甘孜—理塘断裂带北段玄武岩地球化学特征及构造意义

沿甘孜-理塘断裂带广泛发育有三叠纪玄武岩,该断裂带北段的玄武岩多为SiO_2大部分不饱和蚀变较强的基性岩,根据TiO_2K_2O、P_2O_5、Al_2O_3和CaO含量判定为亚碱性拉斑玄武岩系列。痕量元素特征表明,玄武岩为轻稀土弱富集型,∑REE、∑LREE/∑HREE、δEu、Eu/Sm、Sm/Nd都显示与大洋拉斑玄武岩一致。笔者认为,理塘断裂带南段在晚二叠世打开并逐步向北推进,北段于早三叠世打开,中三叠世为甘孜-理塘海发育的鼎盛时期,晚三叠世逐渐闭合。     

黑龙江铁力兴安一带斑岩型钼矿资源潜力预测

黑龙江省铁力市兴安地区发育晚三叠世-早侏罗世的细粒二长花岗斑岩的U-Pb锆石LA-ICPMS年龄为195～201Ma,钼矿(化)体产于斑岩体的顶部或外接触带的中细粒似斑状二长花岗岩中,斑岩体的岩石学、矿化及围岩蚀变、地球化学异常特征,均显示出斑岩型矿床的特征.另外,在花岗质火山-侵入杂岩体中也见钼矿化,其异常模式虽显示出中温火山热液有关的特征,但从区域成矿演化特征来看,可能与晚三叠世-早侏罗世细粒二长花岗斑岩具有统一的构造-岩浆-成矿体系,具"同源不同环境、部位和同位、不同成矿期次"的特征.     

豆荚状铬铁矿床成矿地球化学指标对比和成矿作用讨论

豆荚状铬铁矿主要赋存于地幔橄榄岩中,与方辉橄榄岩密切相关。在全球的分布与蛇绿岩带分布基本一致,但并非所有蛇绿岩体都赋存有铬铁矿,且其中赋存的铬铁矿体规模和分布都是很不规律的。我们对比研究了国内外9个含铬矿和4个不含铬矿蛇绿岩中地幔橄榄岩的地球化学组成,认为含铬矿地幔橄榄岩具有全岩低含量的CaO(<1.91%)和Al_2O_3(<1.76%)、方辉橄榄岩轻稀土元素富集,橄榄石高Fo值(>90),斜方辉石低Al_2O_3含量(<3.8%)以及副矿物铬尖晶石高Cr/Fe值(>1.5)等特征,可以作为该蛇绿岩体含矿评价的地球化学指标。通过这些指标可知豆荚状铬铁矿床是较高程度部分熔融和地幔交代作用的共同结果,结合前人提出的铬铁矿成矿模式,对铬铁矿的成矿过程有了进一步的认识。     

Episodic fluid flow as a trigger for Miocene‐Pliocene slope instability on the Utgard High,Norwegian Sea

Mass wasting is triggered on many continental slopes by a number of mechanisms, including seismic shaking, high sedimentation rates, the presence of weak geological units and gas hydrate dissociation. In this study, the morphology of a Late Miocene–Early Pliocene mass‐transport complex (MTC) on the Utgard High is unravelled and discussed in relation to possible trigger mechanisms. The approach used here includes 3D seismic interpretation and the analysis of variance attribute maps. The interpreted MTC is located on the crest and flanks of the Utgard High and is composed of three mass‐transport deposits with seismic characters varying from transparent and chaotic seismic facies at the base to slightly deformed layers composed of mounds and rafted blocks in the middle and chaotic to transparent reflections at the top. Lithologically, the MTC consists predominantly of claystone with high gamma ray and low density and resistivity values, demonstrating that the associated mounds represent remobilized ooze sediments. A vertical stack of six magmatic sills emplaced from 55.6 to 56.3 Ma into the Upper Cretaceous shales is interpreted at depths of 3,000–5,500 ms two‐way travel time (TWTT). In association with these magmatic sills are several hydrothermal vent complexes that interacted with the top MTC horizon, signifying that episodic and secondary fluid‐venting events might be the principal mechanism facilitating mass wasting in the study area. In addition, the remobilization of ooze sediments into mounds is hypothesized to be dependent on fluids and clayey layers. As a corollary of this work, the importance of relict and recurrent episodes of fluid flow in the Vøring Basin and their influence on the geotechnical integrity of the overburden and later mass wasting is established.     

阿拉善地块北缘的蛇绿混杂岩带及其大地构造意义

阿拉善地块北缘新近发现两条蛇绿混杂岩带,即恩格尔乌苏蛇绿混杂岩带和查干础鲁蛇绿混杂岩带。这两条蛇绿混杂岩带在地球化学特征和构造特征等方面都有各自的特点。前者规模巨大,表现为洋壳的性质,是华北地台和中亚陆块的最终缝台线;后者表现为弧后小洋盆的性质,是华北地台北缘的一条岛弧和地台的缝合线。这两条蛇绿混杂岩带的发现,以及对它们性质的研究。对该区的构造单元划分和大地构造演化研究有着重要的意义。并为邻区的对比研究提供了依据。     

镧-氨基酸络合物对球等鞭金藻的影响

本文首次研究了镧-脯氨酸和镧-苯丙氨酸络合物对球等鞭金藻(Isochrysis galbana)的影响,结果表明,两种络合物对球等鞭金藻细胞繁殖及叶绿素的合成有明显的促进作用,浓度范围为5-20mg/dm3时,至第6天细胞数分别提高10.8%～17.2%,11.5%-20.5%(P<0.05);叶绿素浓度分别提高31.7%-37.5%,44.7%～48.4%(P<0.05),其中以浓度为10mg/dm3的实验组最高。镧的氨基酸络合物对球等鞭金藻的作用效果与镧相比是等同的。     

克拉麦里—塔克札勒—大黑山蛇绿岩建造稀土元素特征

克拉麦里—塔克札勒—大黑山蛇绿岩建造稀土元素含量由变质橄榄岩—堆积橄榄岩—堆积辉长岩—玄武岩有规律增高 ,总体表现为轻稀土弱富集 ,L/H值大多数大于 1,局部有轻稀土亏损的特征。蛇绿岩建造各单元间稀土元素分布模式不尽相同 ,即使是同一单元在不同地段亦有差异 ,反映地幔岩浆的复杂性。基性熔岩稀土元素分布模式既有洋脊玄武岩的平坦曲线 ,又有轻稀土富集型的夏威夷等洋岛玄武岩的特征 ,反映该蛇绿岩带混杂着洋壳残骸和洋岛碎块。由清水—南明水东—塔克札勒基性熔岩稀土元素含量有规律递增 ,分别是球粒陨石的 9.4、15.4、18.9倍 ,反映玄武质岩浆分异程度逐渐增高 ,间接说明该岩带闭合时间由西向东从中泥盆世—晚石炭世末 ,再向东甚至延续至二叠纪     

Structural and kinematic analysis of the Corredoiras detachment: evidence for early Variscan synconvergent extension in the Ordenes Complex, NW Spain

 An important detachment is described in the allochthonous Ordenes Complex, in the NW Iberian Massif, and its meaning is related to the kinematics of contemporaneous convergent structures. The Corredoiras Detachment (CD) separates a hangingwall unit, characterised by a medium-pressure metamorphic gradient, from a footwall high-pressure and high-temperature unit and an underlying ophiolitic unit. An associated ductile shear zone, nearly 2000 m thick, developed in the lower part of the hangingwall unit, where the Corredoiras Orthogneiss, a Lower Ordovician metagranite, was progressively transformed into augengneisses, mylonitic and ultramylonitic gneisses. The attitude of the stretching and mineral lineation in the mylonites varies due to late refolding at map scale, but the sense of movement can be estimated, being roughly top to the SE. According to crosscutting relationships, the CD developed subsequent to the thrusting of the high-pressure/high-temperature unit onto the ophiolitic unit, and prior to younger extensional detachments, upright folding and strike-slip tectonics. The geometric relationships of the CD with the previous structures in the footwall unit, the subtractive character of the metamorphic gap between its hangingwall and footwall, and the available isotopic data suggest that the CD is an early Variscan, ductile extensional detachment, the movement of which was roughly simultaneous with the onset of thrusting of the allochthonous complexes over their relative autochthon. Received: 17 November 1998 / Accepted: 4 April 1999     

Adsorption of Au(III) and Au(I) complexes on δ-MnO2

The sorption of AuCl₄ ⁻,AuCl₂ ⁻ and Au(S₂O₃)^3- on δ-MnO₂ was investigated at pH2–11.6, 0.01 mol/L and 0.1 mol/L NaNO₃ solutions. At pH 4 in two electrolyte strength solutions, Au sorption densities on δ-MnO₂ are 0.18–0.21 and 0.28μmoL/m² for AuCl₄ ⁻ and Au(S₂O₃)₂ ^3-, respectively, and the Au surface coverage is approximate to or lower than 1%. This adsorption of the two Au complexes decreases as the solution pH increases, which conforms to the sorption regularity of the anion on δ-MnO₂. The Au sorption decreases in the sequence of Au(S₂O₃)₂ ^3- >AuCl₄ ⁻ >AuC1₂ ⁻. The intrinsic equilibrium constants (logK ^int) of the three Au complexes are 1.17–2.7, much higher than those of Cu and Cd. The hydrolysis products of AuCl₄ ^- are preferentially adsorbed by δ-MnO₂ and the inner-sphere Au-surface complexes are formed on the surface. Project supported by the National Studying-abroad Foundation, the National Natural Science Foundation of China (Grant No. 49573200) and the Australian Mining Industry.     

A Review of Study on Fe-C Interaction and Their Adsorption Properties to Soil Heavy Metal

Nowadays, the Fe-C coprecipitate mechanism is recognized by more and more scholars and becomes the hot topic in the environmental science. On the basis of discussing the interaction between iron oxide and organic matter, and the adsorption research progress of Fe-C complexes on heavy metals, the immobilization potential of Fe-C complexes on heavy metals in polluted soil were illustrated. The surface properties and physical characterizations of iron oxide are changed regularly with the interaction of organic matter, which lead to the higher adsorption capacity of Fe-C complexes in contrast to single iron oxide. Besides, the influences of pH values, organic matter types and surface properties of iron oxides on the adsorption capacity of Fe-C complexes on heavy metals were discussed. The excellent adsorption performance of Fe-C complexes in certain conditions will provide important theoretical basis for contaminated soil remediation.