鄂尔多斯盆地西峰油田原油地球化学特征及其成因

通过对鄂尔多斯盆地西峰油田原油进行系统地采样和高分辨率的GC-MS、IRMS分析,研究了原油的生物标志化合物和碳同位素组成特征,并且进行了油源对比,探讨了其成因。研究资料指示了所研究原油属于同一成因类型;原油有机母质为菌藻类和高等植物,特别是高等植物为原油的形成作出了贡献;原油形成于弱还原和淡水或微咸水环境;原油均为成熟原油;原油地球化学特征和上三叠统延长组长,油层组具有亲缘关系,反映了原油主要来源于长,油层组。这些研究结果为盆地的石油勘探提供了科学依据。     

Supercritical Carbon Dioxide Extraction of Organic Matter from Petroleum Source Rocks and Its Implications

Organic matter was experimentally extracted by supercritical fluids(CO2 1% isopropanol)from petroleum source rocks of different thermo-maturities at different buried depths in the same stratigraphic unit in the Dongying Basin.The results show that supercritical fluid extraction(SFE)is more effective than Soxhlet extraction(SE),with higher amounts and greater varieties of hydrocarbons and soluble organic matter becoming extractive.The supercritical CO2 extraction is therefore considered more valuable in evaluation of petroleum source rocks and oil resources,particularly those of immature types.     

长庆气田奥陶系风化壳气藏、气源研究

对10年来长庆气田奥陶系风化充气藏气源问题存在的不同观点（上古生界煤成气和奥陶系海相碳酸盐岩气何者为主）及相应的证据进行了总结和讨论,认为“奥陶系自生自储为主”的观点对地质和地球化学现象的解释存在疑问,包括用次要组分来判别混源天然气的主要来源,用不确切的端员气地球化学特征来计算混源比,对本溪组底部岩石的封盖性和下奥陶统碳酸盐岩的原始生烃潜力评价偏高,忽略了石炭系存在能够生成油型气的海相源岩。因此,长庆气田不能作为海相贫有机质的碳酸盐岩生成的大、中型油气田的实例。根据天然气及气源岩的地球化学特征,提出长庆气田奥陶系风化壳气藏气是以上古生界煤成气为主、石炭系海相源岩生成的油型气为辅的混合气。     

连续流态下好氧颗粒污泥的培养及处理制药废水的性能

在上流式好氧颗粒污泥床反应器中, 以厌氧颗粒污泥和好氧絮状活性污泥为接种泥, 采用人工配制的模拟废水, 成功培养出性能优异的好氧颗粒污泥.反应器内污泥浓度稳定在5g/L左右, 颗粒污泥粒径为0.5~2.0mm, 当进水COD为2000mg/L, 容积负荷为4.8kg/(m3·d)时, 系统对COD的去除率稳定在96%以上.通过扫描电镜观察, 好氧颗粒污泥是层状结构, 表面有大量丝状菌缠绕, 内部有短杆菌和空穴存在.逐步提高制药废水在进水中的比例, 经过47d的培养, 生物制药废水完全取代模拟废水, 系统对COD、NH₃-N、TP的去除率分别稳定在90%、90%和70%以上.      

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

三角洲前缘厚层砂岩孔隙结构及微观渗流特征——以吴仓堡地区长6储层为例

依据薄片、压汞、扫描电镜、物性分析及油水驱替实验资料,对吴仓堡地区三角洲前缘亚相长6厚层砂岩储层的岩石学特征、孔渗特征、孔隙结构特征、成岩作用、微观渗流特征等进行深入研究,分析影响储层储集性能的主控因素。结果表明,受东北物源控制的长6厚层砂岩储层具有成分成熟度中等、结构成熟度较好的特点,储集空间主要为残余粒间孔和粒间溶孔、粒内溶孔,为典型中低孔、特低渗储集层;储层储集性能主要受沉积微相和成岩作用控制。对储层发育影响最大的成岩期位于中成岩A期,中等压实－粘土膜胶结残余粒间孔发育成岩相和弱压实-残余粒间孔+溶蚀孔隙发育成岩相是最有利储层发育的成岩相带。根据微观渗流特征,可划分出4种驱油类型,微观孔隙结构比宏观物性更能反映储层的本质特征。     

准噶尔盆地深层致密油储层特征及致密化成因——以莫索湾—莫北地区侏罗系八道湾组为例

综合利用岩心、岩石薄片、扫描电镜及测井等资料,对准噶尔盆地莫索湾—莫北地区侏罗系八道湾组致密油储层特征及其致密化成因进行研究。结果表明:八道湾组储层为低—特低孔、低—特低渗储层,属典型的深层致密砂岩储层;储层砂体主要为三角洲前缘水下分流河道细砂岩、中—细砂岩,成分成熟度低,具有岩屑和塑性岩屑含量高及胶结物含量低的"两高一低"特征;垂向上以4 100和4 500m为界,可划分为减小原生孔、稳定混合孔及增加次生孔3个孔隙演化带;孔隙主要为中—小孔,孔喉类型以分选较差的中-细孔—细喉型为主,连通性和渗流能力相对较差,结构相对较差。储层致密化主要受控于沉积环境相对稳定性、岩石主要成分、储层埋藏深度及胶结物赋存状态4个因素,构成了致密化的背景、内因和外因;相对稳定的沉积环境、低成分成熟度、高岩屑和塑性岩屑含量、储层埋深大、压溶作用大量减孔,以及不同类型胶结物以4种状态充填孔喉,形成了八道湾组致密储层。     

用生物标志物定量计算混合原油油源的数学模型

多烃源层叠合盆地混源油油源的定量计算是十分困难的问题.典型原油的人工混合配比实验显示,当两个生物标志物浓度不同的原油相混合时,各类生物标志物的比值参数随端元原油混入量呈非线性变化,以生物标志物比值参数和简单的二元线性关系方程定量计算混源油的混合比例将导致错误的结论.三个或者三个以上原油相混合时,各类生物标志物比值参数的变化更加复杂,各端元原油的贡献更加难以判识.但是,人工混合模拟实验表明混合油中生物标志物绝对含量与端元油的混入量呈线性关系,数学推导证明了这种线性关系,由此推导出相应的数学计算模型,其中:二元混合时比值参数与混入量呈双曲线关系,三元混合呈双曲面关系,四元及其以上的多元混合呈多维曲面,可以矩阵的方式定量计算各端元油的比例.依据这些数学模型,应用生物标志物的绝对含量和(或)生物标志物比值参数均可以定量计算出混源原油中各类原油的贡献比例.数学模型比通常的人工模拟实验方法更加经济、方便、精确和可靠.     

储层原始含油饱和度计算方法研究

储层原始含油饱和度是评价储层的重要指标 ,它的计算方法有 :岩心直接测定方法、间接确定法和毛管压力曲线计算方法。简要地讨论了这几种方法 ,重点探讨了利用毛管压力曲线计算储层原始含油饱和度的方法 ,针对该方法目前使用中存在的问题进行了改进 ,并在该方法的理论基础上 ,结合新疆塔里木盆地北部的实例 ,提出一种便于利用毛管压力曲线计算储层原始含油饱和度的适用方法     

关于构造—地层分析及其油气勘探中的应用

构造－地层分析在研究层次上可分为（1）区域构造和深部过程对盆地形成与演化的控制；（2）构造几何学或断裂几何学对盆地或地层几何形态的控制；（3）单元构造样式和单元沉积型式的对应关系。在油气勘探中除了了解前两方面问题外，更重要的是研究后者。根据我国陆相裂谷盆地的特点，分析和讨论了构造－地层分析在油气勘探中的主要研究内容及其应用。