石笋稀土元素含量的两种溶样方法测试结果对比分析

对于采自川东北诺水河溶洞群的石笋SJ3,采用2%的HNO3和HF+HNO3两种溶样方法分析测试了其稀土元素(REE)含量。结果表明:虽然多数石笋中存在碎屑物质,SJ3的少数样品在采用2%的HNO3溶解后有明显的残留物存在,但采用HF+HNO3全部溶解样品得到的SJ3的REE含量与采用稀HNO3溶样得到的结果并没有显著的差别。这表明SJ3的REE可能主要不是直接来自于地表土壤中难溶的硅酸盐矿物,而可能是土壤风化释放的REE通过吸附在颗粒/胶体态物质的表面,经过岩溶地下水的搬运而沉积到SJ3中。由此认为,采用稀酸溶样基本上可以将石笋SJ3的REE释放出来。      

邢台市岩溶水污染现状与演化趋势预测

由于地表水的污染和固体废物的乱堆放,导致邢台市岩溶水多处出现污染现象,且污染范围不断扩大,严重威胁下游水源地的供水安全。本文依据大量水质监测数据,评价了岩溶水的污染现状,采用数值方法预测了污染源继续存在和污染源得到治理两种情况下地下水污染的演化趋势,并分析了其对水源地的影响。预测结果表明:污染源存在时,地下水污染物Cr6+超标浓度等值线将以0.769m/d的速度扩散;在污染源得到有效治理和控制后,地下水污染物超标浓度等值线扩散速度将减少至0.402m/d,可见污染源治理对减缓地下水污染的扩散有重要作用。预测结果可作为选择地下水保护方案和污染治理措施的依据。      

土地覆盖对岩溶地下河碳汇的影响——以广西打狗河流域为例

以广西打狗河为例,对比分析河流东、西两岸地下河的土地覆盖差异及其对岩溶碳汇的影响。打狗河东岸林地占56.13%,耕地占15.15%;而西岸林地、耕地分别只占20.8%、12.95%。但西岸的裸岩和荒地比例大,分别占29.57%和25.95%,而东岸分别占14.19%和10.98%。植被和土壤覆盖差异导致了东、西两岸碳循环的地球化学指标有明显的差异,东岸地下河水的HCO3-、Ca2+、PCO2(平均分别是233.71mg/L、85.5mg/L、909.46Pa)明显高于西岸(分别为177.26mg/L、64.65mg/L、257.37Pa),而东岸的SIC、pH值(分别为0.12和7.40)又低于西岸(分别是0.38和7.85)。因此,东岸有更强的岩溶动力条件,东岸地下河的平均碳汇强度比西岸高14%,其中,东岸下桥地下河的碳汇强度是西岸旦峒地下河的3.7倍。东西岸地下河水的δ13CDIC、TOC资料也进一步证明了土地覆盖条件对地下河岩溶碳汇具有重要的影响。      

新疆西克尔地区下奥陶统鹰山组岩溶分带性研究

塔里木盆地岩溶缝洞型储层作为重要的油气储层备受关注,而目前预测此类型储层的方法较有限。在新疆伽什县西克尔野外露头区地表岩溶现象丰富,志留系地层以填平补齐的方式充填在一系列的溶沟和溶槽中,部分洼地中还有志留系地层残留,表明该区发育加里东中期岩溶。在本区岩溶古地貌的基础上,基于排泄基准面的分析,划分出3级岩溶台面并对应发育3期岩溶。据现代地貌学和岩溶学理论,按照水动力条件的不同并结合本区岩溶发育特征,运用岩溶旋回的观点将第二期岩溶剖面分为表层岩溶带、垂直渗滤带和水平潜流带,认识到西克尔地区古岩溶地下水发育规律及洞穴发育程度。构造运动是垂向岩溶分带性的主控因素;因此,在大的构造背景的前提下,可以有效地预测巴楚地区的缝洞型储层。     

济阳坳陷桩海地区下古生界硅化岩溶储集层空间分布模式

基于岩心描述和镜下观察,分析了研究区下古生界硅化岩溶储集层的岩性特征。通过对沟通潜山 断块和古近纪洼陷的边界断层产状、潜山断块内下古生界产状的分析,认为下古生界碳酸盐岩具备埋藏岩溶作 用条件,提出了古近纪沉积物压释酸性水向潜山断块运移的3种方式,即：翘倾端断面补给畅流运移模式、倾 没端断面补给畅流运移模式和背斜凸起两侧双向渗入补给对流循环模式。利用这 3种模式可以合理解释研究区 下古生界潜山硅化岩溶储集层空间分布的特点和规律。翘倾端断面补给畅流运移模式可以解释潜山断块高部位 硅化岩溶层段储集层的发育情况,倾没端断面补给畅流运移模式和背斜凸起两侧纵向渗入补给对流循环模式, 可以解释潜山断块的低部位硅化岩溶层段储集层的发育情况。该模式还可以合理地解释硅化岩溶储集层在下古 生界赋存层位的 “ 穿层性”特点,同时也能够合理解释潜山断块周缘发育硅化岩溶层段,而潜山断块中心地带 很少出现硅化岩溶层段等现象。     

Method for calibrating a theoretical model in karst springs: an example for a hydropower station in South China

A theoretical, dimensionless rainfall–runoff model was used to simulate the discharge of Wulongdong spring in western Hubei province, South China. The single parameter (time constant τ) in the model is easy to obtain by fitting the recession rate of the observed hydrographs. The model was scaled by simply matching the total annual flow volume of the model to the observed value. Annual distribution of actual evapotranspiration was embedded in the model input to calculate the accumulated deficit of soil moisture before each rain event. Hourly precipitation input data performed better than daily data, defining τ of 0.85 days and returning a Nash–Sutcliffe efficiency of 0.89 and the root mean square error of 0.07. This model offers an effective way to simulate the discharge of karst springs that respond sensitively to rainfall events. The model parameters of a successful simulation can be used to estimate the recharge area and indicate the intrinsic response time of the basin. Copyright © 2016 John Wiley & Sons, Ltd.     

Organic carbon inputs,common ions and degassing: rethinking mixing dissolution in coastal eogenetic carbonate aquifers

Caves deliver freshwater from coastal carbonate landscapes to estuaries but how these caves form and grow remains poorly understood. Models suggest fresh and salt water mixing drives dissolution in eogenetic limestone, but have rarely been validated through sampling of mixing waters. Here we assess controls on carbonate mineral saturation states using new and legacy geochemical data that were collected in vertical profiles through three cenotes and one borehole in the Yucatan Peninsula. Results suggest saturation states are primarily controlled by carbon fluxes rather than mixing. Undersaturation predicted by mixing models that rely on idealized end members is diminished or eliminated when end members are collected from above and below actual mixing zones. Undersaturation due to mixing is limited by CO₂ degassing from fresh water in karst windows, which results in calcite supersaturation. With respect to saline groundwater, controls on capacity for mixing dissolution were more varied. Oxidation of organic carbon increased pCO₂ of saline groundwater in caves (pCO₂ = 10^–2.06 to 10^–0.96 atm) relative to matrix porosity (10^–2.39 atm) and local seawater (10^–3.12 atm). The impact of increased pCO₂ on saturation state, however, depended on the geochemical composition of the saline water and the magnitude of organic carbon oxidation. Carbonate undersaturation due to mixing was limited where gypsum dissolution (Cenote Angelita) or sulfate reduction (Cenote Calica) increased concentrations of common ions (Ca²⁺ or HCO₃^?, respectively). Maximum undersaturation was found to occur in mixtures including saline water that had ion concentrations and ratios similar to seawater, but with moderately elevated pCO₂ (Cenote Eden). Undersaturation, however, was dominated by the initial undersaturation of the saline end member, mixing was irrelevant. Our results add to a growing body of literature that suggests oxidation of organic carbon, and not mixing dissolution, is the dominant control on cave formation and enlargement in coastal eogenetic karst aquifers. Copyright © 2016 John Wiley & Sons, Ltd.     

The Burren: a glacial,karstic and biokarstic expression of a limestone plateau in western Ireland

The term glaciokarst describes a landscape where both glacial and karstic processes have contributed to geomorphological evolution and has been applied to a range of environments from the high arctic to the alpine Mediterranean. Nevertheless, glaciokarstic environments globally often exhibit significant variation in geomorphological processes and landforms due to these geographical differences. The Burren, County Clare, Republic of Ireland, is often quoted as a quintessential glaciokarstic landscape. However, the Burren and other similar environments would appear to lean towards one end of the glaciokarst spectrum, where solutional and biological processes have been dominant throughout the Holocene, in contrast to ice‐dominated glaciokarsts where karstic and biokarstic processes are temperature‐limited and cryospheric processes remain the principal geomorphological agents. Holocene landscape evolution and the development of a range of meso‐, micro‐ and nano‐scale karren features on limestone surfaces appears to be largely biokarstic in origin. Karstification of many glacially scoured limestone pavements would have begun under acidic soil cover, with biological soil processes contributing to smooth, rounded cryptokarstic surface forms. Holocene soil erosion is attributed to anthropogenic activity, climatic fluctuations and the evolution of the karstic groundwater system leading to vertical soil loss through widening grikes. Exposed limestone pavements subject to subaerial conditions often exhibit extensive lichen colonization which has been shown to influence the overall rate of karstification and contribute to the development of micro‐ and meso‐scale bioweathering features. Where cryptokarstic features have been exhumed from beneath soil cover, their evolution under subaerial conditions leads to intermediate, polygenetic karren features. In light of our current understanding of the Burren landscape, it is proposed that the term glaciobiokarstic may be a better expression to encompass the biological processes that have played a fundamental role in the evolution of the Burren and similar landscapes, without neglecting the contribution of glacial and inorganic karstic processes. Copyright © 2016 John Wiley & Sons, Ltd.     

盾构隧道抬升作用下极限上覆土压力计算方法

注浆抬升技术是盾构隧道不均匀沉降治理的有效措施之一,但目前尚存在隧道抬升过程上覆土压力计算困难而无法估算抬升引起的隧道受力变形的问题。利用透明土结合PIV观测技术设计研发了模拟盾构隧道抬升的小比尺室内模型试验系统,通过试验获得了隧道抬升过程极限上覆土压力及上覆土速度场,根据上覆土的剪切滑移特征将上覆土分成了4个不同的运动区域,进而结合相关联流动法则,提出了隧道抬升作用下极限上覆土压力计算模型,并基于虚功平衡方程,推导了极限上覆土压力计算表达式。将计算所得的极限上覆土压力值与试验结果进行对比,两者有较好的吻合度,计算误差在4%～15%之间。     

西南地区石漠化分布、演变特征及影响因素

根据中国西南岩溶区1999—2008年石漠化遥感调查结果,研究了该区石漠化发生现状和近十年间石漠化在区域、岩性、地貌及区域经济等方面的演变特征,并对发生石漠化的影响因素进行分析。结果显示,石漠化集中分布在滇、黔、桂三省区;石漠化的发生与岩性和地貌密切相关,其中纯碳酸盐岩中石漠化发生率高于杂碳酸盐岩,并随灰岩或碳酸盐岩含量减少而降低,而地形高差相对大的峰丛洼地、峰林洼地石漠化发生率最高,并随地貌相对高差变小而降低。石漠化发生程度与岩性、地貌关系表现多样,纯碳酸盐岩中轻度石漠化比例高于中度和重度石漠化之和的比例,杂碳酸盐岩中中度和重度石漠化之和的比例高于轻度石漠化比例;在峰林洼地、峰林/缓丘平原中轻度石漠化比例高于中度和重度石漠化之和的比例,缓丘台地和丘陵谷地中中度和重度石漠化之和的比例高于轻度石漠化,是岩溶构造演化与人类活动共同制约的结果。从1999年到2008年间,该区石漠化已经呈现转轻趋势,主要表现在总面积减少,石漠化程度减轻;石漠化演变过程中发生在不同岩性和地貌中改善或恶化发生率的变化趋势与上述石漠化的发生规律相似。石漠化还不同程度地影响居民的生活水平,调查显示,严重石漠化县域内石漠化面积与农民人均纯收入、人均生产总值等呈负相关,县域内石漠化面积是影响农民人均纯收入,乃至人均生产总值最重要的因素。因此,石漠化调查结果显示,研究区石漠化呈向好趋势,但是治理难点依然存在。