新疆准噶尔盆地北西部层间氧化带砂岩型铀矿形成条件分析

本文从盆地结构、沉积盖层构造特征、盆地沉积的岩相条件及岩石地球化学地特征、区域水文地质条件以及沉积盖层中的后生改造作用等方面，分析准噶尔盆地北西部层间氧化带砂岩型铀矿形成的地质条件。     

辐射损伤法在寻找层间氧化带砂岩型铀矿床的应用研究

本文论述了电子顺磁共振法测量岩石中结晶石英的顺磁中心浓度──辐射损伤法在层间氧化带砂岩型铀矿床中的应用；在层间氧化带中，氧化带岩石中的石英顺磁中心浓度高，铀含量低，即辐射损伤大，古轴量高，而氧化－还原过渡带中的石英顺磁中心浓度低，铀含量高，表明铀源来自氧化带岩石。由此可以探讨矿床成因和成矿物质来源，并用于找矿和成矿预测工作。     

锰矿石的矿物平衡研究

本文应用热力学理论对不同价态锰的各种矿物的平衡关系进行了讨论，同时用湖南棠甘山和遵义锰矿石分析数据对其结论作了验证。     

浅谈中亚地区层间氧化带砂岩型铀矿成矿作用

本文分析了前苏联中亚地区在漫长的地史发展过程中长期的沉积间断、岩相古地理和古气候的变迁，以及水动力条件的改变对层间氧化带砂岩型铀矿形成的作用，并就我国西部当前的找矿工作提出一些值得注意的问题。     

The degree of oxidation of iron in synthetic iron-magnesian biotites

Summary Chemical analytical and pyrolytical methods have been used to study the Fe⁺²/Fe⁺³ ratios and dehydroxylation reactions in synthetic biotites. It has been found for the biotites with Fe/(Fe + Mg) of 20 to 70 mole % that the oxidation degree decreases from 26 to 16% with increasing iron. Based on the measured amounts of water and hydrogen released during pyrolysis it is inferred that the deprotonization is a dominant reaction at low temperatures (T 600°C), accompanied by dehydration as the temperature increases. Depending on the composition, a complete dehydroxylation takes place at T 900 °C, and the measured amount of water corresponds to the iron oxidation degree in the starting samples. The results of this study have important implications with respect to determination of the formation conditions of biotite-bearing rocks, and also for improvement of the techniques for determination of different valence of iron and water.

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Le degré d'oxidation du fer en biotites synthétiques contenants le fer et le magnésium

Résumé Des méthodes chimiques et pyrolitiques ont été utilisées pour l'étude des rapports Fe⁺²/Fe⁺³ et de la réaction de la déhydroxilation en biotites synthétiques. On a trouvé pour les biotites avec Fe/(Fe + Mg) de 20-70 mole % que le degré d'oxidation décroît à partir de 26 jusqu'à 16% pendent que le contenu du fer s'accroît. Sur la base de la quantité d'eau et hydrogène liberée pendant la pyrolyse, on infère que la déprotonisation est une réaction dominante à températures basses (T = 600°C), mais quand la température s'accroît, la déprotonisation est accopagnée de la déhydratation. Dépendant de la composition il y a une déhydroxilation complète à T = 900°C, et la quantité de l'eau mesurée correspond au degré d'oxidation du fer dans les specimens initials. Les résultats de cette étude infuencent la détermination des conditions de formation des roches contenantes biotite et aussi l'amélioration des techniques de la détermination du fer de valences différentes et de l'eau.

     

Features of the atmospheric cycle of aerosol trace elements and sulphur dioxide revealed by baseline observations in Canada

Selected applications of baseline aerosol, SO₂ and deposition chemistry observations in Canada are reviewed to illustrate how new insight can be gained into features of the atmospheric pathway of trace substances such as sources, transformation and removal. A strong annual variation in Arctic aerosol concentration is a manifestation of particle residence times that are much longer in winter than in summer. Differences in the variation of SO₄ ⁼ and V concentrations in the Arctic winter are due to SO₂ oxidation. The mean rate of oxidation between November and April ranges from 0.04 to 0.25%/h and is a minimum in December, January and February. Br measured on filters in the Arctic peaks in concentration later (March and April) than anthropogenic particulate matter suggesting photochemical production. Acidity in Arctic aerosol and in glacial ice are correlated. The relationship yields a best estimate of acidity in the absence of anthropogenic influences of 5.8 mole/l. Coincident air and precipitation measurements of sulphur oxides indicate that on average in eastern Canada 60% of SO₄ ⁼ in rain originates from SO₂ oxidation in the storm. Trends in Arctic ice core acidity and SO₂ emissions in Europe are similar, that is, little variation in the first half of the century and a marked increase since the mid 1950's. This is consistent with meteorological and chemical evidence linking Arctic air pollution with Eurasian sources.     

The NO2-O3 system at sub-ppm concentrations: Influence of temperature and relative humidity

The stoichiometry and kinetics of the reaction of NO₂ with O₃ at sub-ppm concentration level have been investigated as a function of temperature and relative humidity. The experiments were performed in a continuous flow reactor using chemiluminescent and wet chemical methods of analysis.The rate constant found can be described by the Arrhenius expression: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaaiikaiaaik% dacaGGUaGaaGyoaiaaiEdacqGHXcqScaaIWaGaaiOlaiaaigdacaaI% 0aGaaiykaiabgEna0kaaigdacaaIWaWaaWbaaSqabeaacqGHsislca% aIXaGaaG4maaaakiaabwgacaqG4bGaaeiCaiaacIcadaWcgaqaaiaa% cIcacqGHsislcaaIYaGaaGOnaiaaikdacaaIWaGaeyySaeRaaGyoai% aaicdacaGGPaaabaGaamivaiaacMcacaqGGaGaae4yaiaab2gadaah% aaWcbeqaaiaabodaaaGccaqGGaWaaSGbaeaacaqGTbGaae4BaiaabY% gacaqGLbGaae4yaiaabwhacaqGSbGaaeyzamaaCaaaleqabaGaaeyl% aiaabgdaaaaakeaacaqGZbWaaWbaaSqabeaacaqGTaGaaeymaaaaaa% aaaaaa!62A3!\[(2.97 \pm 0.14) \times 10^{ - 13} {\text{exp}}({{( - 2620 \pm 90)} \mathord{\left/ {\vphantom {{( - 2620 \pm 90)} {T){\text{ cm}}^{\text{3}} {\text{ }}{{{\text{molecule}}^{{\text{ - 1}}} } \mathord{\left/ {\vphantom {{{\text{molecule}}^{{\text{ - 1}}} } {{\text{s}}^{{\text{ - 1}}} }}} \right. \kern-\nulldelimiterspace} {{\text{s}}^{{\text{ - 1}}} }}}}} \right. \kern-\nulldelimiterspace} {T){\text{ cm}}^{\text{3}} {\text{ }}{{{\text{molecule}}^{{\text{ - 1}}} } \mathord{\left/ {\vphantom {{{\text{molecule}}^{{\text{ - 1}}} } {{\text{s}}^{{\text{ - 1}}} }}} \right. \kern-\nulldelimiterspace} {{\text{s}}^{{\text{ - 1}}} }}}}\] and are independent of the relative humidity. As commonly encountered in previous studies a lower-than-two reaction stoichiometry is observed.Heterogeneous reactions occurring at the reactor wall seem to be essential in the reaction mechanism. The NO₃ wall conversion to NO₂ and the N₂O₅ wall scavenging in the presence of H₂O are suggested to account for the observed stoichiometric factors.     

层间氧化带中褪色带的成因及其找矿意义

本文列举了国内外层间氧化带砂岩型铀矿床中的一些褪色现象 ,从宏观到微观地分析了褪色带的成因 ,认为褪色带的形成是在层间氧化带形成后 ,由深部上升的还原性气体或油气对氧化砂体进行还原的产物。运用国内外典型的事例说明主要工业铀矿体产于褪色带与原生带之间 ,由于褪色带是次生还原的产物 ,往往会将褪色带误认为是原生带 ,从而导致主要工业铀矿体漏失。由此分析推断出 :乌库尔其地区西部的 2 5 3线一带和中部的 3 89～ 42 1线一带第Ⅴ旋回铀矿体可能还在沿倾向向前延伸 ,目前已揭露的铀晕带是褪色带而不是还原带 ,这些地段的铀矿找矿工作应重新认识评价。     

基于ArcView3.2的证据权重法在层间氧化带型砂岩铀矿定量评价中的应用

介绍了证据权重法及其理论基础,根据层间氧化带型砂岩铀矿成矿理论,应用由ArcView3.2二次开发形成的砂岩铀矿勘查信息系统软件在克鲁伦盆地内提取控矿信息,最后通过证据权重分析综合证据因子,完成盆地内层间氧化带型砂岩铀矿的远景预测。