Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

页岩油资源定量评价中关键参数的选取与校正——以松辽盆地北部青山口组为例

页岩油资源评价过程中,常用热解参数(S1)反映含油性。由于实验关系,所测得的S1存在轻烃、重烃的损失,为更准确的对页岩油资源进行定量评价,本文通过有机质成烃动力学研究以及对样品抽提前后的热解参数进行对比,对S1进行轻、重烃补偿校正,获得泥页岩总含油率参数,根据泥页岩排烃门限确定其可动油含量参数(S1/TOC)。研究结果表明,松辽盆地北部青山口组泥页岩S1校正前后相差2~3倍,排烃门限对应的S1/TOC=75mg/g TOC,结合黏土矿物含量(表征可压裂性),优选出页岩油勘探开发有利区:青一段有利区主要集中在齐家古龙凹陷中北部及龙虎泡大安阶地中部,青二、三段集中在龙虎泡大安阶地中部与齐家古龙凹陷中南部。     

两次强降水风暴双偏振参量特征分析

基于济南S波段双偏振多普勒天气雷达探测数据,结合探空和地面实况资料,对2019年同一区域两次强降水风暴双偏振参量特征进行分析。结果表明:1)两次对流性强降水发生在弱垂直风切变环境下,具有较强的对流有效位能,低层湿度较大,0℃层高度较高,利于短时强降水的产生。2)两次强降水风暴都具有低质心热带降水特征,45 dBZ以上的强回波区主要位于环境0℃层高度之下。3)风暴低层强回波区都对应大的差分反射率因子Z_(DR)和比差分相位K_(DP),Z_(DR)≥0.5 dB,K_(DP)≥0.5°·km~(-1),相关系数CC≥0.95;反射率因子在50～54 dBZ之间,对应的K_(DP)1.0°·km~(-1),CC≥0.97,Z_(DR)适中,是两次强降水风暴导致高强度降水的主要双偏振参量特征。4)两次强降水风暴Z_(DR)柱和K_(DP)柱高度存在明显差异,7月27日强降水风暴前侧出现Z_(DR)柱和K_(DP)柱,高度接近-10℃层高度,8月10日强降水风暴Z_(DR)柱和K_(DP)柱略高于0℃层高度,Z_(DR)柱高度对雷暴强度具有指示作用。     

堆石料Gudehus-Bauer亚塑性本构模型改进及参数确定方法

研究了Gudehus-Bauer亚塑性本构模型和模型参数的求取方法。采用侧限压缩试验曲线求取模型参数颗粒硬度hs和指数n。根据模型方程的推导,建立了拟合指数 和 与围压之间的关系,并提出了新的拟合参数。考虑到堆石料具有明显的剪胀、剪缩性,在Gudehus-Bauer模型线性项中增加了主要控制体积应变项 ,以改善模型对堆石料体积应变曲线的描述。采用堆石料大型侧限压缩试验、常规三轴试验分别验证了新的拟合参数和改进后的Gudehus-Bauer亚塑性本构模型。与堆石料试验成果比较,提出的新拟合参数与改进后的Gudehus-Bauer亚塑性本构模型可以较好地模拟堆石料的应力-应变特性,并较好地改善了堆石料体变曲线的模拟结果。对改进后的模型作了常规三轴加、卸载模拟,模拟结果反映了改进的Gudehus-Bauer亚塑性本构模型具有一定的卸载适应性。     

天然气中甲烷和CO2的二元同位素特征

不同成因的天然气由于形成温度不同,往往会有不同的稳定同位素特征。但是,由于经常不能同时获得天然气以及它的生成母体的同位素成分,很难用单独的C或H同位素成分来确定它的形成温度。在形成天然气时,不同的温度会形成不同的二元同位素的浓度,温度越低,二元同位素的比例越大,因此只需要知道天然气本身的二元同位素的浓度,就可以确定形成温度,从而避免了需要知道天然气生成母体的同位素成分这一难题。本文利用高级量子化学计算,预测了不同温度下天然气中甲烷和CO2气体的二元同位索（Clumped isotope）的特征,提供用于天然气成因分析的新方法。     

地地震多参数BP神经网络预测煤层厚度

依据煤层反射波运动学和动力学特征，提取出了波峰波谷振幅A1、平均频率Fa、主频带能量Qf1、低频带宽能量Qf和峰值频率Fmain等5个地地震特征参数。选取8组学习样本，利用4层BP（Back Propagation)人工神经网络模型，采用动量法和自适应调整的改进算法，训练BP网络，用训练好的BP网络预测煤层厚度。经实例验证，地震多参数BP网络预测煤层厚度精度高，是一种有效的煤厚预测方法。     

考虑渗透率变化的煤层气储层数值模拟及参数敏感性研究

煤层气开采过程中储层渗透率的变化对产气量影响较大,通过引入S＆D渗透率变化模型,建立了考虑渗透率变化的煤储层三维气水两相渗流数学模型,完成模型检验后应用所编制软件研究了煤储层参数、吸附参数及渗透率模型特征参数对开发效果的影响。结果表明,煤层气产量随着初始含气量、煤层有效厚度、裂缝渗透率和Langmuir压力的增大而增大,随储层原始压力、裂缝孔隙度和Langmuir体积的增大而减小,而解吸时间对产气量影响不大;裂缝渗透率随着杨氏模量和基质收缩/膨胀系数的增大而增大,随泊松比和裂缝压缩系数的增大而减小。引入S＆D模型后计算的累积产气量要比常规模型低1.3%,因此不可忽视煤层气产出过程中渗透率的变化。     

非线性铀成矿作用--以上第三系砂岩型铀矿为例

本以滇西上第三系陆相砂岩铀矿为例研究非线性铀成矿作用。与铀矿化有关的参数可分为矿化参量和控制参量,矿化参量以及矿化在控制参量中的分布均遵从对数正态分布,控制参量(温度、压力和地球化学条件)的耦合作用对铀矿化的概率和平均品位的控制作用是非线性的,铀矿化在控制参量构成的相空间中的变化轨迹是一复杂的超曲面。非线性铀成矿作用具分形特征。     

Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.     

在矿产储量管理上应改革沿用的静态工业指标初探

50年代引进前苏联在地勘工作中用静态法制订工业指标、计算矿产储量,为矿山建设提交可供设计利用的矿产储量方面,曾经起到巨大的推动作用。然而,随着改革、开放,上述方法就不能适应市场经济发展的要求,本文试图在剖析静态法制订工业指标、计算矿产储量的四个弊端的基础上,探讨用贸易指标计算矿产储量来取代以往那种用静态法制订工业指标计算矿产储量的管理方法。