利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿

针铁矿(Gt)和赤铁矿(Hm)是广泛存在于土壤和沉积物中的重要铁矿物。这两种矿物在土壤和沉积物中含量很低,常规的测试手段很难有效地测定其含量。利用反射光谱联合加热处理的方法,可对土壤及沉积物样品中针铁矿和赤铁矿进行定性或半定量测定。实验结果显示,样品加热到300℃后,针铁矿的反射光谱的一阶导数特征峰发生了变化,赤铁矿的一阶导数特征峰却没有明显的变化。因此加热前后样品反射光谱一阶导数的变化取决于针铁矿和赤铁矿的含量。利用这种方法估计黄土高原第三纪红粘土样品中的赤铁矿含量约为0.3%～0.4%,针铁矿含量约为0.5%～1%。     

鄂西宁乡式铁矿分布层位岩相特征与成因探讨

鄂西宁乡式铁矿分布广、规模大,尤以普遍发育赤铁矿鲕粒而独具特色。并且它一般赋存于加里东运动后第一个海浸沉积序列中由碎屑岩向碳酸盐岩过渡的层位,岩相古地理环境有明显的控制作用。本文铁矿层中赤铁矿鲕粒类型之繁多,结构之复杂,安全可与碳酸盐鲕粒相提并论,其成因亦非常相似,均为强烈搅动环境中机械沉积的产物。经波浪和潮汐水流的再次搬运富集。最后定们于中等一弱动荡环境或相地低凹摈滨相上部。     

山西芮城水峪地区罗圈组海侵沉积物

华北陆块南缘、西南缘广泛分布的罗圈组及其相应地层多被认为是新元古代末期冰川沉积。山西南部芮城水峪剖面位于华北南缘罗圈组出露范围的最北端,罗圈组受下伏蓟县系龙家园组白云岩风化面形态控制,横向岩性变化剧烈,分别由准原地堆积的风化角砾岩、紫红色含砾泥岩及一套特殊的"含砾砂质鲕粒白云岩"组成,均为温暖气候下海侵或海侵改造产物,与冰川作用无关。"含砾砂质鲕粒白云岩"在华北南缘罗圈组中尚属首次发现,具有明显的指相意义。该地区罗圈组海侵沉积物的存在,可能表明华北南缘罗圈组在各地区存在沉积环境乃至地层时代的巨大差异,不能简单以某一冰期的"冰碛岩"笼统看待。     

四川盆地南部下三叠统飞仙关组一段台内鲕滩的主控因素

四川盆地飞仙关组台缘鲕滩气田的发现,激励了人们重新认识台内鲕滩的发育分布规律及其勘探前景。根据野外露头及钻孔资料的分析,认为四川盆地南部飞仙关组一段的台内鲕滩具有发育向上变浅序列、单滩体厚度一般小于3m、横向连续性较差的特征。着重分析了沉积期古地貌、古水深、海水动荡程度以及古海平面相对升降变化对台内鲕滩的控制作用,并把滩体的发育阶段分为雏滩期(低速建造期)、滩核期(高建造期)及衰亡期3个阶段。结果表明,在缓慢等效的海退过程中,处于高能沉积界面附近的水下古高地有利于台内鲕滩的形成,继承性的泸州古隆起核部是区内有利的滩体发育区,形成的台内滩体具有一定的厚度规模和较大的分布面积。这一认识可为该区飞仙关组台内鲕滩的下一步勘探提供必要的地质支持。     

凉山瓦西乡南红玉中的赤铁矿包裹体特征与成因

瓦西乡产出的南红玉中的红色点状及火焰纹典型包裹体分别是石英中的红色球粒与红色管状包裹体。鏡下及扫描电镜(SEM)研究,红色球粒分布在"三色"层水晶的菱面体单形晶面的间歇层面中,由红色核、黑色壳和红色表层组成;火焰纹管状包裹体主要出现在条带水晶中,管的方向垂直水晶的菱面体晶面,管的内壁呈黑色,外壳为红色。其球粒表层或管外壳的颜色、厚度及透光性则直接影响南红的颜色质量与润泽性。研究表明,球粒状和火焰状包裹体主要由片状、鳞片状或板片状赤铁矿组成;球粒圈层中的赤铁矿晶体c轴取向呈规律变化,可能与其V2O5含量有关。据水晶晶体中的球粒、管及共生矿物绿帘石、黄铜矿包裹体的红外光谱(IR)及流体包裹体均一法测温与激光拉曼(LRS)分析,球或管的赤铁矿属含有机质的低温热液(约160℃)成因,成矿溶液中的有机质也是促使铁氧化物凝聚形成具不同圈层结构的红色球粒与管的主要原因。有机质可能来自下二叠统茅口组碳酸盐。     

Magnetic Anisotropy as an Aid to Identifying CRM and DRM in Red Sedimentary Rocks

To further evaluate the potential of magnetic anisotropy techniques for determining the origin of the natural remanent magnetization (NRM) in sedimentary rocks, several new remanence anisotropy measurement techniques were explored. An accurate separation of the remanence anisotropy of magnetite and hematite in the same sedimentary rock sample was the goal.In one technique, Tertiary red and grey sedimentary rock samples from the Orera section (Spain) were exposed to 13 T fields in 9 different orientations. In each orientation, alternating field (af) demagnetization was used to separate the magnetite and hematite contributions of the high field isothermal remanent magnetization (IRM). Tensor subtraction was used to calculate the magnetite and hematite anisotropy tensors. Geologically interpretable fabrics did not result, probably because of the presence of goethite which contributes to the IRM. In the second technique, also applied to samples from Orera, an anisotropy of anhysteretic remanence (AAR) was applied in af fields up to 240 mT to directly measure the fabric of the magnetite in the sample. IRMs applied in 2 T fields followed by 240 mT af demagnetization, and thermal demagnetization at 90°C to remove the goethite contribution, were used to independently measure the hematite fabric in the same samples. This approach gave geologically interpretable results with minimum principal axes perpendicular to bedding, suggesting that the hematite and magnetite grains in the Orera samples both carry a depositional remanent magnetization (DRM). In a third experiment, IRMs applied in 13 T fields were used to measure the magnetic fabric of samples from the Dome de Barrot area (France). These samples had been demonstrated to have hematite as their only magnetic mineral. The fabrics that resulted were geologically interpretable, showing a strong NW-SE horizontal lineation consistent with AMS fabrics measured in the same samples. These fabrics suggest that the rock's remanence may have been affected by strain and could have originated as a DRM or a CRM.Our work shows that it is important to account for the presence of goethite when using high field IRMs to measure the remanence anisotropy of hematite-bearing sedimentary rocks. It also shows that very high magnetic fields (>10 T) may be used to measure the magnetic fabric of sedimentary rocks with highly coercive magnetic minerals without complete demagnetization between each position, provided that the field magnetically saturates the rock.     

下三叠统鲕粒灰岩中微生物矿化组构特征及意义 ——以川东北地区飞仙关组为例

PTB全球最大生物灭绝事件后,早三叠世被认为是微生物发育繁殖的黄金时期,浅水环境是微生物活动及微生物岩形成的最有利环境。借助高分辨率扫描电镜和能谱分析,在川东北地区开江—梁平海槽西侧下三叠统飞仙关组浅水碳酸盐岩台地边缘的鲕粒灰岩中发现了三种微生物矿化组构:空腔状微生物矿化组构、显微瘤状微生物矿化组构和纤状微生物矿化组构;通过沉积学、岩石学及地球化学的综合分析,认为显微瘤状微生物矿化组构是微生物新陈代谢时形成的纳米球状云质颗粒,纤状微生物矿化组构是微生物的胞外聚合物,而空腔状微生物矿化组构则属于微生物个体。这些微生物矿化组构的发现,为早三叠世微生物大爆发提供了一定的直观证据;推测大量的微生物活动是早三叠世碳酸盐快速沉积现象的直接诱因,并导致于二叠纪末发育的克拉通内裂陷——开江—梁平海槽在早三叠世被快速填平。     

Influence of ferric iron on phase equilibria in greenschist facies assemblages: the hematite‐rich metasedimentary rocks from the Monti Pisani (Northern Apennines)

We have investigated the effects of different Fe₂O₃ bulk contents on the calculated phase equilibria of low‐T/intermediate‐P metasedimentary rocks. Thermodynamic modelling within the MnO–Na₂O–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (MnNKFMASHTO) chemical system of chloritoid‐bearing hematite‐rich metasedimentary rocks from the Variscan basement of the Pisani Mountains (Northern Apennines, Italy) fails to reproduce the observed mineral compositions when the bulk Fe₂O₃ is determined through titration. The mismatch between observed and computed mineral compositions and assemblage is resolved by tuning the effective ferric iron content by P–XFe₂O₃ diagrams, obtaining equilibration conditions of 475 °C and 9–10 kbar related to a post‐compressional phase of the Alpine collision. The introduction of ferric iron affects the stability of the main rock‐forming silicates that often yield important thermobaric information. In Fe₂O₃‐rich compositions, garnet‐ and carpholite‐in curves shift towards higher temperatures with respect to the Fe₂O₃‐free systems. The presence of a ferric‐iron oxide (hematite) prevents the formation of biotite in the mineral assemblage even at temperatures approaching 550 °C. The use of P–T–XFe₂O₃ phase diagrams may also provide P–T information in common greenschist facies metasedimentary rocks.     

鄂尔多斯盆地南缘中寒武统张夏组鲕粒滩相储层特征及主控因素

鄂尔多斯盆地寒武系深层具有良好的勘探潜力,中寒武统张夏组为寒武系勘探的重要目的层系。通过野外剖面详测和岩心、薄片观察及实验分析,对张夏组储层的特征、成因及主控因素进行了分析和研究,并预测了有利储层发育区。研究表明:①张夏组主要发育台缘鲕粒白云岩和台内鲕粒白云岩2类储层。②台缘带鲕粒滩累计厚度集中在50~300 m之间,鲕粒粒径平均为1.25 mm,鲕粒白云岩储集空间以溶蚀孔洞、粒间溶孔和晶间(溶)孔为主,平均测井孔隙度和渗透率分别为2.0%和0.038×10^-3μm²。③台内鲕粒滩厚度在50~120 m之间,鲕粒粒径平均为0.85 mm,鲕粒白云岩储集空间以溶蚀孔洞、粒间溶孔为主,平均测井孔隙度和渗透率分别为3.3%和2.787×10^-3μm²。④张夏组储层受鲕粒滩相、白云石化以及三级/四级层序界面控制,台缘规模有利储层发育在四级海退层序中上部的鲕粒白云岩地层中,台内规模有利储层发育在寒武系顶部不整合面之下的鲕粒白云岩地层中。预测台缘岐山—旬邑一带和台内陇东地区为两大规模有利储层发育区。     

球粒状和棒状纳米赤铁矿光电化学特性研究

本文以乙二醇为诱导剂通过电化学沉积法成功合成了球粒状及棒状纳米赤铁矿。X射线衍射光谱(XRD)和Raman光谱结果表明,球粒状赤铁矿粒径20±5 nm;棒状赤铁矿截面直径约20 nm,长90±10 nm;二者物相皆为单一均匀的赤铁矿。紫外-可见吸收光谱显示两种赤铁矿在300~550 nm范围内均有较好吸收,Tauc方程计算球粒状和棒状赤铁矿禁带宽度分别为2.00 e V和1.99 e V。Mott-Schottky拟合结果表明1 M KOH溶液体系中,棒状赤铁矿载流子浓度为1.95×1021cm-3,高于球粒状赤铁矿(3.16×1020cm-3)。进一步的光电化学实验表明:0.6 V(vs.Ag/Ag Cl)电势下棒状赤铁矿光照下电流密度较暗电流提升550%,球粒状赤铁矿电流密度提升77%。研究证实,赤铁矿形貌对其半导体特性及光电化学特性有影响,且棒状赤铁矿电极表现出更好的可见光响应特性,具有更佳的光电催化潜力。