东天山圪塔山口铜镍矿区镁铁-超镁铁质岩体橄榄石与尖晶石矿物学特征

新近发现的圪塔山口含铜镍矿化镁铁-超镁铁质岩体位于新疆东天山黄山-镜儿泉铜镍矿带东端,共有4个镁铁-超镁铁质岩体,其中Ⅰ、Ⅱ、Ⅲ号岩体均见铜镍硫化物矿化,研究表明其形成时代(282Ma)及岩浆来源与东天山地区其它铜镍矿化镁铁-超镁铁质岩体一致。本文对主要造岩矿物橄榄石及副矿物尖晶石进行了显微镜下观察及电子探针分析,结果表明橄榄石Fo值介于83.1~86.6之间,平均85.2,为贵橄榄石,其Ni含量变化于1273×10-6~2719×10-6,平均1918×10-6;尖晶石根据铝含量的不同可以分为高铝和低铝两种。圪塔山口岩浆为地幔源区发生15.8%~18.8%的部分熔融,并有过剩橄榄石加入的玄武质岩浆经结晶分异作用形成的派生岩浆。对橄榄石分离结晶和硫化物熔离的计算模拟表明橄榄石结晶前,岩浆已经达到S饱和,结晶过程始终伴随硫化物的熔离作用,虽然早期结晶的橄榄石与硫化物熔体间发生了Fe-Ni交换,但仍有很好的铜镍成矿潜力。     

Melt and fluid inclusion evidence for a genetic relationship between magmatism in the Shuangliao volcanic field and inorganic CO2 gas reservoirs in the southern Songliao Basin,China

We have studied melt and fluid inclusions in minerals from alkali basalts, mantle xenoliths, and dawsonite-bearing sandstones from the Shuangliao volcanic field in southern Songliao Basin, Northeast China. The inclusions have been investigated using petrographic, geochemical, and laser Raman spectroscopic techniques. Volcanic rocks of the Shuangliao field are predominantly alkali olivine basalts that contain rare mantle xenoliths. Silicate melt and fluid inclusions are common in both olivine phenocrysts and the mantle xenoliths. The fluid inclusions are mainly composed of CO₂ with small amounts of CO, CH₄, N₂, and H₂O, which is consistent with an upper mantle origin. CO₂ gas reservoirs in the southern Songliao Basin are mostly derived from a mantle–magmatic source. Coeval fluid-inclusion homogenization temperatures, coupled with the thermal burial history, show that the CO₂ gas reservoirs in the southern Songliao Basin are Cenozoic (40–63 Ma) and coeval with the magmatism in the Shuangliao volcanic field. Despite the relatively small scale of this volcanic activity, it released large amounts of CO₂. Much of the magma was not erupted, and CO₂- and H₂O-rich magma was probably intruded into the basin along deep faults, acting as a major source of inorganic CO₂ gas in the southern Songliao Basin.     

东昆仑希望沟橄榄辉石岩LA-ICP-MS锆石U-Pb定年及岩石地球化学特征

东昆仑古特提斯域镁铁-超镁铁质岩石的研究极为薄弱,对青海东昆仑东段希望沟镁铁-超镁铁质杂岩体中橄榄辉石岩进行岩相学、地球化学及年代学分析,以期为东昆仑晚古生代-早中生代构造岩浆演化提供新的约束。利用LA-ICP-MS锆石U-Pb定年,获得希望沟橄榄辉石岩加权平均年龄为（262.4±1.6）Ma,表明岩体侵位于中二叠世。岩石地球化学研究显示,希望沟橄榄辉石岩具有较高的Mg#值（85.31~86.27）,m/f比值介于5.50~6.18,属于铁质超基性岩类;具有低TiO₂（0.41%~0.52%）和低Al₂O₃（3.04%~4.57%）,属钙碱性系列。岩石富集大离子亲石元素（Rb、Th、U）和Pb,相对亏损高场强元素（Nb、Ta、P、Ti）,ΣREE为29.79×10-6~38.96×10-6,（La/Yb）_N为1.71~2.51,平均2.15,δEu=0.73~0.86,具有弱的Eu负异常。岩石成因分析表明,岩石源区为被俯冲改造的岩石圈地幔,岩浆在演化过程中遭受了上地壳物质的同化混染作用。结合东昆仑区域构造演化,认为希望沟橄榄辉石岩为阿尼玛卿古特提斯洋俯冲阶段的岩浆记录。      

江苏徐州塔山橄榄玄武玢岩地球化学特征及其与金刚石成因关系

通过研究徐州塔山地区橄榄玄武玢岩的地球化学特征,对其岩石成因及构造环境进行判别,并进一步对其金刚石成矿前景进行探讨。结果表明,橄榄玄武玢岩属于大陆板内玄武岩,总体上略富集轻稀土元素,是在板内拉张构造背景下由石榴子石相的富集地幔经不同程度部分熔融形成的,且在岩浆结晶过程中存在一定程度的斜长石堆晶作用。其所含微粒金刚石与安徽栏杆金刚石相似,显示出金刚石生长初期的特点,应为幔源捕获成因。与金伯利岩相比,橄榄玄武玢岩在地球化学特征方面存在明显差异,整体表现为古近纪伸展期玄武岩浆的特征,不具备携带大量深源包体的条件,难以形成原生金刚石矿床。     

浅谈吉林敦化意气松南山橄榄石宝石矿矿床地质特征及宝石级橄榄石品级划分方法

本文在野外地质勘查及系统分析前人工作、资料的基础上,对吉林敦化意气松南山橄榄石宝石矿成矿地质背景、控矿因素等进行了归纳总结。对宝石级橄榄石品级的划分方法进行了探讨。     

鲁西地区新生代周村玄武岩的成因研究

山东地区新生代玄武岩主要分布在郯庐断裂带及其以东地区,在鲁西地区分布较少。本文报道了鲁西地区周村玄武岩的全岩主、微量元素组成、橄榄石斑晶及其熔体包裹体Pb同位素组成。结果表明,周村玄武岩为弱碱性玄武岩,其主量元素具有较高SiO_2和Al_2O_3,较低碱(Na_2O+K_2O)、CaO/Al_2O_3、Fe_2O_3~T(Fe_2O_3~T=Fe O/0.8998+Fe_2O_3)的特征;微量元素在原始地幔标准化蛛网图上与EMI洋岛玄武岩(OIB)相似,表现为明显的Ba、K和Sr正异常,Th和Pb负异常,无Nb、Ta和Ti异常;熔体包裹体~(207)Pb/~(206)Pb和~(208)Pb/~(206)Pb分别为0.894~0.921和2.166~2.213,略高于EMI-OIB。这些特征和鲁西地区无棣大山玄武岩有明显区别,但与山东其它地区的弱碱性-拉斑玄武岩相似。周村玄武岩的橄榄石斑晶Ni、Fe/Mn和Ca分别为1403~2611μg/g,70~93和824~2003μg/g。与橄榄岩熔体结晶的橄榄石成分相比,给定橄榄石Fo值,周村玄武岩橄榄石斑晶具有高Ni和Fe/Mn比值,低Ca的特征。结合全岩低CaO和高FeO/MnO比值,橄榄石成分指示周村玄武岩的源区岩性为辉石岩,其形成需要高比例的来自再循环地壳的英安质熔体交代地幔橄榄岩。高比例的英安质熔体和周村玄武岩的微量元素特征,进一步说明该再循环地壳为含辉长岩洋壳。本文的研究结果暗示山东地区弱碱性-拉斑玄武岩的源区辉石岩,主要与再循环洋壳有关。     

Rare Earth Element Determination in Olivine by Laser Ablation‐Quadrupole‐ICP‐MS: An Analytical Strategy and Applications

Olivine offers huge, largely untapped, potential for improving our understanding of magmatic and metasomatic processes. In particular, a wealth of information is contained in rare earth element (REE) mass fractions, which are well studied in other minerals. However, REE data for olivine are scarce, reflecting the difficulty associated with determining mass fractions in the low ng g^?1 range and with controlling the effects of LREE contamination. We report an analytical procedure for measuring REEs in olivine using laser ablation quadrupole‐ICP‐MS that achieved limits of determination (LOD) at sub‐ng g^?1 levels and biases of ~ 5–10%. Empirical partition coefficients (D values) calculated using the new olivine compositions agree with experimental values, indicating that the measured REEs are structurally bound in the olivine crystal lattice, rather than residing in micro‐inclusions. We conducted an initial survey of REE contents of olivine from mantle, metamorphic, magmatic and meteorite samples. REE mass fractions vary from 0.1 to double‐digit ng g^?1 levels. Heavy REEs vary from low mass fractions in meteoritic samples, through variably enriched peridotitic olivine to high mass fractions in magmatic olivines, with fayalitic olivines showing the highest levels. The variable enrichment in HREEs demonstrates that olivine REE patterns have petrological utility.     

一组可用于探测亚稳态橄榄石存在情况的震相

基于简化的波速结构,利用二维伪谱法研究了俯冲带不同位置震源激发的地震波的传播特征.发现当俯冲板块中存在6%的低速异常时,直达P波和直达S波之间存在波阵面近平面的易于识别的P-S转换震相,其传播方向不因震源位置偏离低速层的中心而改变.对于低速层的边界存在±2 km的随机起伏、低速层为楔形、周围介质为水平分层模型这三种情况,这组震相仍然清晰可辨.对于150 km长度的橄榄石楔,模拟结果显示仍然能在一定震中距范围内接收到这一震相.因此,可以尝试用这组震相来探测俯冲带亚稳态橄榄石的存在状态.     

Deformation and seismic anisotropy of the lithospheric mantle in the southeastern Carpathians inferred from the study of mantle xenoliths

Peridotite xenoliths with a broad range of textures provides evidence for consistent microstructural evolution in a vertical transect of the shallow lithospheric mantle (35–55 km depth) beneath the Persani Mountains, SE Carpathians, Romania, due to ongoing plate convergence in the Carpathian Arc nearby. The recrystallized grain size, crystal preferred orientations strength, and resulting seismic anisotropy vary continuously and display a strong correlation to equilibrium temperatures, suggesting a continuous change in deformation conditions with depth. The shallowmost xenoliths have microstructures typical of high stress deformation, marked by strong recrystallization to fine grain sizes, which results in weak crystal preferred orientations and anisotropy. The deepest xenoliths have coarse-grained porphyroclastic microstructures and strong crystal preferred orientations. Replacive orthopyroxene structures, consuming olivine, and high H₂O concentrations in the pyroxenes are observed in some xenoliths indicating limited percolation of fluids or volatile-rich melts. Despite the high stress deformation and high H₂O contents in some of the studied xenoliths, analysis of olivine crystallographic orientations indicates that [100] slip systems, rather than “wet” [001] accommodate most of the deformation in all samples. Seismic anisotropy estimated from the measured olivine and pyroxene crystal preferred orientations suggests that the strike-parallel fast SKS polarization directions and ~ 1 s delay times measured in the SE Carpathians are likely the consequence of convergence-driven belt-parallel flow in the lithospheric mantle.     

基于三重震相波形非线性反演的俯冲带410-km间断面起伏研究

利用NECESSArray宽频带地震台阵记录的P波三重震相波形资料,采用遗传算法,对千岛俯冲板块内部及附近410-km间断面的结构进行了非线性反演.其中,选取了发生在俯冲带的发震时刻为2009年10月10日21时24分(GMT时间)震级为Mw5.9的地震;其三重震相的射线回折点处射线路径的方向与俯冲板块的走向大致一致,...