Numerical study of droplet size dependent chemistry in oceanic,wintertime stratus cloud at southern mid-latitudes

Cloud droplet chemistry is modelled for the first 150 m of rise in a wintertime, mid-latitude, marine stratus cloud using observations made at and near the Cape Grim Baseline Station as a source of input parameters. The emphasis in this work was to study the variation in droplet chemistry as a function of both droplet size and nucleus composition, with a particular focus on the way in which oxidation of dissolved sulfur dioxide varied.At 150 m above the condensation level, solute concentration as a function of droplet size was found to increase by as much as 2 to 3 orders of magnitude for only a factor of 2 increase in droplet radius, primarily as a consequence of the 1/r dependence in the droplet growth equation. This type of size dependence exists at all levels in the model cloud, and has a significant influence on oxidation rate of sulfur dioxide in droplets growing on sulfate nuclei, oxidation by ozone being favoured in the smallest droplets, but oxidation by hydrogen peroxide being favoured in the larger droplets. Oxidation by ozone is favoured at all sizes in droplets formed on sea-salt nuclei as a result of the initially high alkalinity of these droplets, and in the cloud overall is calculated to be the more important oxidation pathway. Although based on a simplified chemical scheme, these results suggest that both size-dependent and nucleus-dependent chemistry of cloud droplets may need to be considered explicitly in cloud modelling work.Volume-weighted mean pH values in the range 5 to 6 were predicted from sensitivity studies in which input variables were varied over reasonable ranges, in agreement with two sets of bulk cloud-water pH data obtained by aircraft near Cape Grim.     

Visualization experiments of iron precipitates: Application for in-situ arsenic remediation

Laboratory experiments were carried out to acquire more insight and understanding of the phenomena associated with the in-situ arsenic remediation. Visualization techniques are the most informative for the detection of Fe(II) while flowing in soils. Green Rust (GR) was considered as representative of in-situ iron precipitates. In a visualization flat cell, the change in color of GR to orange, due to oxidation, was monitored by a digital camera and the images were analyzed giving the spatial and temporal distribution of Fe(II). Moreover, both oxygen and pH changes in time were recorded in two sections along the flow direction in the cell. The measured and calculated concentration profiles were compared and the actual reaction rates were predicted. The reaction rate constants measured in this study, under flowing conditions, are in a good agreement with the values obtained from batch experiments reported in the literature.     

The effects of carbon dioxide leakage on fractures, and water quality of potable aquifers during geological sequestration of CO2

Since industrial revolution, the ＂greenhouse effect＂ is one of the most important global environmental issues. Of all the greenhouse gases, CO2 is responsible for about 64% of the enhanced ＂greenhouse effect＂, making it the target for mitigation, so reducing anthropogenic discharge of carbon dioxide attracts more and more attention. Geological sequestration of CO2 in deep saline aquifers is one of the most promising options. But because unknown fractures and faults may exist in the caprock layers which can prevent the leakage of CO2, CO2 will leak upward into upper potable aquifers, and lead to adverse impacts on the shallow potable aquifers. In order to assess the potential effect of CO2 leakage from underground storage reservoirs on fractures and water quality of potable aquifers, this study used the non-isothermal reactive geochemical transport code TOUGHREACT developed by Xu et al to establish a simplified 2-D model of CO2 underground sequestration system, which includes deep saline aquifers, caprock layers, and shallow potable aquifers, and study and analyze the changes of mineral and aqueous components. The simulation results indicated that the minerals of deep saline aquifers and fractures should be mainly composed of aluminosilicate and silicate minerals, which not only enhance the mass of CO2 sequestrated by mineral trapping, but also decrease the porosity and permeability of caprock layers and fractures to prevent and reduce CO2 leakage. The results from deep saline aquifers showed that the mass of carbon dioxide trapped by minerals and solution phases is limited, the rest remained as a supercritical phase, and so once the caprock aquifers have some unknown fractures, the free carbon dioxide phase may leak from CO2 geologic sequestration reservoirs by buoyancy.     

A Bay–River Coupled Model for Storm Surge Prediction Along the Andhra Coast of India

The paper describes a two-dimensional bay–river coupled numerical model for storm surges along the Andhra coast of India. The effect of the Krishna and Godavari rivers on the surge development is analysed. A comparative study of the surge generated by a tropical cyclone with and without the inclusion of rivers is done in detail. Three cyclones that struck the Andhra coast in November 1977, May 1990 and November 1996 were used for the simulation studies. It is found that the idealized model without a river overestimates the sea-level elevation as compared to a more realistic bay–river coupled model. The temporal variation of surge values at the mouth of the rivers is also studied for all three cyclone cases. It is found that the effect of the presence of rivers depends on the strength of the cyclone, its point of landfall and the location of the rivers with respect to the landfall point.     

A traveltime reciprocity discrepancy in the Podvin & Lecomte time3d finite difference algorithm

We have found that the extensively used finite difference scheme time3d produces time fields which are 'asymmetric' in the sense that traveltimes computed to the right of the source are faster than traveltimes computed to the left. All finite difference schemes will, as they are approximations to the wave equation, to some extent fail to obey reciprocity perfectly. We show, however, that the errors in time3d may be significant—and unnecessarily large. An asymmetry in the point source initialization has been identified, and after correction time3d produces time fields with an improved reciprocity.     

考虑滑脱效应和温度场的煤层气渗流数值模拟

由于煤层气的解吸热效应,煤层气的运移过程是一个非等温过程。因此,温度场对煤层气渗流有着重要的影响。前人在研究煤层气渗流规律的研究中并没有同时考虑滑脱效应和温度场因素的影响,而在实际的深部开采中综合考虑滑脱效应和温度场的影响对研究深部煤层气运移规律有着重要的意义。因此本文建立了考虑滑脱效应及温度场的煤层气渗流数学模型,利用有限元数值方法研究了考虑滑脱效应和温度场耦合的煤层气运移规律;研究了考虑滑脱效应和温度场对压力场分布的影响;对考虑滑脱效应及温度场因素的煤层气产量进行了预测。得出了随着温度的升高煤储层的压力在降低,温度的升高对煤层气的产量有着负面的影响这一重要结论。     

Construction techniques for the Taklamakan Desert Highway: research on the construction materials and the results of field tests

After conducting many laboratory and field experiments, several key technical issues related to the construction of China’s Taklamakan Desert Highway have been satisfactorily resolved. In particular, considerable progress has been made on the dry compaction of a sand sub-base, road design parameters, the creation of a structure that combines a sub-grade and asphalt pavement, analysis of the stability of a sand sub-base strengthened with geotextiles, and on the development of a complete set of construction techniques. The achievements of this research were successfully applied for the first time in the Taklamakan Desert, where the environmental conditions are extremely harsh. The results suggest that the construction of this highway was economical and that the simple construction methods produced a reliable highway. The resulting highway is believed to be the world’s first long-distance graded highway running through a huge desert with migrating dunes.     

GLONASS广播星历用户算法精度分析

分析了GLONASS广播星历的用户算法，指出由于星历参数表示及用户算法的不完善对轨道拟合精度带来损失；分析了用户算法的误差源，并对其大小进行了计算。结果显示，在利用GLONASS广播星历采用数值积分时，由于模型的简化卫星位置计算的精度损失可达0．5m。