基于循环注蒸气和烟气激励的海上稠油开采技术

通过实验和油藏数值模拟,研究循环注蒸气和烟气激励的加热降黏、气体溶解降黏、气体扩大加热腔与减少热损失、蒸气与气体协同增产效应等开采机理,优化注入蒸气和烟气温度、烟气蒸气体积比、周期蒸气和气体注入量等参数,建议注入蒸气与烟气的温度高于300℃,在大气压下烟气蒸气体积比为0.4～0.6.在渤海稠油油田开展4口井循环注蒸气和烟气激励开采的现场试验.结果表明,循环注蒸气和烟气激励开采后稠油井平均日产油量达到冷采的3倍以上,最高日产油量超过100m3,周期产油量达到1.0×104 m3左右.基于循环注蒸气和烟气激励的海上开采稠油技术可以提高海上稠油开采速度和采收率,有潜力成为未来海上稠油油田的主要热采开发方式.     

鄂尔多斯盆地南部直罗油田长8油层油气沸腾包裹体群研究

运用激光拉曼光谱、包裹体充填度测定等方法对鄂尔多斯盆地直罗油田富南3井、6井长8油层裂缝岩芯充填物中包裹体群进行分析,发现富南3井、6井与英旺油田英16井长8油层中油气沸腾包裹体群完全相同,密集分布的气泡不停晃动,证实油气沸腾包裹体群不是孤立的、偶然的地质现象。富南3井、6井和英16井长8油层裂缝岩芯的原始裂缝性质为滑动-剪切裂缝和剪切裂缝,在区域构造的作用下,反复发生拉张-挤压交替活动;在拉张发生的瞬间,与裂缝沟通的油层里的原油发生减压沸腾,原油中的轻质馏分和其他流体进入裂缝空间;在随后的挤压发生时,裂缝基本封闭,一部分流体返回原来的油层,一部分被挤到别的裂隙空间形成新的油藏;残留在裂缝里的碳酸钙,在较高的地层压力下逐渐结晶,并把残留的轻质馏分包裹,形成油气包裹体;这些油气包裹体形成压力较高,又包裹着成分类似液化气的轻质馏分,在常温常压下就处于沸腾状态;这样的过程反复进行,在裂缝充填物中形成了沿着晶体生长线以及成片、成带分布的油气沸腾包裹体群。上述油气沸腾包裹体群的形成过程就是油气的地震泵运移机制,丰富了油气运移地震泵地质模型。     

常顶瓦斯油吸附法脱除微量氯的实验研究

炼油厂将常压塔顶油和减一线油作为重整原料,但由于氯含量过高(30×10-6)无法利用,传统方法是将其中的有机氯转化为无机氯化氢后脱除,但其对加氢催化剂有毒害,采用常顶瓦斯油吸附法可直接脱除微量氯。     

Replacement of Dietary Fish Oil with Vegetable Oils Improves the Growth and Flesh Quality of Large Yellow Croaker （Larmichthys crocea）

We investigated the effect of the replacement of dietary fish oil with vegetable oils on the growth and flesh quality of large yellow croaker(Larmichthys crocea). The basal diet(FO) was formulated to contain 66.5% fish meal and 6.4% menhaden fish oil; whereas the other 3 experimental diets were formulated by replacing the fish oil with 50% soybean oil(SO50), 100% soybean oil(SO100) and 100% palm oil(PO100), respectively. The 4 diets were randomly assigned to 4 floating sea cages(3.0 m × 3.0 m × 3.0 m), and each was stocked with 250 fish individuals with an initial average weight of 245.29 g ± 7.45 g. The fish were fed to apparent satiation twice a day at 5:00 and 17:00, respectively, for 12 weeks. Experimental analysis showed that the specific growth rate of fish fed SO50 or PO100 were significantly higher than that of fish fed FO or SO100(P0.05), and crude lipid contents of ventral muscle and viscera were significantly lower in fish fed FO than in those fed the other 3 diets(P0.05). No significant differences in condition factor, viscerosomatic index, hepatosomatic index, gutted yield and colorimetric values of fish among the dietary treatments were observed(P0.05). Compared to FO diet, SO50, SO100 and PO100 diets led to substantial decreases in the liquid loss and water loss from fresh fillets(1 d, 4℃)(P0.05). Similarly, thiobarbituric acid reactive substance(TBARS) values of fillets under different storage conditions(1 d, 4℃; 7 d, 4℃; 4 weeks,-20℃; 8 weeks,-20℃) decreased significantly after partial or complete replacement of fish oil with vegetable oils. These findings indicated that the growth performance and selected flesh quality properties(liquid holding capacity and TBARS value) of large yellow croaker were substantially improved by replacing dietary fish oil with vegetable oils.     

Oil shale resources in China and their utilization

The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons,which has become a research focus. China contains abundant oil shale resources,ranking fourth in the world,with ca. 7 254. 48 × 10~8 t within 24 provinces,including 48 basins and 81 oil shale deposits. About 48% of the total oil shale resources are concentrated in the eastern resource region,with a further 22% in the central resource region. 65% of the total quantity of oil shale resources is present at depths of 0-500 m,with 17% of the total resources being defined as high-quality oil shales yielding more than 10% oil by weight.Chinese oil shale resources are generally hosted by Mesozoic sediments that account for 78% of the total resources. In terms of the geographical distribution of these resources,some 45% are located in plain regions,and different oil shale basins have various characteristics. The oil shale resources in China represent a highly prospective future source of hydrocarbons. These resources having potential use not only in power generation and oil refining but also in agriculture,metal and chemical productions,and environmental protection.     

Distribution and characteristics of volcanic reservoirs in China

About forty productive oil/gas fields hosted in volcanic reservoirs have been found since 1957 in fourteen basins of China. They can be simply subdivided into two groups, the east and the west. Reservoir volcanic rocks of the east group are predominantly composed of Late Jurassic to Early Cretaceous rhyolite and Tertiary basalt, preferred being considered as rift type volcanics developed in the circum-Pacific tectonic regime. Those of the west are Permo-Carboniferous intermediate/basic volcanic rocks, being island-arc type ones developed in paleo-Asian Ocean tectonic regime.     

温度对马尾藻及其油页岩混合物热解产气特性的影响

【目的】研究马尾藻及其油页岩混合物在不同温度下的热解产气特性。【方法】利用燃烧烟气污染物测试实验台,测量马尾藻及其油页岩混合物在温度区间400℃至800℃下CO和H_2的排放特性,包括峰值浓度、峰值时间和平均浓度。【结果】马尾藻以及其油页岩混合物的热解过程可分为慢速析出、快速析出和降速三个阶段。马尾藻单独热解实验中,排放的CO体积分数峰值达到10 367×10~(-6)。温度的升高有利于马尾藻在热解中CO和H_2的析出,反应的开始时间和完成时间均有所提前。在马尾藻与油页岩混合物的热解中,H2的析出在700℃时达到最高(体积分数峰值为1 254×10~(-6))。油页岩的加入迟滞了CO和H_2的排放时间。【结论】油页岩的加入有效减少马尾藻热解过程中CO的排放并缩短反应时间,提高效率节省能源,马尾藻与油页岩的混合热解具有良好的应用前景。     

An estimation of internal soliton forces on a pile in the ocean

Internal soliton forces on oil-platform piles in the ocean are estimated with the Morison Formula. Different from sur- face wave forces, which change only in magnitude along a pile, internal soliton forces can be distributed over the entire pile in the water and they change not only in magnitude but also in direction with depth. Our calculations show that the maximum total force caused by a soliton with its associated current of 2.1 m s-1 is nearly equal to the maximum total force exerted by a surface wave with a wavelength of 300 m and a wave-height of 18 m. The total internal soliton force is large enough to affect the operations of marine oil platforms and other facilities. Therefore, the influence of internal solitons should not be neglected in the design of oil platforms.     

喀左盆地九佛堂组露头高分辨率层序地层划分

在实测106 km剖面和对喀左盆地九佛堂组沉积特征及演化进行详细研究的基础上,依据相序关系,并结合碳酸钙、油页岩的成因意义,将九佛堂组划分了 1个长期基准面旋回和7个中期基准面旋回。在长期基准面旋回内,上升期的中期基准面旋回发育以上升半旋回为主的不完全对称型中期基准面旋回,上升与下降过渡期的中期基准面旋回,则发育近完全对称的中期基准面旋回,下降期的中期基准面旋回,则发育以下降半旋回为主的不完全对称型中期基准面旋回。经过对中期基准面旋回和短期基准面旋回发育特点和形成原因的详细研究,对代表剖面进行了中期基准面旋回对比。     

Test method and experimental research on resistance of oil shale under high temperature

Heating the oil shale by current underground to accomplish in-situ transformation process, is a viable direction. The electrical properties of oil shale under different temperatures, especially the resistance, become important. Charging oil shale underground to heat oil shale till kerogen’s decomposition temperature, then crude oil and other gases can be generated. The resistance of the oil shale samples was measured by Direct Current (DC) quadripole method to find out the variation rules of resistance value. In the experiments, oil shale presented its semiconductor property. When heated till 350℃-450℃, its resistance changed greatly, optional for heating and cracking. The porosity, oil content, media and composition affected the resistance largely.