小秦岭金矿成矿流体的性质及地质意义

小秦岭金矿成矿流体的性质及地质意义王祖伟，周永章（中国科学院广州地球化学研究所，广州５１０６４０）关键词成矿流体，金矿床，小秦岭小秦岭金矿是我国主要的黄金产地。有关主要矿床类型石英脉型金矿化成矿流体包裹体研究积累了丰富的资料，次要类型蚀变岩型金矿化流...     

Characteristics and origin of sediment-hosted disseminated gold deposits: a review

Sediment-hosted disseminated gold (SHDG) deposits comprise a major portion of the gold production and reserves in the US. Although presently known to be common only in western North America, SHDG deposits are a significant source of world gold production. These deposits are characterized by extremely fine-grained disseminated gold, hosted primarily by arsenian pyrite. Other metals show very little enrichment although in addition to As, anomalous concentrations of elements such as Sb, Hg, Tl and Ba are utilized as exploration tools. The host rocks are dominantly silty carbonates, but ore concentrations are also present in siliceous and silicified rocks as well as intrusive rocks. Alteration consists of decarbonatization, silicification (jasperoid formation) and argillization, which are arranged both spatially and temporally in that order. Argillic alteration is zoned from kaolinite-dominated cores to sericite-dominated margins. The deposits commonly exhibit significant structural (faults) and stratigraphic (composition/permeability) controls. Until the last few years, SHDG deposits were considered as near-surface, epithermal type deposits in origin. Because of their fine-grained nature and the lack of macroscopic features such as veins, it has proven quite difficult to extract geochemical data that are clearly related to their genesis. However, fluid inclusion data indicate pressures corresponding to depths of 2–4 km under lithostatic conditions. Temperatures are constrained by fluid inclusions and phase equilibria to near 225°C. Stable isotope data from alteration minerals and fluid inclusions indicate that the ore fluids were dominated by meteoric waters, some of which had clearly exchanged oxygen with wallrocks during their passage through the crust. Although the data vary, most ore fluids probably had δD values near −150‰ and δ¹⁸O values ranging from −10 to +5‰. Sulfur isotope values reported from SHDG deposits span a wide range, from −30 to +20‰ (sulfides) and 0 to >45‰ (sulfates). Ore-related sulfides (pyrite, realgar) fall at the upper end of the range reported for sulfides. The alteration and mineral assemblage indicate the ore fluids were probably near neutral and gold was likely carried as a bisulfide complex. The depositional mechanism(s) probably included mixing, cooling and oxidation. These mechanisms are consistent with the observed alteration features, i.e. quartz precipitation, calcite dissolution and sericite-kaolinite coexistence. It also explains the presence of both siliceous ores containing native Au and sulfide ores containing Au in pyrite. The extreme variations in sulfur isotopes as seen at Post and fluid inclusion data from Carlin may be indicative of some phase separation (‘boiling’), but such relations have not been documented in other deposits and the importance of phase separation to gold deposition appears minimal.     

A Study on the Geological—Geochemical Dynamics of Hydrothermal Ore Deposition as Exemplified by the Muping—Rushan Gold Deposit Belt,Eastern Shandong,China

This paper presents a method of establishing a hydrothermal ore-forming reaction system.On the basis of the study of four typical hydrothermal deposits,the following conclusions concerning geochemical dynamic controlling during hydrothermal mineralization have been sions concerning geochemical dynaamic controlling during hydrothermal mineralization have been drawn:(1)The regional tectonic activities control the concentration and dispersion of elements in the ore-forming process in terms of their effects on the thermodynamic nature and conditions of the ore-forming reaction system.(2)During hydrothermal mineralization the activites of ore-bearing faults can be divideb into two stages:the brittle splitting stage and the brittle-tough tensing stage,which would create characteristically different geodynamic conditions for the geochemical thermodynamic ore-forming system.(3)The hydrothermal ore-forming reaaction system is an open dynamic system.At the brittle splitting stage the system was so strongly supersaturated and unequilibrated as to speed up and enhance the crystallization and differentiation of ore-forming fluids.And at the brittle-tough tensing stage,the ore-forming system was in a weak supersaturated state;with decreasing temperature and pressure the crystallization of oreforming material would show down,and it can be regarded as an equilibrated state.(4)In the lates stages of hydrothermal evolution,gold would be concentrated in the residual ore-forming solution.The pulsating fracture activite in this stage led to the crush of pyrite ore and it was then filled with gold-enriched solution,forming high-grage“fissure”gold ore.This ore-forming process could be called the coupling mechanism of ore formation.     

Metallogenic model of the copper deposit

The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide deposits. According to the geological background, the types of ore deposits and the mineralization, the metallogenic model of the copper deposits is discussed. It is pointed out that the ore-forming hydrothermal fluids came mainly from magmatic water and were related to the intermediate-acid intrusions, and that the formation of skarn arid massive sulphide deposits coincided with the mineralization of porphyry deposits. Project supported by Doctorate Foundation of the State Education Commission of China.     

关于侵入岩体中金矿床成因研究若干问题的讨论

各时代、不同类型侵入岩中的金矿床是金矿的主要类型。关于金矿床与岩体的成因关系目前尚存在不同的看法，但传统的岩浆热液成因观点仍居统治地位，其原因往往在于不少研究者把岩液热液成因当成了固定模式应用于具体矿床的研究，而不是建立在综合研究的基础之上。本文结合近年来金矿的研究进展，强调侵入岩中金矿床的研究的研究要综合考虑成岩成矿的时代与时差，成矿流体和成矿物质的来源等各方面因素。金矿床定年的进展研究表明，矿     

关于银山矿床成矿作用的几个问题——兼与《江西银山铜铅锌金银矿床》的作者商榷

银山多金属矿床是一个特大型火山—潜火山热液矿床,具有复杂的多期多阶段的成矿作用和有序的成矿分带。成矿作用主要为火山—潜火山热液作用,但在此之前,还经历了一期由韧脆性剪切带形成而引起的动力变质热液作用。根据矿体与3个旋回潜火山岩体的时空关系,火山—潜火山热液成矿作用又可分为两个成矿期和5个成矿阶段。矿床地质地球化学研究表明成矿作用在空间上具有定向迁移的特点,结合流体动力学计算机数值模拟认为定向迁移的根本原因是构造岩浆脉动和隐伏岩体形态产状。笔者认为,矿区深部可能有隐伏岩体,但对隐伏的斑岩铜矿床不应抱很大希望     

矿产开发与环境保护

通过国内多个矿区实例，较系统地叙述了矿产资源开发导致的生态环境破坏和污染状况。表明矿产开发中对环境污染的途径包括河流、土壤、等。最后简要介绍了国内、国外几种对采矿污染比较有效的防治措施。     

内蒙古铜矿床区域成矿特征初步研究

近年来，随着内蒙古周边地区铜矿的地质找矿不断取得重大突破，以及内蒙古铜矿勘查取得的一系列重要新进展，在内蒙古开展铜矿地质勘查工作已引起国内外地质学家的关注。笔者经综合研究地质构造、铜矿勘查及有关地球化学等新信息后，均显示出巨大的铜矿找矿潜力。从内蒙古自治区铜矿勘查史以及与邻区对比研究人手，研究总结了全区铜矿床及铜异常空间分布特征，划分出3个铜成矿区(带)，并进一步划分出铜矿床或异常密集区，初步提出了寻找大型及超大型铜矿床的找矿方向。     

南太行山闪长岩的SHRIMP锆石U-Pb年龄及岩石成因研究

南太行山符山和东冶角闪闪长岩岩体的精细SHRIMP锆石U-Pb定年和元素-同位素地球化学研究表明:符山角闪闪长岩体形成于126.7±1.1Ma,东冶角闪闪长岩体形成于125.9±0.9Ma,与区内基性侵入岩和北太行地区侵入杂岩具有相似的形成年龄,表明晚中生代(±130Ma左右)太行山地区经历了与华北陆块同期的重要构造岩浆事件。区内闪长质岩石SiO_2=54.84％～65.75％,MgO=1.31％～3.89％,K_2O Na_2O=6.53％～11.40％,mg值=0.36～0.58,(La/Yb)_(cn)=9.86～22.77,(Gd/Yb)_(cn)=1.51～2.00;Eu/Eu=1.00～1.23,以富集LREE、LILE元素和明显亏损Nb-Ta、Zr-Hf-Ti等高场强元素为特征。~(87)Sr/~(86)Sr(t)=0.705363～0.706165,ε_(Nd)(t)=-13.8～-16.8,源自于EMI型富集岩石圈地幔,可解释为新生地幔底侵物质熔融后经过结晶分异作用的产物。与华北克拉通内部其他地区一样,早白垩世南太行山地区处于软流圈上涌的岩石圈伸展构造背景。     

Geochemistry of ore-forming fluids and geological significance of the Kuoerzhenkuola gold field in Xinjiang, China

The Kuoerzhenkuola gold field (including the Kuo- erzhenkuola and the Buerkesidai gold deposits), lo- cated 68 km east of Jimunai County in northern Xing- jiang, China, is an important component of the Sawuer gold belt which is the eastward extending part of the Zarma-Sawur gold-copper belt in Kazakhstan. Some studies are concerned with the geology of the gold ores[1―3], the associated volcanic rocks[4], radiogenic isotope[5―8], and the ore-forming environment[8]. Most researchers inferr…