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101.
Steven Creighton Thomas Stachel Sergei Matveev Heidi Höfer Catherine McCammon Robert W. Luth 《Contributions to Mineralogy and Petrology》2009,157(4):491-504
The oxidation state, reflected in the oxygen fugacity (fO2), of the subcratonic lithospheric mantle is laterally and vertically heterogeneous. In the garnet stability field, the Kaapvaal
lithospheric mantle becomes progressively more reducing with increasing depth from Δlog fO2 FMQ-2 at 110 km to FMQ-4 at 210 km. Oxidation accompanying metasomatism has obscured this crystal-chemical controlled depth-fO2 trend in the mantle beneath Kimberley, South Africa. Chondrite normalized REE patterns for garnets, preserve evidence of
a range in metasomatic enrichment from mild metasomatism in harzburgites to extensive metasomatism by LREE-enriched fluids
and melts with fairly unfractionated LREE/HREE ratios in phlogopite-bearing lherzolites. The metasomatized xenoliths record
redox conditions extending up to Δlog fO2 = FMQ, sufficiently oxidized that magnesite would be the stable host of carbon in the most metasomatized samples. The most
oxidized lherzolites, those in or near the carbonate stability field, have the greatest modal abundance of phlogopite and
clinopyroxene. Clinopyroxene is modally less abundant or absent in the most reduced peridotite samples. The infiltration of
metasomatic fluids/melts into diamondiferous lithospheric mantle beneath the Kaapvaal craton converted reduced, anhydrous
harzburgite into variably oxidized phlogopite-bearing lherzolite. Locally, portions of the lithospheric mantle were metasomatized
and oxidized to an extent that conversion of diamond into carbonate should have occurred.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
102.
Peter W. L. Vojak Clive Edwards Martin V. Jones 《Estuarine, Coastal and Shelf Science》1985,20(6):661-671
Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn2+ (2 mgl−1). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn2+ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn2+ to Mn4+. Rates of manganese oxidation were much higher in freshwater (3·32 μgl−1 h−1 in water containing 30 mgl−1 of suspended matter) than in saline water (0·7 μgl−1 h−1 in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl−1 particulates). 相似文献
103.
某废弃煤矿竖井经倾倒有机废液,导致环境污染事件,造成巷道及采空区内地下水污染。本文结合场地实际情况,选取倾倒竖井(事故井)及周边区域为中试区域,采用“抽出处理+原位氧化循环”两阶段联合修复技术对污染场地开展中试研究。本文介绍了场地污染概况、地下水修复中试方案设计和实施,以及对修复效果进行评价。结果表明,中试处理后地下水中COD和二氯甲烷最高去除率分别为97.88%和99.74%。中试试验表明, “抽出处理+原位氧化循环”两阶段修复技术,对处理矿区内巷道及采空区等复杂地层结构下深层地下水中有机污染物具有较好的去除效果,可以结合现场实际情形对整个污染场区进行规模应用。 相似文献
104.
105.
Van T.H.Phan Fabrizio Bardelli Pierre Le Pape Raoul-Marie Couture Alejandro Fernandez-Martinez Delphine Tisserand Rizlan Bernier-Latmani Laurent Charlet 《地学前缘(英文版)》2019,10(5):1715-1729
The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam). 相似文献
106.
107.
108.
Brett A. Yuskiewicz F. Stratmann W. Birmili A. Wiedensohler E. Swietlicki O. Berg J. Zhou 《Atmospheric Research》1999,50(3-4)
Direct physical measurements of particle mass and number concentration indicate an increase in overall aerosol mass resulting from cloud processing, most likely through aqueous-phase chemistry (e.g., SO2 oxidation). Measurements conducted in the Pennines of Northern England reveal an average increase of 14 to 20% in dry aerosol mass (0.003<particle diameter<0.9 μm) after aerosol passage through an orographic cloud. The rate of in-cloud mass production is most sensitive to changes in upwind particle size distributions, SO2 concentration, and cloud water acidity. Newly-formed mass appears in size range between 200 and 600 nm and enhances the bimodality of the particle number distribution after cloud processing. Furthermore, the cloud-produced mass is estimated to increase total light scattering, bsp, by 18 to 24%. The scattering efficiency of the dry, cloud-generated aerosol is 5.0±0.3 m2 g−1 and increases to 7.4±0.7 m2 g−1 when adjusted to 90% relative humidity by incorporating particle hygroscopicity data. 相似文献
109.
S. G. Eeckhout E. De Grave R. Vochten N. M. Blaton 《Physics and Chemistry of Minerals》1999,26(6):506-512
Mössbauer spectra (MS) of anapaite (Ca2 Fe2+(PO4)2?·?4H2O) and of a sample after being immersed in a 4% H2O2 solution at room temperature (RT) over 12 days (hereafter an4ox) were collected at temperatures in the range 4.2 to 420?K and 11 to 300?K respectively. All MS consist of symmetrical doublets, hence magnetic ordering was not observed. The temperature dependencies of the Fe2+ centre shifts of anapaite and an4ox were analysed with the Debye model for the lattice vibrations. The characteristic Mössbauer temperatures were found as 370?K?±?25?K and 340?K?±?25?K, and the intrinsic isomer shifts as 1.427?±?0.005?mm/s and 1.418?±?0.005?mm/s respectively. From the external-field (60?kOe) MS recorded at 4.2 and 189?K for the non-treated sample, the principal component V zz of the electric field gradient (EFG) is determined to be positive and the asymmetry parameter η?≈?0.2 and 0.4 respectively. The temperature variations of the quadrupole splittings, ΔE Q(T), cannot be interpreted on the basis of the thermal population of the 5 D electronic levels resulting from the tetragonal compression of the O6 co-ordination. The low-temperature linear behaviour of ΔE Q(T) is attributed to a strong orbit-lattice coupling. A field of 60 kOe applied to anapaite at 4.2?K produces magnetic hyperfine splitting with effective hyperfine fields of ?136, ?254 and ?171?kOe along the principal axes Ox, Oy and Oz of the EFG tensor respectively. Additional oxidation treatments in solutions with various H2O2 concentrations up to 20% and subsequent Mössbauer experiments at room temperature, have revealed that the anapaite structure is not sensitive to oxidation since eventually only a small amount of Fe2+ (~6.5%) is converted into Fe3+. 相似文献
110.
The sorption of AuCl4
−,AuCl2
− and Au(S2O3)3- on δ-MnO2 was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO3 solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO2 are 0.18–0.21 and 0.28μmoL/m2 for AuCl4
− and Au(S2O3)2
3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases
as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO2. The Au sorption decreases in the sequence of Au(S2O3)2
3- >AuCl4
− >AuC12
−. The intrinsic equilibrium constants (logK
int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl4
- are preferentially adsorbed by δ-MnO2 and the inner-sphere Au-surface complexes are formed on the surface.
Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No.
49573200) and the Australian Mining Industry. 相似文献