构造地块。新生代火山作用在时空上表现出明显的分带。从老到新，火山作用演化的特点是ＳｉＯ２饱和程度减少，碱金属和镁含量增加。从南构造地块到北构造地块出现的玄武岩各具特色。从东南沿海向西北方向，即从东南沿海断裂经长白山－郯庐断裂到大兴安岭－太行山断裂方向，是地壳厚度增加的方向，新生代火山活动的演化     

The Evolution of Alpine Ultramafic Rocks and Partial Melting of the Upper Mantle

Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase of the 100 Mg/(Mg+Fe~(2+) ratio of silicate minerals in order of lherzolite→harzburgite→dunite, i.e. the increase in magnesium; the other is the increase of the 100 Cr/(Cr+Al) ratio of accessory chrome spinel in the same order, i. e. the increase in Chromium. The above-mentioned evolutionary trends are contrary to that of magmatic differentiation. The evolution of fabrics of ultramafic rocks is characterized by progressive variation in order of protogranular texture→melted residual texture, symplectic texture and clastophyritic texture→equigranular mosaic texture and tabular mosaic texture. Experiments of partial melting of lherzolite have convincingly shown that the evolution of Alpine ultramafic rocks resulted from the partial melting of pyrolite. Various subtypes of them represent different degrees of partial melting. The vertical zoning marked by more basic rocks in the upper part and more acid rocks in the lower actually belongs to the fusion zoning of pyrolite.     

祁连山蛇绿岩型超镁铁岩铬铁矿床成矿的主要特征

祁连山造山带目前已发现不同规模的超镁铁岩体（群）1000余个,产有铬铁矿床（点）和矿化点80余处,这些岩体及其矿产主要产在北祁连优地斜增生地体边部的海沟带中,少数产在祁连中间地块的边部。岩体成因类型为蛇绿岩组合中的超镁铁质单元,铬铁矿的富集部位是地幔橄榄岩和堆积杂岩带底部的纯橄榄岩。岩石多为铝过饱和系列,岩体的平均化学成分接近于斜辉橄榄岩;Cr₂0₃的平均含量大于0.40％,Al₂0₃的平均含量近于或者大于1％。铬尖晶石的化学参数特征反映出低铁富镁的介质对形成富铬尖晶石是有利的。富铬岩体中Cr、Co、Ti、V的含量较高。     

Anhydrous and water-saturated melting experiments of an olivine andesite from Mt Yakushi-Yama, northeastern Shikoku, Japan

Abstract Melting experiments have been carried out on an olivine andesite of Mt Yakushi-Yama from the Miocene Setouchi volcanic belt in northeastern Shikoku, Japan. This andesite has been characterized by a low ratio of FeO*/Mg° (= 0.78). Phase relations have been determined within the pressure range of 2.8 to 19.3 kbar at 1000-1300°C under anhydrous and water-saturated conditions. At pressures less than 8.8 kbar, olivine is a liquidus phase. Orthopyroxene appears on the liquidus at 9.3 kbar under the anhydrous conditions. The multiple saturation point rises up to 17.5 kbar for water-saturated experiments. The andesite melt coexists with olivine and orthopyroxene just below the liquidus at 8.8–9.3 kbar and 1230°C for dry conditions, and at 17.5 kbar and 1060°C under water-saturated conditions. These experimental results indicate that the Yakushi-Yama olivine andesite magma could coexist with a harzburgitic mantle at depths between about 30 and 60 km, and at temperatures between 1060 and 1230°C. Experimental data also suggest a possibility that a high magnesian andesite magma would be generated by a direct partial melting of the uppermost harzburgitic mantle under anhydrous conditions.     

吉林伊通-大屯地区晚中生代-新生代玄武岩的地球化学特征及其意义

吉林伊通-大屯地区有长达80Ma的火山喷发历史,为探讨该区深部地质演化提供了条件。从晚白垩长春大屯火山(92．5±0．5Ma)到伊舒地堑内第三纪伊通火山群(31Ma、9～15Ma),玄武岩碱性逐渐增强,Dy/Yb比值逐渐升高,根据地幔动态熔融模型计算获得的玄武岩最终形成深度由约50km变深至110km。根据岩石圈盖效应推测该区晚白垩纪以来岩石圈厚度逐渐增厚。伊通第三纪碱性玄武岩显示了均一的地球化学组成;类似洋岛玄武岩(OIB)的微量元素分配模式和Nb/U比值,以及低(~(87)Sr/~(86)Sr)_i、正ε_(Nd)(t)同位素特征暗示它主要来源于软流圈。与第三纪碱性玄武岩相比,晚白垩大屯拉斑玄武岩具有相对偏高的Ni、Cr和Sc,高Ba/Th、Rb/Nb、Ba/Nb比值,高(~(87)Sr/~(86)Sr)_i和低(~(143)Nd/~(144)Nd)_i。这些特征可能与软流圈熔体与古老富集地幔之间的相互反应有关。伊通-大屯玄武岩的演化特征反映了岩石圈在板内岩浆作用中所担当的不同角色:第三纪时,岩石圈并没有在物质上直接参与岩浆作用,但岩石圈对上涌软流圈起到了机械阻挡作用;而在晚白垩岩浆作用中,岩石圈的间接和直接作用都得到了体现。     

中国大陆科学钻探CCSD-PP3钻孔地幔岩的尖晶石相部分熔融证据

CCSD PP3超镁铁岩表现为高 Mg 和 Cr,低 Ca 和 Al 特征,是中国东部和超高压变质带上极其罕见的亏损地幔岩,通过地球化学和矿物学和 Re-Os 同位素研究发现岩石来自古元古代岩石圈地幔,并在地幔浅部尖晶石相条件下发生部分熔融,最近一次部分熔融作用发生在中-晚元古代,后经岩石圈厚度加大、拆沉或深俯冲过程,岩石转变为石榴石橄榄岩。     

青藏高原新生代火车头山碱性及钙碱性两套火山岩的地球化学特征及其物源讨论

藏北羌塘火车头山新生代火山岩可区分为钙碱性及碱性两个不同的系列。钙碱性火山岩主要岩石组合为玄武岩-安山岩-英安岩,其SiO_2介于49%～70%之间,Al_2O_3>10%,Na_2O/K_2O>1;其中玄武岩具平坦型稀土配分型式,LREE/HREE为1.3～1.8,(La/Yb)_N为2.87～4.45,无明显铕异常,δEu为0.96～1.09;该套岩石的Mg~#与SiO_2相关关系以及La/sm-La等亲岩浆元素与超亲岩浆元素协变关系表明,它们应为幔源岩浆经分离结晶演化的产物,其岩石组合类型以及低的Sm/Yb值(Sm/Yb=1.53～5.35)表明它们的原始岩浆应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融。本区碱性火山岩为一套典型的钾质岩石系列,主要岩石组合类型为碱玄岩-碱玄质响岩-响岩,其SiO_2介于44%～59%之间,Al_2O_3>14%,Na_2O/K_2O介于0.47～1.51之间;岩石轻稀土强烈富集,LREE/HREE为13.20～15.76,(La/Yb)_N=50.44～91.99;其岩石组合类型以及Mg~#与SiO_2相关关系以及La/Sm-La协变关系同样表明它们为共源岩浆分离结晶演化的产物;然而,其较高的Sm/Yb值(Sm/ Yb=2.63～13.98)表明它们并非地幔橄榄岩直接局部熔融的产物,岩石弱的负Eu异常(δEu=0.77～0.85)以及Th、U的强烈富集和Nb、Ta的相对亏损,又反映了原始岩浆中有显著的地壳物质的贡献;该套钾质碱性系列岩石在La/Co-Th/Co同分母协变图上呈直线型分布,而在La/Co-Sc/Th异分母协变图上呈显著的双曲线分布,从而表明其源区为二源混合型,是青藏高原特殊的壳幔混合层局部熔融的产物,这些特征是新生代青藏高原壳幔层圈物质交换的重要岩石学证据。