云南金厂金矿床蚀变超基性岩体与金的成矿作用

金矿化与蚀变超基性岩体的空间关系、矿化特征、蚀变超基性岩体、成矿流体、微量元素、硫同位素组成、表明金主要来源于金厂蛇纹石化、滑石化、碳酸盐化超基性岩体。在岩体蚀变过程中,在碱性相对还原的介质条件下,金主要以硫络合物的形式进入成矿溶液,在Ｔ、Ｐ、ＰＨ、Ｅｈ等物理化学参数发生变化的条件下沉淀。     

Hydrocarbon Generating Potential of Mineral—Bituminous Matrix in Source Rocks

Mineral-bituminous matrix(MBM) makes up a major part of source rocks,but its potential in hydrocarbon generation is uncertain,Mineral and organic (Maceral and kerogen) compositions,organic maturity and fluorescence of MBM are studied based on source rock samples from eastern Jiuquan(Jiudong)Basin.The results show that MBM is dominated by inorganic minerals and among the small percentage of organic components those of secondary origins are predominant over the primary species.This strongly indicates that the significance of MBM in hydrocarbon generation is limited.     

Silicon Isotope Geochemistry of Micro—Fine Disseminated Gold Deposits in SW Guizhou and NW Guangxi,China

Quartz was studied with respect to its silicon isotopic composition and cathodoluminescence in micro-fine disseminated gold deposits in SW Guizhou and NW Guangxi.The results showed that quartz in wall rocks.ores and that in association with hydrothermal silicification are distinctive in silicon isotopes and cathodoluminescence characters.Quartz in association with primary silicification is non-luminescent while that in wall rocks and associated with secondary silicification exhibits striking luminescence.Based on the dynamic fractionation of silicon isotopes,it is suggested that the mineralization was accompanied by rapid transport of aprimary siliceous fluid along the major deep fault system into subordinate faults before ore components deposited in favorable strata via penetration and metasomatism.Therefore,a deep origin is implicit for gold deposits of this type.     

Laboratory sulfurisation of the marine microalga Nannochloropsis salina

To understand more fully the mode of preservation of organic matter in marine sediments, laboratory sulfurisation of intact cells of the cultured microalga Nannochloropsis salina was performed using inorganic polysulfides in seawater at 50°C. Solvent extractable and non-extractable materials were analysed by GC–MS and Py–GC–MS, respectively, to study the incorporation of sulfur into the microalgal organic matter. No GC-amenable sulfur-containing compounds were found in the extracts apart from some minor thiophenes with a phytanyl carbon skeleton. The residue after extraction and hydrolysis contained abundant macromolecular sulfur-containing moieties as revealed by the presence of dominant C₂₈–C₃₂ thiols, thiophenes, thianes and thiolanes in the flash pyrolysates. These products are thought to be formed from moieties derived from sulfurisation of C₂₈–C₃₂ diols and alkenols, characteristic lipids of N. salina. C₁–C₂ alkylated thiophenes were also found in the pyrolysates and probably result from moieties formed upon sulfurisation of carbohydrates. The highly resistant biomacromolecule (algaenan) synthesised by N. salina remains unaffected by sulfurisation. The non-hydrolysable residue isolated from the sulfurised N. salina thus comprises algaenan and (poly)sulfide-bound long alkyl chains. The sulfurisation experiments show that both selective preservation of algaenans and lipid and carbohydrate “vulcanisation” can be involved in the preservation of algal organic matter in marine environments.     

Speleothems as high-resolution paleoenvironment archives: Records from northeastern China

The isotopic compositions of oxygen and carbon and trace concentrations of magnesium and strontium in speleothems formed in limestone caves respond to climate changes outside the caves. Measurements of these properties on a stalagmite from Shihua Cave near Beijing, China, allowed reconstruction of the regional changes in precipitation, temperature and nature of vegetation. Over the last ∼ 500 years, there were fourteen precipitation cycles with a periodicity of 30–40 years, which may well reflect fluctuations in the strength of the East Asian summer monsoons reaching northeastern China. Relative to the mean temperature of this time interval, the period 1620–1900 AD was cold and periods 1520–1620 and 1900–1994 were warm. Over the last ∼ 3000-years, about eight wet/cool-dry/warm climatic cycles of 300–400 years duration occurred, the latest wet/cool half cycle corresponding to the Little Ice Age. The δ¹³C record registers the anthropogenic activities of fossil fuel CO₂ combustion in recent decades and regional deforestation between 13 and 16 centuries when Beijing was bustling with palatial constructions and being developed into the world’s most populated city.     

Metallogenetic characteristics of an unique uranium-tungsten mineralization zone

A polymetallic zone dominated by U-W mineralization was found in Northeast Guangxi. Distributed along the east contact zone of a complex granite mass, it extends for about 100 km in length, with more than fifty deposits and prospects embraced. The deposits show a wide range of genetic types, related to the granite, from magmatic (including pegmatite and skarn deposits) through hydrothermal mineralizations (hypo-, meso- and epithermal) all the way to tin placers, constituting a very intact metallogenetic series of granites. The epithermal U-W deposits are considered as a new type for their unique geological and geochemical characters, such as the paragenesis of U and W and the large time gap (> 40 Ma) between ore and granite. This project was financially supported by the Open Lab. of Ore Deposit Geochemistry, Chinese Academy of Sciences.     

北淮阳盆岭带的构造演化与铀成矿

北淮阳盆岭构造带是大别造山带的重要组成部分。佛子岭岩群代表了早古生代扬子地块北缘大别古岛弧弧前海盆的火山沉积建造,在加里东运动陆块对接过程中变形变质。石炭系梅山群具磨拉石建造特征。在华力西印支期陆内俯冲褶皱带的基础上,燕山期沿桐柏桐城断裂伸展北移,近东西向断陷盆地发育,形成盆岭构造景观。南侧大别山强烈隆升,铸就了现今大别山变质核杂岩构造格局。中生代岩浆活动是区内重要铀源,具有成矿潜力的地质体是响洪甸正长岩体和北带粗面质火山碎屑岩     

秦岭地区铅锌矿成矿浅析

秦岭横亘中国中部,地跨七省,铅锌矿产资源成矿规律明显。迄今已探明３３个矿床,可划分八个成因类型,包括矽卡岩型,热液型,石英脉型,构造蚀变岩型,沉积型,火山沉积型,火山岩型及沉积再造型。     

有机酸对高岭石形成影响的模拟试验研究

利用富里酸、胡敏酸和盐酸与天然矿物－长石、蒙脱石和云母在常温常压下进行反应,探讨矿物溶解及高岭石形成机理。实验表明富里酸对这些矿物具有较大的溶解能力,其原因是由于形成了具有较大溶解度和活动性的有机硅和有机铝复合体。在中性－碱性条件下有利于有机硅复合体的形成,酸性条件下有利于有机铝复合体的形成。在富里酸作用下,蒙脱石和云母分别在４个月和８个月有少量转化成高岭石,说明层状硅酸盐矿物比架状硅酸盐矿物更易     

论氢化物迁移成矿机制──兼论钒钛磁铁矿成矿的化学模式

论述了氢化物的形成条件及其物理化学特性。探讨了岩浆中钛、铁、钒、磷元素的迁移富集机制。建立了钒钛磁铁矿成矿的化学模式。