Volcanically Driven Terrestrial Environmental Perturbations during the Carnian Pluvial Episode in the Eastern Tethys

The Carnian Pluvial Episode (CPE) fingerprints global environmental perturbations and biological extinction on land and oceans and is potentially linked to the Wrangellia Large Igneous Province (LIP). However, the correlation between terrestrial environmental changes and Wrangellia volcanism in the Ordos Basin during the CPE remains poorly understood. Records of negative carbon isotopic excursions (NCIEs), mercury (Hg), Hg/TOC, and Hg enrichment factor (HgEF) from oil shales in a large-scale terrestrial Ordos Basin in the Eastern Tethys were correlated with marine and other terrestrial successions. The three significant NCIEs in the study section were consistently correlated with those in the CPE successions of Europe, the UK, and South and North China. The U-Pb geochronology indicates a Ladinian–Carnian age for the Chang 7 Member. A comprehensive overview of the geochronology, NCIE correlation, and previous bio- and chronostratigraphic frameworks shows that the Ladinian–Carnian boundary is located in the lower part of Chang 7 in the Yishicun section. HgEF may be a more reliable proxy for tracing volcanic eruptions than the Hg/TOC ratio because the accumulation rates of TOC content largely vary in terrestrial and marine successions. The records of Hg, Hg/TOC, HgEF, and NCIEs in the Ordos Basin aligned with Carnian successions worldwide and were marked by similar anomalies, indicating a global response to the Wrangellia LIP during the CPE. Anoxia, a warm-humid climate, enhancement of detrital input, and NCIEs are synchronous with the CPE interval in the Ordos Basin, which suggests that the CPE combined with the regional Qinling Orogeny should dominate the enhanced rate of terrigenous input and paleoenvironmental evolution in the Ordos Basin.     

中国春季气温异常变率的非线性特征

运用一种基于神经网络的非线性主成分分析法(NLPCA)对中国1951-2003年53 a春季气温距平场进行分析,结果表明,春季气温异常变率具有显著的非线性特征,当非线性主元u分别取最大值和最小值时,对应的空间气温异常分布型具有显著的非对称性.     

泌阳凹陷下二门油田油气成藏机制探讨

为了弄清下二门油田的油气成藏机理,利用包裹体、平衡剖面和生烃史模拟等技术,详细分析了其油气充注成藏过程,结果表明,早期(古近纪核二末期至核一末期)油气小规模缓慢充注,形成早期小规模油气藏;中期(古近纪廖庄期末构造抬升期)受差异抬升构造运动影响,油气大规模快速充注,形成中期大规模原生背斜油气藏;晚期(新近纪上寺组沉积末期)断裂发育,早、中期原生油气藏遭受破坏,同时深凹区核三下、上段生成的高成熟油气沿砂体侧向运移补给,油气大规模沿断层向上运移,遇遮挡形成大量次生油气藏和气藏。     

油气包裹体的显微红外光谱测试技术及应用

单一油气包裹体的成分一直是地质学家关注的焦点,它能为油气成藏研究提供最直接的证据。显微红外光谱技术可以测定单个油气包裹体的成分、分子结构和其中油气包裹体的成熟度。本文应用显微红外光谱技术、包裹体的鉴定和均一温度测定技术,分析了大庆探区海拉尔盆地乌27井、巴16井、希3井等样品的包裹体。研究表明,乌27井有过两期成藏,并以第二期为主;巴16井也有过两期主要成藏,且第二期具混源的特点;希3井只有一次主要成藏期。同时利用红外光谱的CH2/CH3值、Xinc、Xstd划分了三口井的油气成藏期次,结果与镜下鉴定结论相一致,并确定了其中油气包裹体的成熟度。本文还探讨了显微-红外光谱测试单一油气包裹体的发展方向。     

有机地球化学指标的分析

有机地球化学的指标经过近几十年的研究,已能较好地指导油气勘探工作。通过对未熟—低熟烃源岩及原油与成熟烃源岩及原油的有机地球化学指标的比较,着重论述了未熟—低熟油、源中可用的指标系列及内涵,指出成熟度方面甾烷C2920Rββ/(αα ββ)、αααC2920S/(20S 20R)及βα-莫烷/αβ-藿烷和ββ-藿烷等是比较可靠的地球化学参数;在生源方面非环状类异戊二烯化合物、三环萜烷和四环萜烷系列等是可靠的标志物;形成环境方面β-胡萝卜烷及重排甾烷/规则甾烷等都是重要的指标。     

地磁Z分量低点时间季节性变化研究

通过小波分析和频谱分析,发现Z分量低点时间的小波变换结果曲线(α=6)明显地随节气而变化;对地磁Z分量低点时间季节性变化进行了初步的比较分析.     

下二门油田H2Ⅲ油组交联聚合物驱后油藏剩余油分布特征

微观驱油试验表明,交联聚合物驱后剩余油进一步减少,主要以斑块状、小油滴状等形态分布于微孔隙中;数值模拟显示,下二门油田H2Ⅲ油组交联聚合物驱后80.8%的面积已为中强水淹,纵向上79.7%的剩余油分布于主力油层.受构造、储层物性及井网因素控制,未淹、弱水淹剩余油平面上主要分布在断层附近、断层破碎带、微构造高点和砂体上倾尖灭区等部位;纵向上主要分布于低渗透层段.针对剩余油分布特征,通过完善注采关系、优化注采结构,单元含水量的上升速度和产量递减幅度得到控制,采收率在交联聚合物驱的基础上进一步提高了2.01%.     

巴布亚盆地侏罗系陆架边缘三角洲沉积特征及其油气勘探方向

为明确巴布亚盆地主要的含油气系统发育层段——侏罗系的沉积特征及其与油气勘探的关系,在分析前人研究成果、沉积背景与古物源的基础上,通过地震相、测井相、岩心相"三相"联合分析及与周边的布劳斯盆地的类比,识别了沉积微相类型,刻画了沉积体系的纵横向展布特征;通过不同沉积相带生烃指标、储层物性参数对比,明确了有利的烃源岩与储层发...     

Coupled finite‐element simulation of injection well testing in unconsolidated oil sands reservoir

This paper presents a finite‐element (FE) model for simulating injection well testing in unconsolidated oil sands reservoir. In injection well testing, the bottom‐hole pressure (BHP) is monitored during the injection and shut‐in period. The flow characteristics of a reservoir can be determined from transient BHP data using conventional reservoir or well‐testing analysis. However, conventional reservoir or well‐testing analysis does not consider geomechanics coupling effects. This simplified assumption has limitations when applied to unconsolidated (uncemented) oil sands reservoirs because oil sands deform and dilate subjected to pressure variation. In addition, hydraulic fracturing may occur in unconsolidated oil sands when high water injection rate is used. This research is motivated in numerical modeling of injection well testing in unconsolidated oil sands reservoir considering the geomechanics coupling effects including hydraulic fracturing. To simulate the strong anisotropy in mechanical and hydraulic behaviour of unconsolidated oil sands induced by fluid injection in injection well testing, a nonlinear stress‐dependent poro‐elasto‐plastic constitutive model together with a strain‐induced anisotropic permeability model are formulated and implemented into a 3D FE simulator. The 3D FE model is used to history match the BHP response measured from an injection well in an oil sands reservoir. Copyright © 2013 John Wiley & Sons, Ltd.     

Thermal depolymerization of kerogen and formation of immature oil

Two Chinese immature oil shales from the continental deposits of kerogen type I and II have been thermally treated combined with the technique of supercritical fluid extraction at 630–650 K and 15–25 MPa in a semi-continuous laboratory scale apparatus. Toluence is selected as the solvent. Up to 70–80% of the kerogen matrix can be converted to a thermal bitumen and extracted simultaneously. The chemical structural parameters from the NMR, IR, XRD, ESR and EA analyses of the kerogen and the thermal bitumen show striking resemblance in nature. It implies that the thermal bitumen is primarily a depolymerized product of the kerogen. Based on the GC/MS spectra of the aliphatic eluate of the thermal bitumen, the predominance of the odd/even ratio of the alkanes and the epimeric ratios, such as 20S(20S + 20R) of C-29 steranes and 22S/(22S + 22R) of C-32 terpanes, show that the maturity of the thermal bitumen from these oil shales is comparable to that of commercial immature oils from East China. The thermal bitumen is thought to be an intermediate product of the thermal degradation of kerogen.Since the thermal bitumen is mainly composed of asphaltenes and resins, it has a structure of gel. The gel-state bitumen may turn to sol-state readily due to its low aromaticity and polarity, or due to selective adsorption of asphaltenes by clay minerals. Then the migration potential of the bitumen is enhanced.Consequently, under favorable geological conditions, the thermal depolymerization of kerogen seems to be a probable mechanism to explain the formation of immature oils.