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131.
132.
Min Wang Wei Wang Benlin He Mingliang Sun Yansheng Yin Lan Liu Wuyuan Zou Xuefei Xu 《中国海洋大学学报(英文版)》2010,9(4):376-380
TiO2 films were formed on metallic titanium substrates by the anodic oxidation method in H2SO4 solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning
electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight
illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry
impedance spectrum (EIS) and polarization curves. The result showed that the TiO2 film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on
its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV
illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO2 film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO2 film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was
2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the
TiO2 film possesses much better performance under dark condition, and it can be applied as an engineering material under dark
seawater environment. 相似文献
133.
134.
135.
《International Geology Review》2012,54(11):1418-1444
Quaternary volcanic rocks in the Kuandian (KD), Longgang (LG), Changbaishan (CBS), Wangqing (WQ), and Jilin (JL) volcanic centres in eastern Liaoning and southern Jilin provinces contain mantle xenoliths of spinel-facies lherzolites and minor harzburgites. Among the study sites, the KD, LG, and CBS volcanic fields are located on the northeastern margin of the North China Craton (NCC), whereas the WQ and JL fields lie on the southern margin of the Xing'an–Mongolia Orogenic Belt (XMOB). The (Fo) components of olivine (Ol) and Cr# (=Cr/(Cr + Al)) of spinel, together with trace element abundance of clinopyroxene, suggest that the subcontinental lithospheric mantle (SCLM) in the study area has undergone a low degree (4–6%) of partial melting. The rocks do not show modal metasomatism, but clinopyroxene grains in selected samples show elevated large ion lithophile element compositions, suggesting that the mantle xenoliths underwent minor cryptic metasomatism by exchange with a silicate melt. Two-pyroxene thermometry yielded equilibration temperatures ranging from 740°C to 1210°C. The corresponding oxygen fugacity (fO2) was calculated to range from FMQ –2.64 to +0.39 with an average of –0.59 (n?=?53). The oxidation state is comparable to that of abyssal peridotites and the asthenospheric mantle. We failed to discover differences in equilibration temperatures and oxidation state between lherzolites and harzburgites, suggesting that partial melting did not affect fO2 values. In addition, similar fO2 of non-metasomatized and metasomatized samples suggest that metasomatism in the region did not affect fO2. Our data suggest that the present SCLM beneath the northeastern margin of the NCC and the southern margin of the XMOB are very similar and likely formed from a fertile asthenosphere after delamination of an old lithospheric keel below the NCC in response to the west-dipping subduction of the Pacific oceanic plate since early to middle Mesozoic time. 相似文献
136.
Physical, chemical, and mineralogical analyses of undisturbed drill cores of pelitic schist from a landslide area in Japan clarified the mechanisms of chemical weathering of pelitic schist. Oxidizing surface water percolates downward and reaches an oxidation front, where chlorite is altered to Al‐vermiculite, graphite and pyrite are oxidized and depleted, and goethite precipitates. Oxidation of pyrite also occurs just below the oxidation front, probably by ferric iron. Pyrite oxidation yields sulphuric acid, which penetrates further downward, interacting with and weakening the rocks. In addition to this chemical weakening, stress release and shearing along schistosities form an incipient shear zone, which propagates to a sliding zone that forms the rupture surface of a landslide. Once a sliding zone has developed, it inhibits downward groundwater flow across it because of its low permeability, slowing the downward propagation of the weathering zone until this filtration barrier is broken by landslide movement. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
137.
138.
从川西高原饮用水赋存的环境-地质条件出发进行研究,较全面的探讨了该区气象、水文、土壤等环境要素对水中氧化还原电位的制约作用。通过对研究区内饮用水赋存环境的一系列环境地质调查与氧化还原电位的现场测试可以得出:(1)该研究区所处特殊的地理位置(青藏高原的东南部-横断山系北段,属川西高山高原区)导致该区具有冬长,无夏,春秋短,气温低,温差大等独有的气象条件;该区主要的构造侵蚀高山地貌类型导致地下水循环具有径流途径短,水力坡度大,水-土间交换作用十分强烈的特点,该区土壤的特点是淋滤作用较强且成弱酸性等,这三个环境要素的特点是直接导致该区饮用水中氧化还原电位值升高的主要原因;(2)由于不同类型水(河水、沟水、泉水、土井水)其与大气接触程度的差异导致其氧化还原值呈现由高到低的趋势,即河水〉沟水〉泉水〉土井水。 相似文献
139.
A Study of DMS Oxidation in the Tropics: Comparison of Christmas Island Field Observations of DMS, SO2, and DMSO with Model Simulations 总被引:2,自引:0,他引:2
G. Chen D. D. Davis P. Kasibhatla A. R. Bandy D. C. Thornton B. J. Huebert A. D. Clarke B. W. Blomquist 《Journal of Atmospheric Chemistry》2000,37(2):137-160
This study reports comparisonsbetween model simulations, based on current sulfurmechanisms, with the DMS, SO2 and DMSOobservational data reported by Bandy et al.(1996) in their 1994 Christmas Island field study. For both DMS and SO2, the model results werefound to be in excellent agreement with theobservations when the observations were filtered so asto establish a common meteorological environment. Thisfiltered DMS and SO2 data encompassedapproximately half of the total sampled days. Basedon these composite profiles, it was shown thatoxidation of DMS via OH was the dominant pathway withno more than 5 to 15% proceeding through Cl atoms andless than 3% through NO3. This analysis wasbased on an estimated DMS sea-to-air flux of 3.4 ×109 molecs cm-2 s-1. The dominant sourceof BL SO2 was oxidation of DMS, the overallconversion efficiency being evaluated at 0.65 ± 0.15. The major loss of SO2 was deposition to theocean's surface and scavenging by aerosol. Theresulting combined first order k value was estimated at 1.6 × 10-5 s-1. In contrast to the DMSand SO2 simulations, the model under-predictedthe observed DMSO levels by nearly a factor of 50. Although DMSO instrument measurement problems can notbe totally ruled out, the possibility of DMSO sourcesother than gas phase oxidation of DMS must beseriously considered and should be explored in futurestudies. 相似文献
140.
Abstract: The sulfur isotopic ratios (δ34 S) of ore minerals from the Toyoha deposit, Hokkaido, one of the largest Pb–Zn–Ag polymetallic vein-type deposits in Japan, were studied. More than 90% of the δ34 S values of the studied sulfide minerals collected from the Toyoha deposit range from +5 to +9%, with an average of approximately +7% irrespective of the mineral species, veins, elevations, depth, mineralization stages and mineral assemblages. Relatively uniform δ34 S values obtained in this study suggest that the reduced aqueous sulfur species predominated over the oxidized sulfur in the ore solution throughout the mineralization stages. Thus, the source of sulfur for the ore sulfides is postulated to be magmatic.
The temperature obtained from the fluid inclusion study and the temperature of the sulfur isotopic geothermometer are not consistent. This suggests that each mineral precipitated under disequilibrated conditions with respect to the sulfur isotope.
The change in redox conditions presumably encountered between the mineralization stages did not account for the isotopic fluctuations since the isotopic exchanges between the oxidized and reduced aqueous sulfurs are much slower than the rate of oxidation of the ore solution. 相似文献
The temperature obtained from the fluid inclusion study and the temperature of the sulfur isotopic geothermometer are not consistent. This suggests that each mineral precipitated under disequilibrated conditions with respect to the sulfur isotope.
The change in redox conditions presumably encountered between the mineralization stages did not account for the isotopic fluctuations since the isotopic exchanges between the oxidized and reduced aqueous sulfurs are much slower than the rate of oxidation of the ore solution. 相似文献