河南省铁山庙式铁矿床的形成过程与"二铁"矿床氧化作用特征

河南省铁山庙式铁矿床为沉积变质矿床,总储量达数亿t,矿石类型为磁铁矿、赤铁矿型。为了研究矿床氧化带的分布规律,指导采矿、选矿工作的顺利开展,对“二铁”矿床进行了现场踏勘、取样测试,结合有关资料比较系统地研究了河南省铁山庙式铁矿床氧化带的分布,以及对采选工作的影响,探讨了铁矿的形成过程和不同地质时期的氧化作用。结果表明,氧化矿硬度变低、密度变小、易于开采;氧化带东厚西薄、东深西浅;氧化矿与原生矿呈上下交叉、水平交叉出现;氧化带的分布与现代地形无关,仅与古地形有关。     

旋回年代学及其应用意义--华北地台中寒武世碳酸盐岩鲕滩高频旋回的年代学研究

华北地台中寒武世鲕滩碳酸盐岩沉积序列中发育大量分属4～7级的高频层序,依据旋回平均厚度的频率分布、不同级别旋回叠加样式和比率、沉积发育样式和跨越整个地台的可对比等特征认为,它们受控于地球轨道参数变动,是典型的米兰柯维奇旋回,其中Ⅳ、Ⅵ级分别对应于长、短偏心率旋回,时限分别为0.4Ma和0.1Ma.应用轨道旋回规则的周期间隔给出了中寒武世各级层序、地层阶和相应界面的年龄值.     

川东北飞仙关组鲕滩储层成岩作用和孔隙演化

川东北飞仙关组鲕滩储层是四川盆地重要的勘探目的层,受成岩作用的改造非常强烈。通过对岩心、普通薄片、铸体薄片、阴极发光、碳氧同位素、微量元素和流体包裹体等多种资料进行综合研究,详细阐述了主要成岩作用的类型、形成机理及其产物,分析了其对储层的影响。胶结作用和压实作用是原生孔隙和部分次生孔隙的主要破坏者;混合水白云石化作用、溶蚀(岩溶)作用、破裂作用是次生孔隙的主要建造者,其产生的溶孔、溶洞和裂缝是天然气的主要储集空间和运移通道。成岩作用是储层物性的主要控制者,控制了孔隙的演化过程。     

四川广安市响水飞仙关组剖面特征及地质意义

四川省广安市桂兴镇响水村下三叠统飞仙关组地质剖面,位于华蓥山背斜的西翼,其古地理位置位于早三叠世川东碳酸盐台地西侧。对该剖面的详细研究,有利于恢复飞仙关期川东碳酸盐台地西侧的沉积演化过程。响水剖面飞仙关组一段属于半局限浅海陆棚和开阔台地含泥灰岩沉积。飞仙关组二段下部为碳酸盐台地西缘斜坡相及开阔台地相;其上部为较稳定的开阔台地沉积。飞仙关组三段是碳酸盐台缘鲕滩和开阔台地沉积。飞仙关组四段属于典型的混积台地潮坪沉积。川东碳酸盐台地西侧飞仙关组由两个向上变浅的沉积旋回组成,第2个沉积旋回是碳酸盐台地向西增生和鲕滩发育的主要时期。     

Influence of the olivine additive fineness on the oxidation of magnetite pellets

Olivine is used as an additive in Luossavaara–Kiirunavaara AB (LKAB) blast furnace pellets. The LKAB iron ore is magnetite which oxidizes to hematite during the sintering process. Olivine retards the oxidation of magnetite pellets if the threshold temperature of magnesioferrite formation is exceeded.In this study, we have developed a thermogravimetric measuring method to study the relationship between the olivine reactivity in green pellets and the olivine fineness. A less reactive olivine makes the pelletizing process more tolerant of excessively high temperatures in the green pellets during oxidation.The reactivity of olivine decreases when the amount of fine tail in olivine is decreased. The top size is limited by balling. Grinding tests in pilot scale show that if the olivine additive is ground in closed circuit with a ball mill keeping good control over the top size, the olivine fineness can be appreciably decreased without disturbing balling. The olivine reactivity can be decreased by 40% compared to the reference olivine in the production plant. Also, savings can be made on both the grinding energy and grinding media consumption. The results in both pilot scale and full production scale show that better oxidation in the grate due to a coarser olivine additive improves the low temperature reduction strength (LTD, ISO 13930) in pellets.The measuring method developed for the olivine reactivity enabled evaluation of different particle-sizing methods for olivine characterisation. The screening size fraction %−45 μm showed a good correlation to olivine reactivity in green pellets within a very large measuring range. The correlation of laser diffraction analysis to the olivine reactivity showed, however, that the laser diffraction measuring method is affected too much by variations in the large particles.     

江西大吉山五里亭花岗岩中变生褐帘石的加热研究

对采自我国南方燕山期五里亭花岗岩体中的褐帘石,经偏光显徽镜、电子探针仪、差热仪、X射线等方法进行分析得出,该矿物为变生褐帘石。加热800℃,850℃,950℃,970℃,1100℃退火系列样品的X射线粉晶数据分析得出:1.变生褐帘石X射线粉晶分析的最宜加热温度为800-850℃;2.加热至970℃的退火样品,褐帘石已分解为方铈石、赤铁矿、钙长石,加热到1100℃,褐帘石已渐消失,方铈石、钙长石和赤铁矿成为主要矿物相。     

Mn2+和Fe3+的致色作用:来自意大利白垩纪远洋红色灰岩的启示

本文首先详细研究了含Mn2 和Fe3 的致色矿物菱锰矿、鲕状赤铁矿、云母赤铁矿和镜铁矿的可见光吸收光谱及其一阶导数谱,鲕状赤铁矿、云母赤铁矿和镜铁矿的可见光吸收一阶导数谱的红光区的吸收谷的位置的变化表明随赤铁矿结晶度的降低,吸收谷由586.4nm移至577.4nm,而菱锰矿展示出了Mn2 的因电子跃迁产生的四个典型吸收及其一阶导数谱上577nm的吸收谷的强度比赤铁矿相应谷的强度低一个数量级,表明其电子跃迁的致色机理与赤铁矿的染色机理完全不同。依据赤铁矿的结晶度和鲕状赤铁矿与大洋红层中赤铁矿的沉积成因相似的原则遴选出鲕状赤铁矿为含Fe3 致色矿物,依据菱锰矿是和方解石具有相似结构且为红色的原则选取菱锰矿为含锰致色矿物,并佐以化学纯氧化镁为基体配制了一系列的含菱锰矿、鲕状赤铁矿和菱锰矿及鲕状赤铁矿的两相或三相混合物。详细研究了三类混合物的可见光吸收光谱的一阶导数谱,发现含菱锰矿和含鲕状赤铁矿在573nm附近均存在一吸收谷,鲕状赤铁矿的重量分数低至0.05%时仍可见一明显吸收谷且该吸收谷移至565nm附近,菱锰矿在低至0.50%时也可见这一吸收且在低至0.11%时仍可显示出菱锰矿的信息,其575nm的吸收峰未见偏移;混合物可见光一阶导数吸收谱上鲕状赤铁矿的575nm附近的吸收谷的强度随鲕状赤铁矿的重量分数的升高而增强,而所有的配制混合物中该吸收谷的位置低于577.4nm的事实也表明为使致色矿物和氧化镁混合均匀的研磨降低了赤铁矿的结晶度。本研究表明Mn2 的电子跃迁激发和细小、结晶差的赤铁矿的染色共同造就了意大利白垩纪远洋红色灰岩的红色。     

重庆市巫山县桃花赤铁矿岩相古地理初探

重庆市巫山县桃花赤铁矿属于沉积铁矿床,矿床的形成主要受岩相古地理条件控制。本文介绍了铁矿赋存层位的沉积相。通过古气候、古水深、古构造、沉积环境及氧化还原条件等方面的研究,编制了巫山县桃花赤铁矿岩相古地理图,讨论了铁矿的生成条件,为后期的找矿工作起到了指导作用。     

四川盆地东部下三叠统飞仙关组白云岩化作用及其与储集层发育的关系*

四川盆地东部下三叠统飞仙关组鲕滩相储集层多为白云岩,主要分布于环开江—梁平盆地的台地边缘相带。岩石学和地球化学特征表明,飞仙关组鲕滩相储集层经历了多期白云岩化作用,其中最重要的一期发生于成岩早期近地表环境,由蒸发海水回流引起,形成的粉晶交代白云石构成了现今白云岩的主体。飞仙关组早期白云岩经历了不同程度的埋藏重结晶作用,形成了不同的岩石结构类型。飞仙关组白云岩的孔隙多为原岩中继承而来,白云岩化作用对储集层发育的意义并非创造孔隙,而是保存已有的孔隙。由于白云岩化作用发生的时间早以及白云岩的抗压溶性质,原生（鲕）粒间孔以及早期大气淡水溶蚀作用形成的鲕模孔/粒内溶孔可以在很大程度上保存下来,构成了现今鲕滩相储集层的主要储集空间。     

Rocky relationships: the petroglyphs of the Murujuga (Burrup Peninsula and Dampier Archipelago) in Western Australia

The petroglyphs of the Murujuga (Burrup Peninsula and Dampier Archipelago) in Western Australia are of exceptional cultural value for the nation. It is Australia’s largest and most significant collection of aboriginal rock art essentially as petroglyphs, with the number estimated at more than one million engravings. The Murujuga is a textbook example of ancient and modern times colliding as it also hosts potentially polluting, major industrial complexes such as iron ore and salt ports; liquefied natural gas, liquid ammonia and ammonium nitrate plants; railway lines, pipelines and rock quarries. The work presented in this paper is underpinned by an annual monitoring study of 10 selected sites including two control sites located on Dolphin and Gidley islands and eight test sites located closer to the industrial areas. The main rock types of the Murujuga, gabbro and granophyre, have been affected by weathering consisting of a cm-thick leached zone capped by a skin of orange and red iron and manganese oxides. The petroglyphs were engraved by removing the few top millimetres of the iron oxide-rich layer and the contrast with the paler leached zone clearly showing the carved motifs. Phosphorus is abnormally enriched in the leached zone and the surface coating, with manganese exclusively on the surface coating, demonstrating the impact of bird droppings and ‘desert varnish’ on the rocks. The colour difference and the hematite–goethite ratio, measured with a field portable reflectance spectrometer, between the background and engraving provides a tool to estimate the relative age of the petroglyphs and the selection of the backgrounds. As the fine-grained granophyres were preferentially chosen from the coarser-grained gabbros to host the petroglyphs, the goethitic (or yellower) backgrounds were prepared as canvas before being engraved. Many petroglyphs register the food items of the area, which changed as the last ice age ended and sea levels rose. We hypothesise that based on their locations and colour difference the constraint for the oldest age of the petroglyphs exceeds 17 000?years BP.