25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

富碱斑岩中超镁铁深源包体岩石的矿物学特征

在云南省鹤庆县六合乡富碱斑岩体中找到超镁铁深源岩石包体，这对于研究富碱斑岩的起源和演化及其成岩成矿作用具有重要意义。本文较系统地研究了深源包体岩石的矿物学特征，揭示该深源包体具有原始上地幔岩在地幔条件下受到一定程度富集地幔流体交代作用改造的特征，具有富集地幔低程度部分熔融属性，为富碱斑岩的成岩成矿演化提供了重要的矿物学依据。     

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.     

基于ODBC的地震前兆数据批量卸出与转换程序的实现

介绍了CDBC技术、工作流程及数据传递方式；分析了研制数据卸出与转换程序的关键技术及实现方法；描述了程序的组织结构。通过实例说明了该程序在全国前兆台网中心卸载与转换地震前兆数字化的观测数据中的应用。     

有限弹性变形地壳中的地震波

地壳由半无限大的基岩上一层厚度为H^-的表土层组成，入射地震波为垂直的SH波，产生水平地面运动。当浅源大地震发生时，在极震区以外行波传播产生地面运动将使地壳介质有非线性的有限弹性变形。用小参数摄动法使非线性控制方程为线性化的小参数各阶控制方程，得出头两阶线性控制方程的解析解。     

Validation through HVSR measurements of a method for the quick detection of site amplification effects from intensity data: an application to a seismic area in Northern Italy

An instrumental validation is attempted of an innovative approach devoted to the quick individuation, from macroseismic data, of site amplification phenomena able to significantly modify seismic hazard levels expected on the basis of average propagation effects only. According to this methodology, two evaluations of hazard are performed at each investigated locality: the former, obtained by epicentral intensity data ‘reduced’ at the site through a probabilistic attenuation function and, the latter, computed by integrating such data with seismic effects actually observed at the site during past earthquakes. The comparison, for each locality, between these two hazard estimates allow to orientate the identification of those sites where local amplifications of earthquake ground motion could be significant. In order to check such methodology, indications obtained in this way from macroseismic data are compared with the estimates of transfer functions performed through the HVSR technique applied to microtremors. Results concerning municipalities located in a seismic area of Northern Italy indicate a good agreement between macroseismic and instrumental estimates.     

A Reconnaissance Method for Delineation of Tracts for Regional-Scale Mineral-Resource Assessment Based on Geologic-Map Data

The U.S. Geological Survey (USGS) is proposing to conduct a global mineral-resource assessment using geologic maps, significant deposits, and exploration history as minimal data requirements. Using a geologic map and locations of significant pluton-related deposits, the pluton-related-deposit tract maps from the USGS national mineral-resource assessment have been reproduced with GIS-based analysis and modeling techniques. Agreement, kappa, and Jaccard's C correlation statistics between the expert USGS and calculated tract maps of 87%, 40%, and 28%, respectively, have been achieved using a combination of weights-of-evidence and weighted logistic regression methods. Between the experts' and calculated maps, the ranking of states measured by total permissive area correlates at 84%. The disagreement between the experts and calculated results can be explained primarily by tracts defined by geophysical evidence not considered in the calculations, generalization of tracts by the experts, differences in map scales, and the experts' inclusion of large tracts that are arguably not permissive. This analysis shows that tracts for regional mineral-resource assessment approximating those delineated by USGS experts can be calculated using weights of evidence and weighted logistic regression, a geologic map, and the location of significant deposits. Weights of evidence and weighted logistic regression applied to a global geologic map could provide quickly a useful reconnaissance definition of tracts for mineral assessment that is tied to the data and is reproducible.     

A study on the early-warning technique concerning debris flow disasters

According to the principle of the eruption of debris flows, the new torrent classification techniques are brought forward. The torrent there can be divided into 4 types such as the debris flow torrent with high destructive strength, the debris flow torrent, high sand-carrying capacity flush flood torrent and common flush flood by the techniques. In this paper, the classification indices system and the quantitative rating methods are presented. Based on torrent classification, debris flow torrent hazard zone mapping techniques by which the debris flow disaster early-warning object can be ascertained accurately are identified. The key techniques of building the debris flow disaster neural network (NN)real time forecasting model are given detailed explanations in this paper, including the determination of neural node at the input layer, the output layer and the implicit layer, the construction of knowledge source and the initial weight value and so on. With this technique, the debris flow disaster real-time forecasting neural network model is built according to the rainfall features of the historical debris flow disasters, which includes multiple rain factors such as rainfall of the disaster day, the rainfall of 15 days before the disaster day, the maximal rate of rainfall in one hour and ten minutes. It can forecast the probability, critical rainfall of eruption of the debris flows, through the real-time rainfall monitoring or weather forecasting. Based on the torrent classification and hazard zone mapping, combined with rainfall monitoring in the rainy season and real-time forecasting models, the debris flow disaster early-warning system is built. In this system, the GIS technique, the advanced international software and hardware are applied, which makes the system′s performance steady with good expansibility. The system is a visual information system that serves management and decision-making, which can facilitate timely inspect of the variation of the torrent type and hazardous zone, the torrent management, the early-warning of disasters and the disaster reduction and prevention.     

Phénomènes karstiques fossiles et actuels au sein des formations métamorphiques silico-alumineuses de la nappe pan-africaine de Yaoundé (Sud-Cameroun)Fossil and present-time karstic phenomena in silico-aluminous metamorphic formations of the Pan-African nappe of Yaoundé (South-Cameroon)

Numerous karstic features have been recognised in the non-carbonaceous micaschists and gneisses of the Yaoundé Pan-African nappe, south of Cameroon. It is shown that their formation was controlled by the structural features of the rocks. The wells and the pipes in the bedrock outcrops point out a current karstification process, resulting from the plagioclase dissolution by the acid rain waters. Hill wall alveoli and caves, of pre-Miocene age, are exhumed features that were done by dissolution in the aquiferous underground. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 545–550.