利用电磁方法探测内蒙古塔木素高放废物预选场址岩体的内部构造

高放废物地质处置库选址要求围岩完整稳定,它与岩体深部地质结构密切相关,因此是场址评价中必须考虑的因素.在高放废物储库选址新区内蒙阿拉善塔木素岩体,采用可控源音频大地电磁法进行了剖面探测.分析了典型测深曲线,区分了地质构造和完整围岩的响应特征;针对高放废物预选场址的特点,对原始数据进行了处理;结合已有地质、钻井及测井资料完成了解释;结果表明,利用可控源音频大地电磁法有效地查明了该地岩体内部结构,该岩体存在裂隙和破碎,完整性欠佳.     

Mineralization of Catechol by Fenton and Photo‐Fenton Processes

Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe²⁺, 7.09 mM H₂O₂, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.     

米尺度裂隙岩体模型水流-传热试验的数值模拟分析

为了研究高放射性核废物地下处置库近场的水流-传热耦合问题,采用国内高放废物地下处置库预选场址--甘肃北山地区的花岗岩石块体,加工组合成米尺度的规则裂隙岩体模型,设置边界热源和裂隙水流,试验模拟裂隙水水流与传热之间的相互作用。作为该室内模型试验的前期理论研究,采用等效孔隙介质数值模型,着重分析了裂隙开度、裂隙流量和热源功率对流场和温度场的影响。在设定条件下,计算分析表明：热传导和裂隙水水流由热源作用初期的不耦合很快转化为耦合;不流动的裂隙水主要表现为热存储和热传导,而流动的裂隙水还引起流动传热和水与岩石之间的对流换热,使岩体温度场明显不同于单纯热传导的情况;如果保持裂隙水流量不变,则裂隙开度的变化对水流-传热影响不大;如果保持裂隙水流速不变,则裂隙开度的变化对水流-传热影响显著;热源功率越大,通过裂隙水的热流量越大,裂隙水压强越大,而当温度超过100 ℃时,裂隙水会因汽化而压强显著增大;加热7 d时,热量的输入和输出几乎相等,裂隙水流带走的热量接近热源供给的热量,模型系统基本达到了热平衡。     

浙江省突发性地质灾害应急空间辅助决策支持系统设计与实现

浙江省是我国东南沿海经济较发达的省份,但同时也是地质灾害多发频发的省份。近年来随着极端天气增多,我省各级行政管理部门的地质灾害应急工作面临着前所未有的挑战。本文介绍了我省突发性地质灾害应急空间辅助决策支持系统建设情况,提出了地质灾害应急辅助决策所涉及到的多源异构数据融合与集成的技术方法,构建了从灾（险）情报送、信息收集与分析、灾（险）情评价、专家会商到最终科学决策的突发性地质灾害空间辅助决策支持系统。本系统的建设极大的提高了我省突发性地质灾害应急决策能力,对其他省份的突发性地质灾害应急辅助决策支持系统的建设具有一定的参考价值。     

西南省域地震灾害耦合因素分析

利用西南震害资料,对西南省域（云南、四川、重庆、西藏、贵州）在一定时空尺度上M≥5．0历史地震事件活动水平及震害特征进行系统分析,找出地震灾害（包括人员伤亡、经济损失、次生灾害等）的时间发展特征、空间分布特征和强度分级特征;研究地震灾害与西南区域人口分布、经济水平、地形地貌、人文因素之间的耦合关系,为进一步减轻、减少地震灾害应急处置的不确定性和风险性提供有效建议。     

新鲜生活垃圾压缩与直剪联合测定试验研究

在环境土工实验室人工配制了新鲜生活垃圾,采用大型压缩与直剪联合测定仪器,对96个新鲜垃圾试样进行了压缩变形、剪应力及剪应变联合测定试验,研究了垃圾的压缩变形对强度的影响及规律。试样的初始孔隙比分别为2.1、2.5、2.9,试样竖向压力分别为25、50、100、200 kPa,每级压力作用下的时间分别为0、0.25、0.5、1、2、6、12、24 h。试验研究表明,（1）不同压缩时间下剪应力与剪应变的关系符合双曲线模型,模型参数a在0.028～0.144之间,参数b在0.012～0.024之间;（2）不同竖向压力及不同剪应变限值下抗剪强度与竖向压缩应变（压缩时间）的关系可以拟合成多项式的形式,得到了参数的拟合值及相关系数,相关系数在0.63～0.98之间;（3）不同初始孔隙比的抗剪强度与竖向压力的关系符合库仑定律,得到了不同剪应变限值的抗剪强度参数,黏聚力在11.1～34.2 kPa之间,内摩擦角在 11.2°～30.6°之间。     

Monitoring of organic micropollutants in Ghana by combination of pellet watch with sediment analysis: E-waste as a source of PCBs

Plastic resin pellets collected at 11 beaches covering the whole Ghanaian coastline were analyzed for polychlorinated biphenyls (PCBs). PCB concentrations (∑13 congeners) were higher in Accra, capital city, and Tema (39–69 ng/g-pellets) than those in rural coastal towns (1–15 ng/g-pellets) which are close to global background, indicating local inputs of PCBs. River sediments were also analyzed for PCBs together with molecular markers. Sedimentary PCBs concentrations were highest at a site (AR02) downstream of an electronic waste (e-waste) scrapyard. At the site (AR02), concentration of linear alkylbenzenes (LABs), a marker of municipal wastewater, was lower than another site (AR03) which is located at the downstream of downtown Accra. This result suggests that PCBs are introduced more to the river from the e-waste site than from activities in downtown Accra. PAHs concentrations were relatively higher in urban areas with strong petrogenic signature. Abundance of triphenylbenzenes suggested plastic combustion near e-waste scrapyard.