晚中生代─新生代南海周缘地块运动与南海演化

报道了由华南几个盆地的古地磁数据综合而得的反映该区白垩纪以来古纬度变化曲线，结合Ｓｃｈｍｉｄｔｋｅ等（１９９０）发表的加里曼丹１５０Ｍａ以来的古地磁数据，表明华南与加里曼丹在４０Ｍａ前具有大致相同的古纬度变化史，差异仅出现在距今３０Ｍａ前后和１０Ｍａ以来。若此趋势可靠，则可作出下列推断：（１）南海的扩张只能发生在距今３０Ｍａ附近或１０Ｍａ以后华南与加里曼丹反向运动时期；距今３０Ｍａ的扩张已被广为接受；（２）华南与加里曼丹之向可能存在的古南海只能在９１Ｍａ之前存在；（３）南海演化可能存在两期扩张。南海的拟合可通过沿３５００ｍ等深线的先道时针旋转、后北向平移两个步骤完成。这与Ｈａｙａｓｈｉｄａ等（１９９１）提出的日本海张开与扩张模式很相似，提示东亚边缘海的形成和演化可能具有同样的机制。华南距今５０Ｍａ以来的古纬度变化与Ｔａｐｐｏｎｎｉｅｒ（１９８２）的传播挤出构造模式所预期的基本吻合，表明距今５０Ｍａ以来华南古纬度变化的运动学机制可用Ｔａｐｐｏｎｎｉｅｒ模式作解释。     

南海南部约30 ka来沉积有机质的生物输入特征

对位于南沙海区的1962柱状样中的有机质进行了热解色谱分析，估算了沉积有机质中水生生物输入和陆源生物输入的变化情况，得出了两种输入的高分辨率的堆积速率曲线，并依此探讨了有关的古海洋事件。发现Younger Dryas、Heinrich及Bond周期事件在本海区皆有表现，说明“西太平洋暖池”在末次冰期是不稳定的。     

Quantum yield for the photochemical production of dissolved inorganic carbon in seawater

The direct photooxidation of coloured dissolved organic matter (CDOM) to dissolved inorganic carbon (DIC) may provide a significant sink for organic carbon in the ocean. To calculate the rate of this reaction on a global scale, it is essential to know its quantum yield, or photochemical efficiency. We have determined quantum yield spectra, φ(λ), (moles DIC/mole photons absorbed) for 14 samples of seawater from environments ranging from a turbid, eutrophic bay to the Gulf Stream. The spectra vary among locations, but can be represented quite well by three pooled spectra for zones defined by location and salinity: inshore φ(λ)=e^{−(6.66+0.0285(λ−290))}; coastal φ(λ)=e^{−(6.36+0.0140(λ−290))}; and open ocean φ(λ)=e^{−(5.53+0.00914(λ−290))}. Production efficiency increases offshore, which suggests that the most highly absorbing and quickly faded terrestrial chromophores are not those directly responsible for DIC photoproduction.     

径流量和潮量的减小对河口与河口湾型通道地形演变的影响——以神泉、乌坎通道为例

以神泉通道和乌坎通道的演变实例说明,河口型与河口湾型通道的形成和演变受径流量或潮流量的制约。而人为作用使径流量或潮流量减小,导致通道地形急剧演变和稳定程序变差。因此必须保持径流来量或纳潮量不变。但对不同类型的通道要作具体分析。     

Remote sensing composite information of Nansha reef''s closed atoll and model of its spatial structur evolution——Ⅱ

Based on the Nansha Islands' closed atoll conception-remote sensing system in Part Ⅰ,through the solution of the information function value and isostatic value of closed and quasi-closed atoll, and by using topological analysis on growth form and the composite remote sensing quantization date as the calculating coefficients, the feature vector system and its mathematical model of two kinds of atoll are built, and the multivariate analysis is made with some examples.     

氮磷营养盐与有机汞联合作用对微氏海链藻生长的影响

探讨在高营养盐（氮、磷、硅分别为浮游植物生长的营养盐阚值≥40、50、9倍）条件下，氮浓度及氮磷摩尔比值[n（N）／n（P）]变化、汞（甲基汞和乙基汞）对微氏海链藻（Thalassiosira weissflogii）生长的影响。结果表明，高营养盐区海链藻的生长遵循营养盐限制的唯一因子论；氮浓度和氮磷比提高促进生长，当n（N）／n（P）=64则呈抑制效应；生长初期，甲基汞和乙基汞均产生毒性抑制作用，生长中后期，适量甲基汞（浓度≤1．0μg／L）、乙基汞（浓度≤0．5μg／L）却呈兴奋效应，促进生长；汞形态不同，剂量-效应关系不同。氮和有机汞是海链藻生长的刺激因子。适度有机汞污染与氮富营养化对微氏海链藻的生长产生协同效应。     

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

国外海岸沙丘形成与演化的研究

自20世纪80年代以来，国外对海岸沙丘的研究已从主要对其地貌形态的研究转向海岸海丘与海岸变迁尤其是全球变化关系的研究上，海岸沙丘形成与演化的研究倍受关注，进行了大量研究并取得了一定的研究成果。这里介绍了国外在海岸沙丘形成与演化研究方面的主要进展及其成果，并以此探讨了国内今后开展海岸沙丘形成与演化研究的主要方向与问题。     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.