Formation Mechanism of High Quality Marine Source Rocks—Coupled Control Mechanism of Geological Environment and Organism Evolution

High quality marine source rock (HQMSR) is the key prerequisite for medium to large hydrocarbon accumulations. However, the forming mechanism remains unclear. On the basis of the in-vestigation for the geodynamic setting of the Middle-Upper Yangtze during the Early Cambrian in dif-ferent spatial scales and the analysis of trace elements, the main controlling factors of the development of high quality marine source rock are discussed, with specific consideration of the burial rate of the organic matter. The ...     

广东大降坪硫(铅锌)矿床岩浆热液叠加作用——来自闪锌矿Rb-Sr年龄及硫同位素的证据

广东大降坪硫(铅锌)矿床位于与岩浆作用有关的大绀山多金属矿田的中部,主矿体为赋存在震旦纪变质岩中的层状、透镜状黄铁矿矿体,最近在两个不同产状的黄铁矿矿体下部又新发现了脉状及层状铅锌矿体。文章通过对铅锌矿体的年龄及硫同位素研究,探讨其与主矿体的成因关系,获得了脉状铅锌矿体中闪锌矿的Rb-Sr等时线年龄为(88.5±3.9)Ma,即晚白垩世,与上部黄铁矿矿体的年龄(约630 Ma)相差较大,而与整个大绀山多金属矿田的成矿作用时限一致。三种不同产状的矿体硫同位素组成差异明显:层状黄铁矿矿体富集硫的轻同位素(δ34S=-10.90‰~-25.55‰),且与围岩的硫同位素范围一致,说明硫来自生物的细菌还原硫;透镜状黄铁矿矿体δ34S组成范围较宽(-9.38‰~22.69‰),具多源性硫的特征;铅锌矿体的δ34S在-7.1‰~6.4‰之间变化,硫可能来自深源岩浆,并受围岩成分混染。多方面的证据表明,大降坪黄铁矿矿体下部的铅锌矿体形成于晚白垩世的岩浆热液成矿作用,透镜状黄铁矿矿体受到岩浆热液的叠加。     

高硒环境样品中硒的形态分析方法

在恩施富硒碳质岩和土壤样品中硒矿物学研究的基础上,提出了硒连续化学提取的改进方案。化学操作上定义为7个连续步骤:水溶态(MQ水提取)、可交换态(0.1 mol/L的K2HPO4 KH2PO4,pH=7.0)、有机结合态(0.1 mol/L NaOH)、元素态(1 mol/L Na2SO3溶液)、酸溶性提取态(15%CH3CO2H溶液)、硫化物/硒化物态(1 mol/L CrCl2 HCl溶液)和残渣态硒(HNO3 HF H2O2混合消化液)。使用HG-AFS法检测了各结合态中的硒形态和总硒,上述流程提取硒加和与总硒间显著一致,平均回收率为99.2%,符合平行样品间变异系数低于10%的精度要求。该方法简单易行,能够准确地揭示富硒地质样品中硒的形态信息。     

Environmental Assessments of Trace Metals in Sediments from Dongting Lake, Central China

INTRODUCTIONFresh water lakes are one of the planet’s mosti mportant freshwater resources.They support life invarious forms,develop tourism and provide uniquerecreational opportunities.It is also a good source ofthe provision of drinking-water for local communi-ties.Studies on trace elements in rivers,lakes,andsedi ments(Zhou et al.,2004;Gray et al.,2000;Grosheva et al.,2000;Klavins et al.,2000;Aucoinet al.,1999;Bortoli et al.,1998;Elbaz-Poulichet etal.,1996;Johansson et al.,1995;F r…     

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.     

甚低频电磁法在哈尔楚鲁图银-多金属矿区控矿构造特征分析中的应用

以哈尔楚鲁图银-多金属矿床为例,阐述了甚低频电磁法(VLF-EM)在覆盖区控矿构造特征分析及隐伏矿体找矿预测中的应用。VLF-EM测量和地质解释成果表明:矿区内断裂构造主要有NWW、NNW及NE三个方向。其中,NNW和NWW向断裂为主要含矿构造,二者构成菱形网格状或雁列式控矿构造基本格局,断裂交汇地段为形成较大矿体的有利地段;NE向断裂未见工业矿体产出,对矿体起到错断和破坏作用。     

胃肠酸度下中药及补铁制剂中铁活性的影响研究

在人体胃肠液的酸度条件下,采用正辛醇-水分配体系模拟药物在人体肠胃中的分配情况,研究了中药和补铁制剂中铁的形态及其在人体内的吸收情况,并探讨了中药不同比例的配伍、胃肠酸度及还原性物质的存在对水溶态铁和醇溶态铁的影响。结果表明,药物溶液中的铁形态与药物本身特性和配伍情况有关,酸度及配伍对药物中铁的溶出率和溶液中铁的形态有较大影响,人体对铁的吸收与胃肠酸度和还原性物质的存在有关。     

华北地台北缘花岗岩—绿岩型金矿田及盲矿体的找矿模型

花岗岩—绿岩型金矿田的找矿模型地质上是富镁铁质绿岩、韧性剪切带与重熔岩体的三体一位;物探上位于航磁高背景场的负磁异常带边缘,矿田晕分散流异常规模大、强度高,有明显的浓集中心。隐伏矿床、盲矿体的找矿模型地质上是韧性剪切带、退变质带及脆性断裂带的三体一位;物探上呈现高极化率、低电阻、位于磁异常边缘的“一高一低一边”模型;化探原生晕上呈现As、sb、F、Ag、Bi、W的找矿模型。     

大厂矿田成矿分带特征及其控制机理研究

大厂锡多金属矿田由西向东分为三个带,东、西部为锡石-硫化物矿带,中部为矽卡岩型锌铜矿带.三个矿带在水平方向上具有明显的不对称,在矿物组合和矿体产出形态上相差也较大,通过对构造形态的空间分析以及成矿流体物理化学性质的比较,阐明大厂矿田成矿分带特征,并解释了不同矿带在垂向上的矿体形态差异.     

陕西青山金矿床黄铁矿的标型特征研究及矿床成因探讨

陕西青山微细浸染型金矿床中的主要矿石矿物黄铁矿具有标型意义,研究表明,富金矿段的黄铁矿具有颜色暗黄-灰黄、颗粒细小破碎、晶形差,为五角十二面体和复杂聚形、亏硫与铁的特点。矿区矿源层为含炭热水沉积岩层组成的黑色岩系,具有热水沉积成矿预富集-韧脆性构造叠加-大气降水为主的含矿热液改造的类卡林型金矿床的成矿特点,富金细粒黄铁矿是地下热卤水与大气降水热液两种流体混合与沸腾使物理化学条件瞬变的产物。