祁连山青海云杉(Picea crassifolia)林土壤有机碳与化学性质的相互关系

通过对祁连山大野口流域的青海云杉林大样地进行土壤剖面取样, 分析了样地土壤有机碳与pH值、养分和阳离子交换量等基本化学性质的变化规律及其相互关系. 结果表明: 随土层深度不断增加, 土壤有机碳含量逐渐减小, 在20～30 cm以下趋于稳定(P > 0.05); 土壤pH值不断增大, 仅在0～10 cm与10～20 cm差异显著(P<0.05); 土壤全氮、速效氮、全磷和阳离子交换量不断减小, 全氮含量在30～40 cm以下趋于稳定(P > 0.05), 速效氮含量变化剧烈(P<0.05), 全磷含量差异性不显著(P > 0.05), 阳离子交换量与有机碳含量变化规律相同; 土壤速效磷、全钾和速效钾含量没有明显的变化规律, 速效磷和全钾含量差异性不显著(P > 0.05), 速效钾含量仅在0～10 cm与10～20 cm差异显著(P<0.05). 土壤有机碳与全氮、速效氮、全磷、速效磷、速效钾和阳离子交换量之间呈极显著和显著正相关, 与土壤pH值和全钾含量之间呈极显著和显著负相关. 土壤有机碳与其他基本化学性质的回归方程具有较高精度(R²=0.793), 影响土壤有机碳含量的主要化学因子依次为土壤阳离子交换量、速效钾和全磷含量.     

山东半岛蓝色经济区土壤有机碳储量及固碳潜力分析

土壤碳储量研究在碳循环和全球变化中具有重要意义,但以往碳储量计算结果受到数据来源的制约。山东省多目标区域地球化学调查采用双层网格化采样和分析,获取了大密度、高精度土壤有机碳数据,为土壤碳库的准确计算奠定了基础。笔者利用这些数据计算了山东半岛蓝色经济区表层（0～20 cm）、中上层（0～100 cm）及全层（0～160 cm）的土壤有机碳（SOC）密度和储量,并对其空间分布特征及固碳潜力进行了研究。结果显示,经济区内3种土壤层次的碳库组成不同,表层SOC储量占总碳（TC）储量的71.67%,随深度增加所占比例逐渐减小,而无机碳(SIC)储量所占比例逐渐增加,全层二者所占比率较为接近:表层SOC储量为132.64 Mt,碳密度为2.06 kg/m²;中上层为458.27 Mt,碳密度为7.11 kg/m²;全层为619.96 Mt,碳密度为9.61 kg/m²。各层SOC密度处于全国偏低水平,且在不同土壤类型、地貌类型、土地利用类型之间有一定差异:褐土土表层SOC密度最高（2.48 kg/m²）,风沙土最低（0.91 kg/m²）;灌溉水田表层SOC密度最高（3.45 kg/m²）,菜地最低（1.61 kg/m²）。表层SOC密度分布总体上呈现为沿海地区低、鲁北平原和胶莱盆地中等、山地丘陵和中低山区偏高的分布格局。从第二次土壤普查和本次多目标调查数据所建立的回归方程分析发现,在今后一定时期内,本区表层土壤总体表现为“碳汇”效应,未来可净增总有机碳（TOC）量60.94 Mt,其中“碳源”量5.07 Mt,“碳汇”量65.97 Mt。     

赤道太平洋上层水体颗粒态生物硅分布及与营养盐的关系

依托中国“大洋一号”第20和第21调查航次,分析测定了东、西赤道太平洋4个站位的颗粒态生物硅浓度及其粒级结构。结果显示赤道太平洋采样站各层位颗粒态生物硅(PBSi)总浓度分布范围为5~65 nmol/dm³,东赤道太平洋的调查站位颗粒态生物硅的总浓度平均值达46 nmol/dm³,是西赤道太平洋的近3倍。PBSi的粒径结果显示在东赤道太平洋调查站位0.8~20 μm粒径颗粒是PBSi的主要来源,其平均贡献率高达64%;而在西赤道太平洋2种粒径的生物硅贡献率相当。营养盐分布对PBSi的浓度及粒径分布有显著的影响,并在一定程度上控制了“硅质泵”的组成结构,是控制大洋生物泵运转的重要因素。     

1980s-2010s内蒙古草地表层土壤有机碳储量及其变化

以我国内蒙古草原为研究区域,结合1982-1988年第二次土壤普查资料以及2011-2012年实地考察数据,构建了基于遥感数据和土壤数据的区域表层土壤有机碳储量估算方法,对研究区1980s和2010s表层土壤有机碳储量、空间分布特征及其变化进行研究,结果表明：(1) 1980s、2010s内蒙古草地表层土壤 (0~20 cm) 有机碳储量分别为2.05 Pg C、2.17 Pg C,土壤有机碳密度约为3.48 kg C·m^-2、3.69 kg C·m^-2,其空间分布上呈现从草甸草原、典型草原、荒漠草原逐渐降低的特征;(2) 1982-2012年间,内蒙古草地表层土壤有机碳储量略有增加,但增加幅度较小,其中草甸草原和典型草原表层土壤有机碳储量增加,荒漠草原则表现为减少。研究结果将为研究区因地制宜地采取固碳措施,实现草地可持续管理提供科学参考。     

Organic Geochemistry of the Early Jurassic Oil Shale from the Shuanghu Area in Northern Tibet and the Early Toarcian Oceanic Anoxic Event

This paper presents new geological and geochemical data from the Shuanghu area in northern Tibet, which recorded the Early Toarcian Oceanic Anoxic Event. The stratigraphic succession in the Shuanghu area consists mostly of grey to dark-colored alternating oil shales, marls and mudstones. Ammonite beds are found at the top of the Shuanghu oil shale section, which are principally of early Toarcian age, roughly within the Harplocearasfalciferrum Zone. Therefore,the oil shale strata at Shuanghu can be correlated with early Toarcian black shales distributing extensively in the European epicontinental seas that contain the records of an Oceanic Anoxic Event. Sedimentary organic matter of laminated shale anomalously rich in organic carbon across the Shuanghu area is characterized by high organic carbon contents, ranging from 1.8% to 26.1%. The carbon isotope curve displays the δ^13C values of the kerogen (δ^13Ckerogen) fluctuating from -26.22 to -23.53‰ PDB with a positive excursion close to 2.17‰, which, albeit significantly smaller, may also have been associated with other Early Toarcian Oceanic Anoxic Events (OAEs) in Europe. The organic atomic C/N ratios range between 6 and 43, and the curve of C/N ratios is consistent with that of the δ^13Ckerogen values. The biological assemblage,characterized by scarcity of benthic organisms and bloom of calcareous nannofossils (coccoliths), reveals high biological productivity in the surface water and an unfavorable environment for the benthic fauna in the bottom water during the Oceanic Anoxic Event. On the basis of organic geochemistry and characteristics of the biological assemblage, this study suggests that the carbon-isotope excursion is caused by the changes of sea level and productivity, and that the black shale deposition, especially oil shales, is related to the bloom and high productivity of coccoliths.     

甘肃侏罗纪植物化石Ginkgo huttonii角质层地球化学特征

对甘肃民和盆地侏罗纪植物化石Ginkgo huttonii(Sternb．)Heer的角质层与现生银杏Ginkgo biloba的角质层进行了地球化学特征对比分析,结果表明植物化石角质层有机物特征符合石油形成中沥青的演化特点。通过有机物组分含量分析,它们相当于中国中、新生代油源岩有机质类型中的腐泥型一腐殖腐泥型。对烃组分三角图进行投点,落入Ⅱ型干酪根范围内。通过有机质中的一些指标分析,发现Ginkgo huttonii的角质层处于低成熟阶段,与煤中显微组分角质体的成烃模式基本一致。另外,角质层的可溶有机质分布特征表明,植物化石角质层对陆相高蜡原油的形成有一定的作用,证明高等植物对蜡质有贡献。当前研究及古植物学资料表明,银杏是一种有利于煤成油的植物。     

Fate of the Evros River suspended particulate matter in the northern Aegean Sea

Evros River is the most important river flowing into the North Aegean Sea (eastern Mediterranean) in terms of freshwater discharge, and the second largest one of Eastern Europe after the Danube River. Salinity and temperature measurements, together with suspended particulate matter concentrations were obtained in various depths at 14 stations in the adjacent Alexandroupolis Gulf during four seasons (June 1998, September 1998, February 1999 and March 2000) in order to investigate the particle dynamics and distributions in the northern Aegean Sea. Analysis of the collected data, together with particle observations under the scanning electron microscope and study of satellite images showed that, under certain circumstances driven by the hydrological and wind regime of the area, the Evros River particulate matter, with the associated pollutants, can be transferred far away from the estuary and implicitly comprise a hazardous factor for the environmental status of the northern Aegean Sea. This fact, combined with the future construction of the Burgas-Alexandroupolis pipeline, may cause a negative impact on the studied natural ecosystem.     

大庆长垣以西地区扶余油层次生孔隙预测

为了在普遍低孔、低渗的背景下寻找次生孔隙发育的储层,在次生孔隙形成机制分析和储层成岩作用研究的基础上,结合考虑影响次生孔隙形成的多种因素,对大庆长垣以西地区扶余油层次生孔隙发育区进行预测。研究表明,该地区次生孔隙的形成主要受青山口组下排有机酸和碳酸的影响,且受到断层的控制和超压的影响,次生孔隙主要分布在齐家地区和龙虎泡阶地等凹陷周边区域,在西部斜坡区亦发育由大气水淋滤所形成的次生孔隙。在次生孔隙发育区,若发育岩性圈闭或构造圈闭,则为有利的油气聚集场所。 