Geochemistry of ice-covered, meromictic Lake A in the Canadian High Arctic

The geochemical processes occurring within meromictic Lake A (maxdepth 120 m) on northern Ellesmere Island, Canada, were investigated to determinethe history of the lake and to provide a baseline for future studies. The lake contained seawaterdiluted by freshwater input that had been mixed prior to the lake's isolation from tidalaction. Input of freshwater after isolation of the lake created vertical stratification resultingin the creation of distinct oxic, suboxic and anoxic zones. Dissolved oxygen was present to 13 m,and sulphide beneath 32 m. Manganese and iron cycling dominated the redox chemistrybetween these depths. Total manganese concentrations reached 176 M, higher thanin most other natural stratified lake or marine environments.     

内蒙古好老鹿场地区晚古生代超基性-基性岩的发现及意义

在内蒙古东部好老鹿场地区1∶5万区调工作中,发现了一套新的岩石组合,分别由铁镁质堆积岩、基性岩墙群、蚀变基性火山岩等组成。该套岩石组合经较强的构造破坏,呈大小不等的岩块产于本巴图组砂板岩之中。总体延伸方向呈近东西向展布,明显受区域性构造控制。岩石化学、岩石地球化学等方面的资料表明,辉石橄榄岩、辉长岩具有低A l、贫Ca和富Na的特点,MgO/(MgO FeO)比值为0.25,MgO含量偏低。稀土元素总量偏低,为76.03×10-6~114.81×10-6,轻重稀土富集不明显,分馏作用较弱。∑L/∑H为0.73~0.8,配分曲线呈平坦的“W”型,δEu=1.03~1.23,略显正异常。基性火山岩具明显的富Fe、Mg、Na,贫A l、Ti、K的特征,微量元素显示形成于洋中脊环境。同时在辉长岩中获得单颗粒锆石U Pb年龄为362.4 M a,时代为早泥盆世晚期。其形成环境为洋中脊,属于泥盆纪古亚洲洋消减部分的残留体。     

江西黄连坑锰矿成矿特征及成因探讨

江西省武宁县境内分布了众多的小型铁、锰矿床(点),前人称之为“武宁式”铁矿。通过对黄连坑锰矿区地层的含矿性、控矿构造及容矿构造、矿体特征、矿石类型等地质特征的论述,认为震旦系地层是“初始矿源层”,滑脱构造对成矿物质起迁移、富集及容矿作用。并与萍—乐断陷盆地内的沉积加热液叠改型乐华锰矿床进行了对比分析,二者在矿体规模、矿石类型、锰品位等方面存在显著差别,应属不同成因类型的矿床。初步认为黄连坑锰矿床属构造控矿、风化淋滤成因。     

Eclogite and carpholite-bearing metasedimentary rocks in the North Qilian suture zone, NW China: implications for Early Palaeozoic cold oceanic subduction and water transport into mantle

Low‐temperature eclogite and eclogite facies metapelite together with serpentinite and marble occur as blocks within foliated blueschist that was originated from greywacke matrix; they formed a high‐pressure low‐temperature (HPLT) subduction complex (mélange) in the North Qilian oceanic‐type suture zone, NW China. Phengite–eclogite (type I) and epidote–eclogite (type II) were recognized on the basis of mineral assemblage. Relic lawsonite and lawsonite pseudomorphs occur as inclusions in garnet from both types of eclogite. Garnet–omphacite–phengite geothermobarometry yields metamorphic conditions of 460–510 °C and 2.20–2.60 GPa for weakly deformed eclogite, and 475–500 °C and 1.75–1.95 GPa for strongly foliated eclogite. Eclogite facies metasediments include garnet–omphacite–phengite–glaucophane schist and various chloritoid‐bearing schists. Mg‐carpholite was identified in some high‐Mg chloritoid schists. P–T estimates yield 2.60–2.15 GPa and 495–540 °C for Grt–Omp–Phn–Gln schist, and 2.45–2.50 GPa and 525–530 °C for the Mg‐carpholite schist. Mineral assemblages and P–T estimates, together with isotopic ages, suggest that the oceanic lithosphere as well as pelagic to semi‐pelagic sediments have been subducted to the mantle depths (≥75 km) before 460 Ma. Blueschist facies retrogression occurred at c. 454–446 Ma and led to eclogite deformation and dehydration of lawsonite during exhumation. The peak P–Tconditions for eclogite and metapelite in the North Qilian suture zone demonstrate the existence of cold subduction‐zone gradients (6–7 °C km^?1), and this cold subduction brought a large amount of H₂O to the deep mantle in the Early Palaeozoic times.     

锰三角地区电解锰压滤渣高温可控脱硫生产活性微粉项目经济效益与社会效益分析

电解锰压滤渣是工业生产金属锰过程中采用湿法酸浸电解工艺产生的一种工业废渣。这种传统的废渣处理处置方式,极易造成严重的环境污染和地质灾害的发生。本次研究将电解锰压滤渣通过焙烧生产活性微粉、产生的脱硫烟气制硫酸,是一种能有效解决电解锰压滤渣处理处置和综合利用的方法。本文对"锰三角"地区拟建20万吨电解锰压滤渣焙烧生产活性微粉、脱硫烟气制硫酸生产示范线项目,进行了区域市场调研,对项目的经济效益与社会效益进行分析。该项目年均可实现销售收入4162.7万元,为当地循环经济和锰产业可持续发展探索了一条新的出路。     

Investigations of the effects of manganese addition to Dry Creek Saltfield brines

Trials conducted at Dry Creek, a solar saltfield north of Adelaide, Australia, indicate that manganese, as manganous sulphate, can increase both the purity and strength of salt crystals grown at an ambient or neutral-slightly acid pH range resulting in a salt suitable for high purity uses. The improved load bearing strength of the crystals indicates that manganous sulphate could also be useful in salt floor maintenance. However, the impact of an apparently slight rise in pH to 8.5 was significant. Crystals produced at the higher pH from the manganese enriched brine were opaque with many tiny, almost colloidal crystals. The salt did not drain well, had low load bearing strength and was notably impure.     

Extractable and total Fe and Mn contents of three sand dune soils in NW Nigeria

The profile distribution of total, diethylene triamine penta-acetic acid (DTPA)- and 0·1 HCl-extractable Fe and Mn were determined in 12 pedons formed on three contiguous sand dunes in the semi-arid savanna of Nigeria. The total Fe and Mn contents varied from 100 to 3750 and 40 to 11,375 μg g⁻¹, respectively. Values of 0·1 HCl-extractable Fe and Mn varied from 8·0 to 123 and 1·5 to 43·5 μg g⁻¹, respectively. The corresponding values of DTPA-extractable Fe and Mn were 4·5 to 16·0 and 1·0 to 38·8 μg g⁻¹. Total Fe and Mn correlated significantly with clay in nearly all the dunes (p≤ 0·01) but were not significantly correlated with organic matter. The 0·1 HCl-extractable Mn had a positive significant correlation with soil pH (r= 0·58*) in Illela dunes but a negative significant correlation with pH in the Sangiwa dunes (r= −0·75***). The values of extractable Fe and Mn in the sand dune soils are above the critical limits reported in other literature, thus deficiencies of these micronutrients do not pose a problem to crop production in the study area.     

The Canary Islands swell: a coherence analysis of bathymetry and gravity

The Canary Archipelago is an intraplate volcanic chain, located near the West African continental margin, emplaced on old oceanic lithosphere of Jurassic age, with an extended volcanic activity since Middle Miocene. The adjacent seafloor does not show the broad oceanic swell usually observed in hotspot-generated oceanic islands. However, the observation of a noticeable depth anomaly in the basement west of the Canaries might indicate that the swell is masked by a thick sedimentary cover and the influence of the Canarian volcanism. We use a spectral approach, based on coherence analysis, to determine the swell and its compensation mechanism. The coherence between gravity and topography indicates that the swell is caused by a subsurface load correlated with the surface volcanic load. The residual gravity/geoid anomaly indicates that the subsurface load extends 600 km SSW and 800 km N and NNE of the islands. We used computed depth anomalies from available deep seismic profiles to constrain the extent and amplitude of the basement uplift caused by a relatively low-density anomaly within the lithospheric mantle, and coherence analysis to constrain the elastic thickness of the lithosphere ( T_e ) and the compensation depth of the swell. Depth anomalies and coherence are well simulated with T_e =28–36 km, compensation depth of 40–65 km, and a negative density contrast within the lithosphere of ∼33 kg m⁻³. The density contrast corresponds to a temperature increment of ∼325°C, which we interpret to be partially maintained by a low-viscosity convective layer in the lowermost lithosphere, and which probably involves the shallower parts of the asthenosphere. This interpretation does not require a significant rejuvenation of the mechanical properties of the lithosphere.     

Five-Stage Model of the Palaeozoic Crustal Evolution in Xinjiang

The great majority of the Palaeozoic orogenjc belts of Central Asia are of the intercontinental type, whose evolution always follows a five-stage model, i.e. the basal continental crust-extensional transitional crust-oceanic crust-convergent transitional crust-new continental crust model. The stage for the extensional transitional crust is a pretty long, independent and inevitable phase. The dismembering mechanism of the basal continental crust becoming an extensional continental crust is delineated by the simple shear model put forward by Wernike (1981). The continental margins on the sides of a gently dipping detachment zone and moving along it are asymmetric: one side is of the nonmagmatic type and the other of the magmatic type with a typical bimodal volcanic formation. In the latter case, however, they were often confused with island arcs. This paper discusses the five-stage process of the crustal evolution of some typical orogenic belts in Xinjiang.