辽宁省凤城市四道门沟铁矿床地质特征及成因分析

辽宁省凤城市四道门沟铁矿床位于辽东铁、硼成矿带内。以下元古界辽河群变质岩系最为发育,褶皱构造是直接控制本区变质层控铁硼矿的重要控矿条件,其控制着矿体的产出空间位置,并控制着区内铁矿体的展布特征。该区的铁矿属于火山沉积变质-超变质热液迭生层控矿床,矿石自然类型为磁铁矿-透闪石型,局部有磁铁矿-蛇纹石型和磁铁矿-硼镁铁矿型。     

危机矿山接替资源勘查实践——以安庆铜矿为例

总结了国家危机矿山接替资源勘查项目在安庆铜矿的工作实践,强调了接替资源勘查的重要性和科学性。简介了在现有矿山范围找矿勘查工作的一般原则和方法步骤,并取得了初步勘查成果。     

Study on the multi-sources of ore-forming materials and ore-forming fluids in the Huize lead-zinc ore deposit

TheHuizelarge sizedPb ZndepositinYunnan ProvinceislocatedinthecenteroftheSichuan Yun nan GuizhouPb Zn Agpolymetalmineralizationzone(SYGPb ZnMMD)inwesternYangtzePlateandis oneofthefamousPb Zn GebasesinChina(Wang Jiangzhenetal.,2003;WangXiaochunetal.,2000).Thisdeposit,whichischaracterizedbylarge scale(Pb+Znmetallicreservesarehigherthan5mil liontons),highPb+Zngrade(thePb+Zngradesof mostoresare25%-35%),highabundanceofuseful associatedelements(Ag,Ge,Cd,Ga,etc.)and someimportantbreakt…     

Fluid Inclusion Study and Opaque Mineral Assemblage at the Deep and Shallow Part of the Batu Hijau Porphyry Copper-gold Deposit, Sumbawa, Indonesia

The Batu Hijau deposit is the only porphyry type deposit in production in the Sunda‐Banda arc, Indonesia. This study discusses the reason for the localization of copper grade at the deep part of the deposit based on the observation of opaque mineral assemblage. In addition, the formation condition of quartz veins and opaque minerals is discussed on the basis of the fluid inclusion microthermometry. Samples were selected from drill holes SBD100, SBD168, SBD194, SBD254, and SBD257 to cover the wide vertical range. At the Batu Hijau deposit, quartz veins have been classified mainly into four types called A, B, C and D veins, and the A veins contain mainly bornite, often associated with digenite and chalcocite. In addition, magnetite occurs in A veins. However, at the deep part of the deposit, there are quartz veins associated with magnetite, but few copper sulfides such as bornite and chalcopyrite in quartz veins, as observed in SBD257. Quartz veins at depth in SBD257 have abundant magnetite and pyrite. Pyrite in quartz veins at depth in SBD257 mainly occur at the rim of magnetite grains or interstices between them. In quartz veins in SBD254, there are abundant copper sulfides such as bornite and chalcopyrite in spite of the depth. Bornite and chalcopyrite occur as inclusions in magnetite grains in quartz veins in SBD254. Pyrite which often occurs in low grade zone in quartz veins in SBD254 is also recognized at the rims of copper sulfides. This indicates that pyrite in SBD257 and SBD254 formed later than magnetite. On the other hand, blebs of bornite and chalcopyrite inclusions in magnetite grains, which are recognized in quartz veins in SBD168 at shallow high grade part, suggest that the hydrothermal fluid, from which magnetite was deposited also brought the copper sulfides such as bornite and chalcopyrite to the deep part of the Batu Hijau deposit. Therefore, it is concluded that initially the high grade ore zone extended to depth without localization. However due to the later overprinting hydrothermal activity, copper sulfides and magnetite were replaced or dissolved and pyrite was formed, resulting the low grade zone at the deep part of the deposit. Dissolution temperatures (Td) of halite obtained by from fluid inclusion microthermometry show significant differences between SBD168 and other drill holes. The high Td obtained in SBD168 may indicate larger volume of NaCl crystals in hydrothermal fluid at the time of entrapment of the fluid inclusions and formation of other opaque minerals such as magnetite and copper‐iron sulfides. It suggests that the ratio of vapor to brine is also higher at the shallow part of the deposit. The higher vapor to brine ratio may suggest a higher degree of boiling. Removal of vapor phase separated from brine during boiling increases the concentration of substances dissolved in the brine, and this will result in saturation, as evidenced by the salinity and NaCl saturation. The higher degree of boiling suggested by the higher vapor to brine ratio at shallow part may have increased the copper concentration in the brine that may have lead the saturation, resulted in the deposition of copper‐bearing minerals.     

新疆布尔克斯岱金矿床的构造成矿机理

文章对布尔克斯岱金矿床构造成矿进行较详细地分析，在此基础上结合地洼理论提出了布尔克斯岱金矿床的构造成矿模式：原始矿源层→矿源层→构造破碎蚀变带成矿。     

非线性铀成矿作用--以上第三系砂岩型铀矿为例

本以滇西上第三系陆相砂岩铀矿为例研究非线性铀成矿作用。与铀矿化有关的参数可分为矿化参量和控制参量,矿化参量以及矿化在控制参量中的分布均遵从对数正态分布,控制参量(温度、压力和地球化学条件)的耦合作用对铀矿化的概率和平均品位的控制作用是非线性的,铀矿化在控制参量构成的相空间中的变化轨迹是一复杂的超曲面。非线性铀成矿作用具分形特征。     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

铜官山矿田深部构造的三维计算模拟及其找矿意义

计算模拟已成为研究矿田深部三维构造重要可行手段,对深部找矿具有重要意义。基于铜官山矿田地质背景及所获勘查数据特征,我们采用知识驱动下多级约束和多源数据融合建模方法模拟矿田范围内–2000 m以上主要地质界面。以逆冲推覆导致断展–断弯褶皱理论模式解释大地测深的电阻率数据,推断地质界面位置,在Micromine-GOCAD耦合平台上在多级约束下融合多源的界面位置数据,以离散光滑插值算法和Delaunay三角网剖分法重构主要地质界面,在计算机虚拟空间再现矿田三维构造格架。结果显示:铜官山岩体和天鹅抱蛋岩体三维形态变化复杂,总体上向西倾,向深部岩体规模快速变小。位于铜官山岩体东接触带的铜官山铜矿田深部无找矿潜力,原因是接触带产状变陡,并且是岩体直接与上泥盆统砂岩接触;矿田深部主要构造为走向NE并沿倾向弯曲的逆冲推覆断层;铜官山背斜东翼含矿的中–上石炭统层位向深部倒转后又在–1200 m至–1500 m深度返转成向东南缓倾的正常层位,其底部与逆冲推覆断层重合,是深部找矿的有利靶区。     

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.     

吉林集安铅锌矿地球化学与分散元素

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。