全文获取类型
收费全文 | 291篇 |
免费 | 46篇 |
国内免费 | 78篇 |
专业分类
测绘学 | 1篇 |
大气科学 | 57篇 |
地球物理 | 93篇 |
地质学 | 165篇 |
海洋学 | 78篇 |
天文学 | 2篇 |
综合类 | 7篇 |
自然地理 | 12篇 |
出版年
2023年 | 6篇 |
2022年 | 4篇 |
2021年 | 9篇 |
2020年 | 9篇 |
2019年 | 13篇 |
2018年 | 7篇 |
2017年 | 10篇 |
2016年 | 16篇 |
2015年 | 17篇 |
2014年 | 21篇 |
2013年 | 14篇 |
2012年 | 14篇 |
2011年 | 10篇 |
2010年 | 15篇 |
2009年 | 7篇 |
2008年 | 22篇 |
2007年 | 12篇 |
2006年 | 7篇 |
2005年 | 22篇 |
2004年 | 12篇 |
2003年 | 8篇 |
2002年 | 18篇 |
2001年 | 14篇 |
2000年 | 14篇 |
1999年 | 15篇 |
1998年 | 25篇 |
1997年 | 13篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 6篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有415条查询结果,搜索用时 171 毫秒
61.
62.
63.
Betty K. Pun Christian Seigneur Daniel Grosjean Pradeep Saxena 《Journal of Atmospheric Chemistry》2000,35(2):199-223
Atmospheric particles contain a myriad of organiccompounds, including many multifunctional,water-soluble organic compounds. Many of thesecompounds are postulated to be secondary of origin. This work investigates the possible precursors ofseveral classes of multifunctional, water-solublesecondary organic compounds by analyzing the pathwaysleading to their formation, based on known gas-phasereactions. The analysis is termed `retrosynthetic'due to the backward direction of the analysis, fromproducts to precursors. Pathways for multi-functionalcompounds were generated combinatorially, consideringthe formation of one functional group at a time.Many multifunctional organic compounds with carboxylicacid, carbonyl, and hydroxy functional groups werefound to be first- or second-generation products ofcommon anthropogenic and biogenic volatile organiccompounds such as alkanes, alkenes, aromatics, andcyclic alkenes. The estimated yields of water-solubleorganic compounds from primary precursors ranged fromless than 1% to over 10%, based on stoichiometricconsiderations. The SOA formation index, whichcombines the concepts of yields and rates, was used tocompare the feasibility of the retrosyntheticpathways. Many of the candidate pathways involve theisomerization reaction of alkoxy radicals andoxygenated intermediate products such asmonocarboxylic acids and hydroxyaldehydes. 相似文献
64.
Determination of thermal maturity and organic matter type by principal components analysis of the distributions of polycyclic aromatic compounds 总被引:1,自引:0,他引:1
The thermal maturity and organofacies sensitivity of polycyclic aromatic compound (PAC) distributions was explored by examination of the aromatic fractions of solvent extracts from a diverse set of 53 shales, coals and kerogen macerals which have undergone either natural or artificial maturation and which represent all three principal sedimentary organic matter (OM) types. Systematic changes with maturation were observed in the following groups of isomers: tri- and tetramethylnaphthalenes, methyl- and dimethylphenanthrenes, methyl- and dimethyldibenzothiophenes, methylpyrenes, and methylchrysenes. The maturity differences were quantified by mathematical ratios of the relative concentrations of the more thermally stable isomers to the less stable, on the basis of theoretical considerations and empirical observations. The PAC maturity parameters, unlike those derived from saturated biomarker stereoisomers, are typically effective across the entire oil generation window. To compensate for the effects of OM type on the maturity parameters, they were combined using principal components analysis. The resulting first principal component was in good agreement with independent indicators of maturity. The relative distributions of C0–C3 alkylphenanthrenes, dibenzothiophene, methyldibenzothiophenes and methyldibenzofurans were evaluated by a separate principal components analysis. The results permitted an independent grouping of the samples by OM type and suggested additional, simple molecular ratios that allow graphical recognition of OM type, including the ratio of dibenzothiophenes to dibenzofurans and a ratio using C2-alkylphenanthrene isomers. 相似文献
65.
超临界萃取/气相色谱—质谱测定油页岩中的生物标志物 总被引:4,自引:1,他引:3
采用超临界萃取 /气相色谱 -质谱技术测定了广东茂名油页岩中环己烷的链取代烃、甾烷、甾烯和藿烷等生物标志物 ,其分析结果与经典索式抽提和文献结果基本相符。该方法与索式抽提法相比简单、快速、无污染和危险 ,可用于油页岩等固体样品中生物标志物的分析 相似文献
66.
67.
对氯甲烷的海洋生物地球化学循环的研究进展进行述评。介绍了氯甲烷在海洋环境中的来源、分布、去除、海-气通量、大气氯甲烷的源、汇估算及海水中氯甲烷的分析方法等方面,并提出在国内海域进行氯甲烷研究的几点设想。 相似文献
68.
69.
微区分析是现代分析技术在地质研究应用中的一个重要领域。通过电子探针对矿物的微区分析,提供了矿床成因理论研究的新依据。本文以金银互化物的研究为例,讨论了在不同在因类型矿床中,金-银构成一个连续的类质同象系列,且变化是有规律可循,其微量元素的含量与该矿床成矿地质环境和相应的地球化学场有关,从而为找矿提供了新的地质信息,拓宽了寻找同类伴生元素矿床或发现新类型矿床的途径。 相似文献
70.
Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH2OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH2OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm. 相似文献