商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.     

渤海西岸全新世气候演化与海陆变迁

应用第四纪地质学和海相生物等化石数量统计,以天津马棚口海岸带BQ1孔化石鉴定与统计结果,对古气候、古事件进行对比研究。通过岩芯编录,在岩性层中划分出4个海相层、5个过渡层、9个海面波动。结合研究区广泛分布的贝壳堤和牡蛎礁,利用其大量的测年资料,重现了6道海岸线;根据海相化石个体统计数,画出全新世气候演化曲线,与孢粉和物候所画的古气候演化曲线大体一致。研究历代海陆变迁,必然涉及到历史上长期争论不休的西汉大海侵等问题,谭其骧（1965）圈定的大海侵范围、海岸线分布以及考古结果几乎都能联系在一起,因此,大海侵之谜终于尘埃落定。考古界对河北平原自东汉—金的空白也有了初步答案,同时,发现中国朝代兴衰与气候冷暖有明显的对应,从而建立了气候分期。     

中坝隧道地下分水岭演化的数值模拟分析

由于铁路隧道的施工,地下水进入隧道,形成了新的排泄基准面,对区域地下水环境产生较大影响,故对该类问题进行深入研究具有重要的工程实践意义。以中坝岩溶隧道为例,采用Visual modflow对中坝隧道进行三维数值模拟,模拟中坝隧道开挖建设后,地下分水岭的演化过程,以此来探讨分析其对地下水环境的影响。     

塔里木盆地塔中隆起及北围斜区断裂体系与油气成藏关系

笔者探讨了断裂在油气聚集中的作用,它是制约塔中隆起及北围斜区油气分布规律的关键因素。基于地震资料断裂解析,塔中隆起及北围斜区断裂体系主要由北西—南东延伸的压扭性断裂带与北东—南西延伸的走滑断裂构成。断裂体系主要形成于中晚加里东中期,此后经历了晚加里东、晚海西和喜山期的继承性活动与改造。中加里东中期构造是该区构造的主要定型期,断裂不仅控制了构造带发育,也是风化壳岩溶储层、礁滩相储层、热液溶蚀碳酸盐岩储层形成关键因素。断裂带后期活动为油气运聚提供了通道,北北东断裂是油气由北部坳陷向隆起长距离运聚的主要通道。断裂带的复杂性造就了研究区油气具有沿断裂带分布,成藏模式多样,差异富集特征。     

江苏平原地区(淮河流域)潜水碘含量控制因素探讨

本文通过工作区潜水碘含量的分布特点,与所处土壤、水文地质条件、地形地貌等一起进行综合分析,对地下水中碘的控制因素有了一个全新的认识:与前人认为地下水中碘的含量与有机质成正比的观点不同的是,本文认为地下水中碘的含量与有机质含量无固定关系,但有机质有助于促进水溶性碘的增加,相似水文地质条件下成正比;地下水径流条件对潜水碘含量影响重大,径流条件较好的丘陵、岗地往往较低,地势低平、径流条件较差的洼地和泛滥沉积区往往为高碘地区;相同水文地质条件下,地下水中的碘含量与土壤中的含量成正比;碘的另一重要特征是在地下水中的浓度较为稳定,随时间、开采而变化不大。     

冀中坳陷东北部石炭-二叠系烃源岩热史及成熟史模拟

石炭-二叠系煤成气藏是冀中坳陷东北部亟待突破的勘探领域。文中基于大量的钻井、测井、地球化学和古地温资
料,分别模拟构建了大城凸起、文安斜坡和武清凹陷的埋藏史和考虑岩浆热液侵入作用的热演化史。研究结果表明冀中坳
陷东北部石炭-二叠系地层总体上经历了“三沉两抬”的构造演化过程,在印支运动前全区具有近似的演化历史,印支
期、燕山期区内构造演化开始分异,至新生代形成总体“东隆西坳”的构造格局。区内烃源岩热演化包括一次生烃和二次
生烃,并可细分为长期隆升型、后期强烈沉降深成变质型和岩浆热变质型三种类型。一次成烃主要发生在三叠系末期,二
次成烃分别在新近纪和古近纪岩浆侵入期。区内斜坡浅部和隆起区一次成烃,斜坡和凹陷深部为后期强烈沉降深成变质二
次成烃、斜坡和凸起岩浆热液侵入区发生岩浆热变质二次成烃。一次成烃期Ro 值在0.7%左右,不具成藏潜力,二次成烃
期烃源岩可达高熟、过熟阶段,成藏配置条件好,成藏潜力巨大。     

考虑河流地貌演化因素的清江隔河岩库区岸坡稳定性预测

根据清江中下游河流地貌演化与岸坡稳定性的响应关系,将河流地貌演化因子作为岸坡稳定性评价指标,采用层次分析与信息量评价模型相结合的方法,通过地理信息系统实现了清江隔河岩库区的岸坡稳定性定量预测,其预测结果与现实情况比较吻合。研究表明该方法是一种行之有效的岸坡稳定性预测方法,以及河流地貌演化对岸坡稳定性预测具有显著作用。     

黔北下志留统龙马溪组烃源岩有机地球化学特征及其古环境意义

通过对黔北地区下志留统龙马溪组烃源岩的有机碳、类异戊间二烯烃、萜烷及甾烷等有机地球化学的研究,发现具有以下特征:①正构烷烃分布以单峰分布为主,主峰碳为nC18~nC20;②Pr/Ph比值在0.16~1.24之间,普遍具有植烷优势;③伽马蜡烷指数0.10;④Ts/(Tm+Ts)比值较高,在0.42~0.61之间,且分布十分稳定;⑤C27/C29甾烷比值在0.65~1.53之间,多数样品具C29甾烷分布优势;⑥有机碳含量普遍大于0.5%,且自下向上呈规律性递减;⑦δ13Corg-28‰,普遍偏轻。这些特征均指示研究区龙马溪组的有机物产率较高,同时具有良好的有机质保存环境。通过对比岩性及有机地球化学剖面,将龙马溪组烃源岩划分为3个发育阶段。     

珠江口盆地东沙隆起生物礁地质及地震特征

东沙隆起珠江组生物礁是珠江口盆地重要的储层类型,礁灰岩主要为珊瑚藻灰岩,分为骨架岩、粘结岩及障积岩。研究区生物礁发育于开阔台地、台地边缘及台地前缘斜坡3类沉积相中,生物礁类型可分为台内点礁、台地边缘堡礁及台缘斜坡塔礁,以台地边缘堡礁为主。珠江组沉积早期,东沙隆起发育滨岸砂质沉积;中期海水逐渐淹没东沙隆起,形成镶边浅水碳酸盐台地,发育生物礁;晚期海侵台地逐渐淹没消亡,被浅海陆棚泥质沉积代替。流花台地厚度最大,最厚达563m,台地顶面地震强反射使外形轮廓清晰,台地内部中-弱振幅至空白反射,连续性降低;惠州台地厚度较流花台地薄,厚度多大于100m,顶界面强反射轮廓清晰,内部层状反射能量强-中振幅、高-中连续、中-低频,局部空白反射;陆丰台地厚约30m,只有一个高连续的强振幅。生物礁地震响应以丘形、箱型、低丘-透镜状为特征,礁顶常为强振幅,内部为波状、有时见前积结构,翼部可见上超和披覆现象等。     

Accumulation of terrestrial organic carbon on an active continental margin offshore southwestern Taiwan: Source-to-sink pathways of river-borne organic particles

Sediment samples (213 sites) collected from the tectonic-active continental margin, offshore southwestern Taiwan were analyzed for grain sizes, organic carbon, nitrogen and carbon isotopic composition to obtain mass accumulation rate of terrestrial organic carbon and carbon budget to evaluate fate of terrestrial organic carbon from small mountainous rivers on the continental margin offshore southwestern Taiwan. Terrestrial organic carbon accumulation rates range from 0.29 to 45.6 g C m⁻² yr⁻¹ with a total accumulation budget of 0.063 Mt yr⁻¹, which accounts for less than 13% of total river particulate organic carbon loads exported from the adjacent rivers, the Gaoping (a.k.a., Kaoping), Erhjen and Tsengwen rivers. This low burial efficiency of terrestrial organic carbon demonstrated that a majority of river-borne particles together with organic materials was moved away from the study area.For the river-borne particles from the Gaoping river, a pair of depocenters in the upper slope flanking the Gaoping submarine canyon are the locations where the maximum TC_org accumulation rate were observed which hold up to 45% (0.016 Mt yr⁻¹) of the calculated accumulation found in the study region. On the other hand, the occurrence of higher-fraction terrestrial organic carbon in the upper and middle Gaoping submarine canyon suggests that a majority of particulate organic carbon of the Gaoping river was transported directly into the deep-sea basin through the Gaoping submarine canyon. Our results demonstrated that active margin with narrow shelf and slope is not an efficient sink for the large amount of terrigenous organic carbon supplied by the small rivers, but, a transient environment for these river derived particles.