林分密度对华北土石山区油松人工林土壤有机碳及养分特征的影响

 以木兰围场国有林场管理局实施间伐后6种保留密度下（540、650、1 084、1 104、1 408和1 860 株 / hm2）油松人工林为研究对象,研究各土层的土壤有机碳和N、P、K等养分元素含量及其相关关系。研究结果显示：(1) 土壤有机碳含量和碳密度垂直递减特征明显,均随土壤深度的增加而显著减小,当林分密度由540 株 / hm2增加到1 860 株 / hm2时,土壤有机碳含量及碳密度变化规律不尽一致,其分布区间分别为10.56~21.21 g / kg,与5.48~11.70 kg / m2;(2) 林分密度对土壤有机碳及碳密度有显著的影响,1 408 株 / hm2油松林下土壤有机碳含量及碳密度分别与650 株 / hm2和1 860 株 / hm2油松林下土壤有机碳含量及碳密度呈显著性差异,而其它林分密度间无显著差异。当林分密度为1 104 株 / hm2时,各土层土壤全N和P、K的有效量及全量均保持在一个相对较高的水平,在0~60 cm深度土壤全N、全P、全K、有效P和速效K含量均值均达到最高,分别为1.38 g/kg、0.34 g/kg、32.75 g/kg、33.10 mg/kg和118.85 mg/kg;(3) 不同林分密度、不同土层土壤有机碳含量、碳密度与土壤全N及P、K的全量和有效量的相关显著性有差异,对整个土壤剖面而言,土壤有机碳含量及碳密度与土壤全N、全P、速效K均呈显著或极显著正相关;(4) 在本研究林分密度范围内,从林地土壤固碳的角度,建议将油松人工林的林分密度控制在1 104 株 / hm2。     

滇东石漠化伴生“红裸土”表层有机质含量与酸碱度关系分析

对滇东地区石漠化伴生"红裸土"典型发育地带的表层样品的有机质和酸碱度分析表明:"红裸土"表层有机质含量范围为0.60～38.5(g.kg-1),平均值为13.49(g.kg-1);酸碱度在4.20～5.72。不但"红裸土"表层有机质含量低,呈中强酸性,且"红裸土"表层土壤有机质含量与酸碱度成弱正相关。这一特征与同区域有植被覆盖下的表层土壤相反,与其他典型的喀斯特地区土壤表层有相似的变化规律。这些特征说明"红裸土"可能是形成石漠化过程的一个阶段。     

1999—2009年新疆能源消费碳排放的因素分解及实证研究

从影响因素角度用LMDI分解方法对新疆1999—2009年的碳排放进行研究。结果表明:能源结构和能源强度对新疆人均碳排放增长起抑制效应,且能源强度的抑制效应大于能源结构的抑制效应;产业规模和人口规模对新疆人均碳排放增长起拉动效应,且产业规模的拉动效应大于人口规模的拉动效应。能源强度和能源结构的抑制效应难以抵消由产业规模和人口规模拉动的新疆人均碳排放的增长。在实证研究结果的基础上提出了相应的政策建议。     

土壤有机物质对土壤介电常数的影响

土壤介电常数是开展微波土壤水分和冻融状态的监测的基础,也是植被和积雪的下垫面边界条件,然而目前已有的介电常数研究都没有对高有机质含量的土壤开展系统观测。本文将土壤中的自然有机物质分为腐殖质和植物性残留物两类。采用控制变量实验方法,通过测量5种不同有机质含量的东北黑土和加入不同比例毛白杨碎屑的扁都口草甸土,研究了腐殖质和植物性残留物的对土壤介电常数的影响。结果表明,腐殖质会降低干燥土壤的容重,从而发挥间接作用,使介电常数降低;而对于相同容重下观测的潮湿土壤,腐殖质含量较多的土壤介电常数更大。与Dobson模型的比较显示,在29℃室温下,腐殖质对25%重量含水量潮湿土壤实部的影响在±2左右,虚部能达到1。与腐殖质相比,植物性残留物对风干土壤和潮湿土壤的影响都十分明显。植物性残留物能有效地疏松土壤并代入植物组分的介电特征。当重量含水量为30%时,含毛白杨含量为20%的混合土壤比纯扁都口土壤在实部平均减小3—7左右,虚部减小 1—3左右。因此,根据实验观测以及和模型的比较,土壤中的有机物质会改变土壤介电性质,对微波遥感造成影响。     

降水中甲酸和乙酸研究综述

对大气降水中甲酸和乙酸的相关研究进行了综述。介绍了过去曾采用的研究降水样品中两种有机酸的处理和分析方法,以及目前最常用的实验室分析方法。对降水中两种有机酸的浓度范围、全球时空分布以及受影响因素等相关研究工作进行了系统归纳,并且结合理论计算说明了有机酸对降水酸度的影响是不可忽视的。介绍了历史研究工作中得出的降水中两种有机酸的来源,包括天然源、人为源和有机物的二次化学转化等,以及有机酸源研究对于开展其它降水有机酸工作的研究意义。     

清洁发展机制（CDM）造林再造林项目碳汇成本研究——以CDM广西珠江流域治理再造林项目为例

以清洁发展机制（CDM）广西珠江流域治理再造林项目为例,对项目及其5种造林模式临时核证减排量（temporary certified emission reduction,缩写为tCER）和长期核证减排量（long-term certified emission reduction,缩写为lCER）成本的动态变化进行了初步研究。结果表明：从项目期初到期末,整个项目及5种造林模式人工林的tCER成本均逐渐降低,其中项目成本由第一承诺期末的40.33 ￥/t CO₂降至最后承诺期末的13.34 ￥/t CO₂;lCER成本先降低后升高,在第一承诺期末均降至最小值,项目成本由第一承诺期末的40.33 ￥/t CO₂增加至最后承诺期末的105.27 ￥/t CO₂;各造林模式tCER和lCER成本均以枫香+杉木、枫香+马尾松较高,马尾松+荷木、马尾松+栎类较低,桉树最低;贴现率对项目tCER和lCER、桉树tCER、枫香+杉木lCER成本影响均较大,而对马尾松+栎类tCER和lCER成本影响均较小;对桉树一个轮伐期内的tCER成本进行了敏感性分析,单位面积碳贮量的变化对其影响较大;考虑木材收益时,项目期末tCER净现值为13.11 ￥/t CO₂,从中反映了该CDM项目实施是可行的。     

中国黑碳气溶胶分布特征与辐射强迫的模拟研究

利用区域气候模式RegCM3模拟2000年我国黑碳气溶胶的分布特征和辐射强迫。结果表明,黑碳气溶胶主要分布在我国黄河以南、青藏高原以东的广大区域,柱含量由南向北递减;柱含量最大值在0.6mg／m^2以上,出现在中南、四川盆地、湖南、贵州、广西、广东西部和云南南部等地区;青藏高原南侧黑碳气溶胶次高值区的存在,反映了气溶胶的跨国界输送并影响区域气候的特点。黑碳气溶胶的大气顶辐射强迫介于0.1—0.8w／m^2之间,地表辐射强迫介于-0.1— -2.0W／m^2之间,两者分布特征与柱含量分布特征基本一致。同柱含量相似,黑碳气溶胶大气顸辐射强迫和地表辐射强迫也有明显的季节性变化,春季最大,秋、冬季次之,夏季最小。     

Modeling Methane Emissions from Paddy Rice Fields under Elevated Atmospheric Carbon Dioxide Conditions

Methane(CH4 ) emissions from paddy rice fields substantially contribute to the dramatic increase of this greenhouse gas in the atmosphere.Due to great concern about climate change,it is necessary to predict the effects of the dramatic increase in atmospheric carbon dioxide(CO2 ) on CH4 emissions from paddy rice fields.CH4MOD 1.0 is the most widely validated model for simulating CH4 emissions from paddy rice fields exposed to ambient CO2(hereinafter referred to as aCO2 ).We upgraded the model to CH4MOD 2.0 b...     

Composition and major sources of organic compounds in urban aerosols

Total suspended particles (TSP), collected during June 2002 to July 2003 in Guangzhou, a typical economically developed city in South China, were analyzed for the organic compound compositions using gas chromatography–mass spectrometry (GC/MS). Over 140 organic compounds were detected in the aerosols and grouped into different classes including n-alkanes, hopanoids, polycyclic aromatic hydrocarbons, alkanols, fatty acids, dicarboxylic acids excluding oxalic acid, polyols/polyacids, lignin products, phytosterols, phthalates and water-soluble sugars. The total amounts of the identified organic compounds including unresolved complex mixture (UCM) ranged from 3112 ng/m³ in spring to 5116 ng/m³ in winter, comprising on seasonal average 2.8% of TSP. Primary organic compounds peaked in winter although there are no heating systems burning fuels in Guangzhou. The highest saccharide levels occurred in fall due to agricultural activities. This study demonstrated that utilization of fossil fuels, biomass burning, soil resuspension and plastic/refuse burning are the major contributors to the identified organic compounds in the urban atmosphere of South China.     

Chemical Characteristics of Carbonaceous Aerosols During Dust Storms over Xi＇an in China

Characterization of carbonaceous aerosols including CC (carbonate carbon), OC (organic carbon), and EC (elemental carbon) were investigated at Xi'an, China, near Asian dust source regions in spring 2002. OC varied between 8.2 and 63.7 μg m-3, while EC ranged between 2.4 and 17.2 μ m-3 during the observation period. OC variations followed a similar pattern to EC and the correlation coeflcient between OC and EC is 0.89 (n=31). The average percentage of total carbon (TC, sum of CC, OC, and EC) in PM2.5 during dust storm (DS) events was 13.6%, which is lower than that during non-dust storm (NDS) periods (22.7%). CC, OC, and EC accounted for 12.9%, 70.7%, and 16.4% of TC during DS events, respectively. The average ratio of OC/EC was 5.0 in DS events and 3.3 in NDS periods. The OC-EC correlation (R2=0.76, n=6) was good in DS events, while it was stronger (R2=0.90, n=25) in NDS periods. The percentage of water-soluble OC (WSOC) in TC accounted for 15.7%, and varied between 13.3% and 22.3% during DS events. The distribution of eight carbon fractions indicated that local emissions such as motor vehicle exhaust were the dominant contributors to carbonaceous particles. During DS events, soil dust dominated the chemical composition, contributing 69% to the PM2.5 mass, followed by organic matter (12.8%), sulfate (4%), EC (2.2%), and chloride (1.6%). Consequently, CC was mainly entrained by Asian dust. However, even in the atmosphere near Asian dust source regions, OC and EC in atmospheric dust were controlled by local emission rather than the transport of Asian dust.