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61.
为了计算高温,高压和高密度流体的热力学性质,提出了一个具有19个参数的维里型状态方程,其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外,在已报道的pVT数据所覆盖的大部分超临界区域内,该方程均可适用。用该方程对H2O,CH4,H2,CO2,CO和O2等流体pVT关系的计算结果令人满意,其中pVT上限分别为:91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0.8%,最大偏差小于5.4%。 相似文献
62.
离散裂隙渗流方法与裂隙化渗透介质建模 总被引:4,自引:1,他引:4
流体渗流模拟的连续介质方法通常适用于多孔地质体,并不一定适用于裂隙岩体,由于裂隙分布及其特征与孔隙差异较大。若流体渗流主要受裂隙的控制,对于一定尺寸的裂隙岩体,多孔介质假设则较难刻划裂隙岩体的渗流特征。离散裂隙渗流方法不但可直接用于模拟裂隙岩体非均质性和各向异性等渗流特征,而且可用其确定所研究的裂隙岩体典型单元体及其水力传导(渗透)张量大小。主要讨论了以下问题:(1)饱和裂隙介质中一般的离散流体渗流模拟;(2)裂隙岩体中的REV(典型单元体)及其水力传导(渗透)张量的确定;(3)利用离散裂隙网络流体渗流模型研究裂隙方向几何参数对水力传导系数和REV的影响;(4)在二维和三维离散裂隙流体渗流模型中对区域大裂隙和局部小裂隙的处理方法。调查结果显示离散裂隙流体渗流数学模型可用来评价不同尺度上的裂隙岩体的水力特征,以及裂隙方向对裂隙化岩体的水力特征有着不可忽视的影响。同时,局部小裂隙、区域大裂隙应当区别对待,以便据其所起的作用及水力特征,建立裂隙化岩体相应的流体渗流模型。 相似文献
63.
64.
川滇密西西比河谷型铅锌矿床成矿流体来源研究:流体Na-Cl-Br体系的证据 总被引:11,自引:1,他引:11
应用流体包裹体滤液分析方法,测定了川滇7个MVT铅锌矿床成矿流体的Na,Cl,Br含量,结果表明成矿流体的x(Na/Br)和x(Cl/Br)的平均值分别为185和73,并与高度蒸发浓缩的残留海水的x(Na/Br)和x(Cl/Br)相近。成矿流体的Na,Cl含量呈正相关,在lgNa-lgCl图解中呈线性分布。根据这些事实以及矿床地质特征,认为原始成矿卤水起源于蒸发浓缩的残留海水,原始含矿卤水与富含有机质的大气降水混合导致矿质沉淀而成矿。 相似文献
65.
四川攀西地区具有特定的地质条件,区域地球化学特征、有利的成矿环境和已发现的银矿床点,都证明区内具有很好的成矿地质条件,寻找大型独立银矿很有前景。主攻内生型和沉积变质型银矿床是今后工作的重点。 相似文献
66.
The composition of quartz inclusions and trace elements in ore indicate that gold-bearing fluid in the Xiadian gold deposit,Shandong Province,stemmed from both mantle and magma,belonging to a composite origin.Based on theoretical analysis and high temperature and high pressure experimental studies,gold-bearing fluid initiative localization mechanism and the forming environment of ore-host rocks are discussed in the present paper.The composite fluid extracted gold from rocks because of its expanding and injecting forces and injecting forces and flew through ore-conducive structures,leading to the breakup of rocks.The generation of ore-host faults and the precipitation of gold-bearing fluid occurred almost simultaneously.This study provides fur-ther information about the relationships between gold ore veins and basic-ultrabasic vein rocks and intermediate vein rocks,the spatial distribution of gold ore veins and the rules governing the migration of ore fluids. 相似文献
67.
Constraints on the application of carbon isotope thermometry in high- to ultrahigh-temperature metamorphic terranes 总被引:7,自引:0,他引:7
Nine marble horizons from the granulite facies terrane of southern India were examined in detail for stable carbon and oxygen isotopes in calcite and carbon isotopes in graphite. The marbles in Trivandrum Block show coupled lowering of δ13C and δ18O values in calcite and heterogeneous single crystal δ13C values (? 1 to ? 10‰) for graphite indicating varying carbon isotope fractionation between calcite and graphite, despite the granulite facies regional metamorphic conditions. The stable isotope patterns suggest alteration of δ13C and δ18O values in marbles by infiltration of low δ13C–δ18O‐bearing fluids, the extent of alteration being a direct function of the fluid‐rock ratio. The carbon isotope zonation preserved in graphite suggests that the graphite crystals precipitated/recrystallized in the presence of an externally derived CO2‐rich fluid, and that the infiltration had occurred under high temperature and low fO2 conditions during metamorphism. The onset of graphite precipitation resulted in a depletion of the carbon isotope values of the remaining fluid+calcite carbon reservoir, following a Rayleigh‐type distillation process within fluid‐rich pockets/pathways in marbles resulting in the observed zonation. The results suggest that calcite–graphite thermometry cannot be applied in marbles that are affected by external carbonic fluid infiltration. However, marble horizons in the Madurai Block, where the effect of fluid infiltration is not detected, record clear imprints of ultrahigh temperature metamorphism (800–1000 °C), with fractionations reaching <2‰. Zonation studies on graphite show a nominal rimward lowering δ13C on the order of 1 to 2‰. The zonation carries the imprint of fluid deficient/absent UHT metamorphism. Commonly, calculated core temperatures are > 1000 °C and would be consistent with UHT metamorphism. 相似文献
68.
Ahmed Barakat Christian Marignac Marie-Christine Boiron Mohamed Bouabdelli 《Comptes Rendus Geoscience》2002,334(1):35-41
The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41 相似文献
69.
Determining gaseous composition of fluid inclusions with quadrupole mass spectrometer 总被引:3,自引:0,他引:3
Quadrupole mass spectrometer (QMS) is an instrument for effectively determining gaseous composition of fluid inclusion. The
gaseous component is extracted from inclusions with thermal decrepitation method and then determined with the sensitive QMS
instrument. The method is characterized by high sensitivity and high accuracy with the relative standard deviation (RSD,n=6) of less than 3%. It has been successfully used for analyzing fluid inclusions. The analytical results meet the requirement
of geological study. 相似文献
70.