颗粒态有机物在长江口及其邻近海域的夏季分布和影响因素初析

利用气相色谱法对长江口及其邻近海域的表层颗粒态木质素(p-lignin)进行测定和分析,结合粒度、有机碳(OC%)、叶绿素a(Chl a)、碳稳定同位素(δ13C)等参数研究颗粒态有机物的夏季分布,并对其分布影响因素进行了初步分析。结果表明,悬浮颗粒物粒度组成以粘土和粉砂为主,平均粒径为7.9μm;OC%的值为0.57—7.41%,Chl a的值为0.35—3.71μg/L,δ13C的值为-25.7‰—–16.6‰,在口门外水华站位出现OC%、Chl a和δ13C的最大值,表明浮游生物的现场生产是主要贡献;紫丁香基酚类(S)、香草基酚类(V)和肉桂基酚类(C)8种木质素酚单体的含量Λ8(相对于总有机碳的含量)为0.0406—1.47mg/100mg OC;紫丁香基系列与香草基系列的质量比值(S/V)的分布范围较宽,为0.5—1.6之间,均值为0.8;肉桂基含量与香草基含量比值(C/V)的分布范围为0.02—0.2之间,均值为0.09;香草基酚类的酸醛比值[(Ad/Al)v]在0.24—2.30之间。盐度、总悬浮颗粒物(TSM)浓度是控制长江口内区与邻近海域颗粒态有机物来源与分布差异的重要控制因素,颗粒态木质素在向海输送过程中还会受到矿物组分、生物降解、浮游生物现场生产等各种因素的作用,使其组成成分和性质发生改变。木质素等参数表明最大浑浊带尽管对颗粒态有机物向海输送有改造作用,但是影响区域有限。     

Are assemblages of the fireworm Hermodice carunculata enhanced in sediments beneath offshore fish cages?

Abundances of the fireworm Hermodice carunculata were counted through a monitoring assessment study of fish cages in Barranco Hondo（NE Tenerife）. Seven campaigns were conducted from November 2007 to June 2010 and temporal variations were found, as well as differences among sampling stations. The polychaete H. carunculata obtained its highest abundance in sediments beneath fish cages throughout the study period. Thus, the assemblages of this omnivorous species were favoured by the presence of fish cages.     

白令海颗粒有机物碳、氮同位素组成及其生物地球化学意义

Stable carbon and nitrogen isotopic composition of particulate organic matter(POM) were measured for samples collected from the Bering Sea in 2010 summer. Particulate organic carbon(POC) and particulate nitrogen(PN) showed high concentrations in the shelf and slope regions and decreased with depth in the slope and basin, indicating that biological processes play an important role on POM distribution. The low C/N ratio and heavy isotopic composition of POM, compared to those from the Alaska River, suggested a predominant contribution of marine biogenic organic matter in the Bering Sea. The fact that δ13C and δ15N generally increased with depth in the Bering Sea basin demonstrated that organic components with light carbon or nitrogen were decomposed preferentially during their transport to deep water. However, the high δ13C and δ15N observed in shelf bottom water were mostly resulted from sediment resuspension.     

The evolution of rifting on the volcanic margin of the Pelotas Basin and the contextualization of the Paraná–Etendeka LIP in the separation of Gondwana in the South Atlantic

The Pelotas Basin is the classical example of a volcanic passive margin displaying large wedges of seaward-dipping reflectors (SDR). The SDR fill entirely its rifts throughout the basin, characterizing the abundant syn-rift magmatism (133–113 Ma). The Paraná–Etendeka Large Igneous Province (LIP), adjacent to west, constituted the pre-rift magmatism (134–132 Ma). The interpretation of ultra-deep seismic lines showed a very different geology from the adjacent Santos, Campos and Espírito Santo Basins, which constitute examples of magma-poor passive margins. Besides displaying rifts totally filled by volcanic rocks, diverse continental crustal domains were defined in the Pelotas Basin, such as an outer domain, probably constituted by highly stretched and permeated continental igneous crust, and a highly reflective lower crust probably reflecting underplating.The analysis of rifting in this portion of the South Atlantic is based on seismic interpretation and on the distribution of regional linear magnetic anomalies. The lateral accretion of SDR to the east towards the future site of the breakup and the temporal relationship between their rift and sag geometries allows the reconstitution of the evolution of rifting in the basin. Breakup propagated from south to north in three stages (130–127.5; 127.5–125; 125–113 Ma) physically separated by oceanic fracture zones (FZ). The width of the stretched, thinned and heavily intruded continental crust also showed a three-stage increase in the same direction and at the same FZ. Consequently, the Continental-Oceanic Boundary (COB) shows three marked shifts, from west to east, from south to north, resulting into rift to margin segmentation. Rifting also propagated from west to east, in the direction of the final breakup, in each of the three segments defined. The importance of the Paraná–Etendeka LIP upon the overall history of rupturing and breakup of Western Gondwanaland seems to have been restricted in time and in space only to the Pelotas Basin.     

桑沟湾及附近海域表层沉积物碳氮同位素分析及有机质来源

Naturally existing stable carbon and nitrogen isotopes are important in the study of sedimentary organic matter sources. To identify the sources of sedimentary organic matter in Sanggou Bay and its adjacent areas, which is characterized by high-density shellfish and seaweed aquaculture, the grain size, organic carbon(OC), total nitrogen(TN), carbon and nitrogen isotopic composition(δ13C and δ15N) of organic matter in the surface sediment were determined. The results showed that, in August, sedimentary OC and TN ranged from 0.17% to 0.76% and 0.04% to 0.14%, respectively. In November, OC and TN ranged from 0.23% to 0.87% and 0.05% to 0.14%, respectively. There was a significant positive correlation between OC and TN(R=0.98, P0.0001), indicating that OC and TN were homologous. In August, the δ13C and δ15N of organic matter varied from-23.06‰ to-21.59‰ and 5.10‰ to 6.31‰, respectively. In November, δ13C and δ15N ranged from-22.87‰ to-21.34‰ and 5.13‰ to 7.31‰, respectively. This study found that the major sources of sedimentary organic matter were marine shellfish biodeposition, seaweed farming, and soil organic matter. Using a three-end-member mixed model, we estimated that the dominant source of sedimentary organic matter was shellfish biodeposition, with an average contribution rate of 65.53% in August and 43.00% in November. Thus, shellfish farming had a significant influence on the coastal carbon cycle.     

Seasonal dynamics of light absorption by chromophoric dissolved organic matter (CDOM) in the NW Mediterranean Sea (BOUSSOLE site)

We analyze a two-year time-series of chromophoric dissolved organic matter (CDOM) light absorption measurements in the upper 400 m of the water column at the BOUSSOLE site in the NW Mediterranean Sea. The seasonal dynamics of the CDOM light absorption coefficients at 440 nm (a_cdom(440)) is essentially characterized by (i) subsurface maxima forming in spring and progressively reinforcing throughout summer, (ii) impoverishment in the surface layer throughout summer and (iii) vertical homogeneity in winter. Seasonal variations of the spectral dependence of CDOM absorption, as described by the exponential slope value (S_cdom), are characterized by highest values in summer and autumn at the surface and low values at the depths of a_cdom(440) subsurface maxima or just below them. Variations of a_cdom(440) are likely controlled by microbial digestion of phytoplankton cells, which leads to CDOM production, and by photochemical destruction (photobleaching), which leads to CDOM degradation. Photobleaching is also the main driver of S_cdom variations. Consistently with previous observations, a_cdom(440) for a given chlorophyll a concentration is higher than expected from Case I waters bio-optical models. The total non-water light absorption budget shows that surface waters at the BOUSSOLE site are largely dominated by CDOM during all seasons but the algal bloom in March and April. These results improve the knowledge of CDOM absorption dynamics in the Mediterranean Sea, which is scarcely documented. In addition, they open the way to improved algorithms for the retrieval of CDOM absorption from field or satellite radiometric measurements.     

Tracing dissolved organic matter cycling in the eastern boundary of the temperate North Atlantic using absorption and fluorescence spectroscopy

Apparent oxygen utilization (AOU), dissolved organic carbon (DOC), coloured dissolved organic matter (CDOM) absorption spectra, and CDOM fluorescence characteristic of aromatic amino acids (excitation/emission 280 nm/320 nm; F(280/320)) and marine-humic like substances (320 nm/410 nm; F(320/410)) were measured in full depth during a cruise in the temperate Eastern North Atlantic (ENA). An optimum multi-parameter (OMP) inverse method was run to calculate water mass proportion-weighted average (archetypal) concentrations of these chemical parameters for all water masses and samples. Archetypal concentrations retain the variability due to water mass mixing and basin scale mineralization from the water mass formation sites to the study area. Conversely, the difference between measured and archetypal concentrations, retain the variability due to dissimilarities in mineralization processes within the study area. Our analysis indicates that DOC supported 26±3% of the AOU in the dark temperate ENA and that basin scale processes occurring at and from the formation area of the water masses explained 63% of the total DOC variability. Our data also suggests that DOC remineralized at the basin scale was of lower molecular weight, and with a lower proportion of fluorescent aromatic amino acids than found within the study area. The relationship between the absorption coefficient at 254 nm (a_CDOM(254)) and AOU indicates that a_CDOM(254) was consumed during organic matter remineralization in the dark ocean, with 55% of the variability being explained by basin scale processes. The relationships of F(320/410) with AOU and DOC confirmed that marine humic-like substances are produced by microbial degradation processes, at a rate of 6.1±0.9×10⁻³ mg equivalents of QS mol AOU⁻¹. Our results also indicate that basin-scale remineralization processes account for 85% of the total variability of F(320/410), emphasizing that large scale processes control the formation of humic-like substance in the dark ENA.     

莱州湾东岸近岸海域规划围填海后冲淤演变预测

运用Mike21模型中的水动力模块对研究区的潮流场进行了模拟,分析研究区的冲淤趋势;利用经验公式,对波浪和潮流进行耦合,计算出极端条件下的最大冲刷深度,对比规划用海实施前后的最大冲刷深度,以对该区域的海岸防护、工程选址等提供科学依据。结果表明:受到填海工程的影响,龙口湾内有轻微淤积,界河至石虎咀近岸海域的波浪和潮流受工程影响而变小,冲刷强度变弱。     

近50年来杭州湾七姊八妹列岛海域海床演变分析

七姊八妹列岛海域位于杭州湾南部的灰鳖洋内,除了岛礁周围局部存有深沟外,其余地区海床平缓.为了探究该海域海床演变情况,在了解杭州湾来水来沙特征基础上,分析了七姊八妹列岛海域的水动力、悬沙和底质分布特征.不同时期海图的对比分析表明,该海域近岸水深较小,人类活动频繁,围涂筑堤工程较多,一直处于淤积状态,属淤涨型岸滩,而离岸较远的海域,泥沙难于落淤而随潮反复搬运,基本处于冲淤平衡状态.1962～2008年这46 a间,七姊八妹列岛海域总体呈现与岸线走向一致的淤积、冲刷间隔分布的冲淤带.平均淤积厚度约2.2 m,淤积幅度约5.0 cm/a,大多数地方平均冲刷厚度约2.4 m,冲刷幅度约5.0 cm/a.这些特点与当地的水动力条件和泥沙沉积特性相一致.