Numerical Simulation Study on the Impacts of Tropospheric O3 and CO2 Concentration Changes on Winter Wheat.Part I: Model Description

Ozone is well documented as the air pollutant most damaging to agricultural crops and other plants.It is reported that tropospheric O3 concentration increases rapidly in recent 20 years. Evaluating and predicting impacts of ozone concentration changes on crops are drawing great attention in the scientific community. In China, main study method about this filed is controlled experiments, for example, Open Top Chambers. But numerical simulation study about impacts of ozone on crops with crop model was developed slowly, what is more, the study about combined impacts of ozone and carbon dioxide has not been reported.The improved agroecosystem model is presented to evaluate simultaneously impacts of tropospheric O3 and CO2 concentration changes on crops in the paper by integrating algorithms about impacts of ozone on photosynthesis with an existing agroecosystem biogeochemical model (named as DNDC). The main physiological processes of crop growth (phenology, leaf area index, photosynthesis, respiration, assimilated allocation and so on) in the former DNDC are kept. The algorithms about impacts of ozone on photosynthesis and winter wheat leaf are added in the modified DNDC model in order to reveal impacts of ozone and carbon dioxide on growth, development, and yield formation of winter wheat by coupling the simulation about impacts of carbon dioxide on photosynthesis of winter wheat which exists in the former DNDC. In the paper, firstly assimilate allocation algorithms and some genetic parameters (such as daily thermal time of every development stage) were modified in order that DNDC can be applicable in North China. Secondly impacts of ozone on crops were simulated with two different methods-one was impacts of ozone on light use efficiency , and the other was direct effects of ozone on leaves photosynthesis. The latter simulated results are closer to experiment measurements through comparing their simulating results. At last the method of direct impacts of ozone on leaf growth is adopted and the coe cients about impacts of ozone on leaf growth and death are ascertained. Effects of climate changes, increasing ozone, and carbon dioxide concentration on agroecosystem are tried to be simulated numerically in the study which is considered to be advanced and credible.     

沂水县龙泉站金矿地质特征及找矿前景

沂水县龙泉站金矿位于沂沭断裂带中段,受沂水汤头断裂控制。金矿体产于沂水汤头断裂主裂面下盘的糜棱岩化碎裂岩和花岗质碎裂岩中,已初步圈出6个金矿体。此外,在牛家小河、石崖官庄、郑家庄地区也发现有较好的矿化显示。通过综合研究,认为该地区金矿化与韧性剪切构造带关系密切,且具有较好的找矿前景。     

The birth of the Paratethys during the Early Oligocene: From Tethys to an ancient Black Sea analogue?

Deeper water black shales, overlain by coccolith-bearing marlstones representing the incipient Paratethys (example: Early Oligocene; Austrian Molasse Basin), have sedimentary characteristics similar to those of the Holocene Black Sea since 7500 years bp. Framboid pyrite size, biomarker and C–N-isotope data additionally indicate that isolation of the Paratethys resulted in Black Sea-type characteristics during nannoplankton zone NP 23.In contrast to the estuarine circulation across the Bosphorus since 7500 years bp, marine conditions prevailed in the incipient Paratethys during NP 21/22. Nitrogen was fixed and low organic carbon accumulation rates prevailed. In both settings a vertical density water-column stratification was accompanied by photic zone anoxia, and by anaerobic methane oxidation in the Paratethys. In the Paratethys increased run off, starting in NP 22, led to estuarine circulation during NP 23. During this period cyclic blooms of calcareous nannoplankton resulted in high calcite accumulation rates which diluted the coeval clay sedimentation. Similar sedimentary features in the Black Sea and the Paratethys during the earliest Oligocene are result from opposite paleoceanographic developments, both leading to estuarine circulation patterns. In the Black Sea, permanent photic zone anoxic conditions were established 7500 years bp in response to the first invasion of saline Mediterranean waters into the former freshwater lake. In contrast, brackish surface water in the Paratethys resulted from nutrient-rich freshwater diluting the marine water body.     

川北甘南地区三叠纪岩相古地理与成矿

川北甘南地区三叠纪时期沉积的岩相古地理明显地划分为早一中三叠世早期（安尼期），扬子大陆西缘台地相碳酸盐岩沉积；和中三叠世晚期（拉丁期）到晚三叠世中期（诺利期），特提斯边缘裂陷海槽浊流相碎屑岩沉积两个迥然不同发展阶段。金和伴生多金属组分来自边缘古陆，而边缘台地相白云岩化阶段和海湾相粉砂－粘土矿物沉积阶段是促成金矿初始富集的最佳环境。     

Physico-chemical Speciation of Lead in South San Francisco Bay

The speciation of lead at a site in the South San Francisco Bay was determined using a combination of physical size fractionation and electrochemical analyses. The ‘ total dissolvable ’ Pb was 8·1 nM from analysis of an acidified unfiltered sample. The ‘ dissolved ’ Pb was equal to 0·20 nM (41 ng l⁻¹), only 2·5% of the ‘ total dissolvable ’ Pb. The difference yielded the ‘ particulate ’ Pb equal to 7·9 nM (1·6 μg l⁻¹). Results from crossflow ultrafiltration indicated that almost all (0·19 nM) of the dissolved Pb was ‘ in solution ’ [<10K nominal molecular weight (MW)] and that colloidal Pb (10K MW to 0·2 μm)accounted for onlyc. 1% of the dissolved Pb at this station. This small concentration (0·01 nM) of colloidal Pb may be attributed to the low amount of organic carbon associated with colloid size fraction as determined by dissolved organic carbon analyses.The chemical speciation of lead was determined in the dissolved sample and ultrafiltered sub-sample. Differential pulse anodic stripping voltammetry (DPASV) on a thin mercury film (TMF) rotating glassy carbon disk electrode (RGCDE) was used to distinguish the kinetically labile inorganic species (Pb′) from the Pb-chelated by organic ligands (PbL_i). Lead titration results were similar for both samples revealing that Pb′, PbL_iand excess unbound ligands were present primarily in the ultrafiltrate, rather than in the colloidal phase. The titration data can be interpreted as dissolved Pb being influenced by two classes of Pb-binding ligands. In the dissolved sample, the concentration of the stronger class of ligands was [L₁]=0·89±0·35 nM, with a conditional stability constant ofK^cond_L1,Pb′=3±1×10¹⁰M⁻¹. The weaker class was [L₂]=12·8±1·9 nM, withK^cond_L1,Pb′=4±1×10⁸ M⁻¹. The presence of these ligands, in excess of the dissolved Pb, resulted in [Pb′]=7±2 pM and [Pb²⁺]=0·3 pM (62 pg l⁻¹). While less than 2·4% of the ambient Pb was ‘ in solution ’, it existed chiefly in the form of organic complexes with [PbL₁]=0·15 nM and [PbL₂]=0·03 nM. More significantly, there were large concentrations of unchelated Pb-binding ligands, (L_i′), available to buffer the free Pb²⁺concentration in the event of perturbations in dissolved Pb.     

海原西华山地区金矿化的地球化学特征及成因

本文通过微量元素、硫同位素、氧同位素及矿物流体包裹体研究等方法首次对宁夏海原西华山地区金矿化的地球化学特征进行了探讨，提出了地层、构造及岩浆活动三者联合控矿的成因认识。这一认识无疑对宁夏为数不多的有色金属矿化区之一──宁夏海原西华山地区的金矿的找矿预测具有实际意义。     

高挂山—牛头寨地区小型环形影象构造分析及其找矿意义

高挂山—牛头寨地区,通过大比例尺航片解译,发现6个大小不等的小型环形影象信息。这些环形影象与岩浆活动、已知矿床、矿化点、重砂异常、物化探异常等的分布有着内在的联系。为预测找矿远景区和找隐伏矿床提供了影象依据。     

大青山地区金地球化学特征

大青山地区出露地层主要是侏罗系中统兰旗组安山岩、安山质角砾熔岩、凝灰岩等;侵入岩为晚侏罗世二长花岗岩;断裂发育,岩石蚀变强烈。金地球化学特征表明,金主要富集在侏罗系中统兰旗组火山岩中。金的原生晕、次生晕异常特征和分布表明,破碎蚀变岩带就是金矿化蚀变带。通过野外地质调查已在三道盘—马家窝铺的安山岩和二长花岗岩中发现了5条金矿化带和29条金银矿脉。实践证明,在大青山地区进行金矿普查运用地球化学方法是有效的。     

DISTRIBUTIONS OF TOTAL, INORGANIC AND ORGANIC PHOSPHORUS IN THE SEDIMENTS NEAR THE HUANGHE RIVER ESTUARY

For some hundred surface sediment samples from five cores taken in two cruises near the Huanghe River Estuary, total phosphorus (TP (.inorganic phosphorus (IP (and organic phosphorus (OP)were determined.On the average, 527×10-6, 455×10~6 and 72×10-6 were found for TP,IP and OP for the surface sediments taken in the two cruises. The distribution of OP and IP was controlled by the sample particle size: OP content increased with the decreasing of the sample particle size, while the maximal value of IP was found in the silt fraction due to the existence of apatite in our samples. Vertical distributions reflected well the channel change of the Huanghe River. Results from the multiple regressions between the three forms of phosphorus and the percentages of different particle size agreed well with the analytical data.     

Transfeer of organic pollutants during sewage-seawater mixing

The transfer processes of organic pollutants during sewage-seawater mixing were simulated in three different mixing systems. The release rate of organic matter from sewage particles to seawater was found to be about 0.02–0.04 d⁻¹. The release processes can be simulated by an exchange-equilibrium kinetic model. Degradation of COD was observed in all three mixing systems and can be described by a first order kinetic equation. The degradation rate constantk ranged between 0.04 and 0.07 d⁻¹. These results have provided important parameters for estimation of environmental capacity.