京津冀地区霾成因机制研究进展与展望

为满足当前对京津冀地区霾研究和控制的迫切要求,本文梳理了近年来京津冀地区霾的长期变化特征、天气学特征、污染物来源等相关研究成果,发现:从2000年以后,京津冀地区的霾日数呈现出了下降趋势;北京细颗粒物(PM2.5)质量浓度也在总体上呈现下降的趋势,但2013年年均质量浓度仍高达89.5μg m–3,约为我国空气质量标准的3倍(35μg m–3),京津冀空气污染的形势依然严峻;近年来京津冀地区的霾污染事件频发可以归因为不利天气条件与大量污染物人为排放的共同作用;大量的研究表明,区域输送对京津冀地区霾事件的形成和维持有不可忽视的影响;京津冀地区的大气污染不再局限于一时一地,针对重污染天气的预警以及应急控制应该以区域预报为基础实现区域联动;京津冀地区独特的地理环境条件加上城市群的快速发展,形成的局地大气环流也会对局地的污染过程产生重大的影响;大气边界层内气象要素的变化对重污染发生具有显著贡献。京津冀地区的污染控制需要城市群的联动应对治理。     

Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr–Nd–Pb isotope data on the Roccamonfina volcanic rocks,Roman Magmatic Province,Southern Italy

The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca. 400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera Roccamonfina volcano. On the basis of new trace element and Sr–Nd–Pb isotope data, we show that the Roccamonfina shoshonitic rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes. The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at Cs, K, Th, U, and Pb. Initial values of ⁸⁷Sr/⁸⁶Sr range from 0.70926 to 0.70999, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788–18.851 for ²⁰⁶Pb/²⁰⁴Pb, 15.685–15.701 for ²⁰⁷Pb/²⁰⁴Pb, and 39.048–39.076 for ²⁰⁸Pb/²⁰⁴Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand, shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks. ⁸⁷Sr/⁸⁶Sr ranges from 0.70665 to 0.70745, ¹⁴³Nd/¹⁴⁴Nd ranges from 0.51234 to 0.51238, ²⁰⁶Pb/²⁰⁴Pb ranges from 18.924 to 19.153, ²⁰⁷Pb/²⁰⁴Pb ranges from 15.661 to 15.694, and ²⁰⁸Pb/²⁰⁴Pb ranges from 39.084 to 39.212. High-K calc-alkaline samples have intermediate isotopic values between ultrapotassic plagioclase leucitites and shoshonites, but the lowest levels of incompatible trace element contents. It is argued that ultrapotassic magmas were generated in a modified lithospheric mantle after crustal-derived metasomatism. Interaction between the metasomatic agent and lithospheric upper mantle produced a low-melting point metasomatised veined network. The partial melting of the veins alone produced pre-caldera leucite-bearing ultrapotassic magmas. It was possibly triggered by either post-collisional isotherms relaxation or increasing T°C due increasing heat flow through slab tears. Shoshonitic magmas were generated by further melting, at higher temperature, of the same metasomatic assemblage with addition 10–20% of OIB-like astenospheric mantle material. We suggest that addition of astenospheric upper mantle material from foreland mantle, flowing through slab tearing after collision was achieved. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

西秦岭北缘新阳—元龙韧性剪切带中花岗质糜棱岩黑云母40Ar 39Ar年龄及地质意义

西秦岭北缘新阳-元龙大型韧性剪切带是分划西秦岭造山带与祁连造山带的区域主构造边界,通过对其物质组成和构造特征的研究,结合两侧不同(洋-陆)构造环境下各类地质体的研究成果,重点对剪切带内花岗质糜棱岩中黑云母单矿物进行了~(40)Ar-~(39)Ar定年研究.在新阳镇和元龙北剪切带中分别获得(347.95±2.17)Ma (MSWD＝1.89)和(351.70±1.72)Ma (MSWD＝0.80)的坪年龄,分析确定其应为黑云母的冷却年龄,表明变形时代应在早石炭世早期之前;反映了最晚在早石炭世早期,该剪切带已横切秦岭与祁连造山带并发生强烈的右行走滑构造拼贴作用.     

河北舍女寺油田女12—女20断块孔二段沉积微相与油气聚集关系研究

黄骅坳陷南部舍女寺油田的古近系孔店组是在断陷盆地的快速充填过程中形成的典型的河流—三角洲沉积。根据取芯井段的取芯和测井资料分析,把剖面结构、砂体几何形态、沉积构造等微相特征进行描述和分析,划分出水下分流河道、河口坝、席状砂等储层沉积微相类型。研究表明,舍女寺地区沉积微相不仅控制储集层的分布,而且控制油气聚集。研究区中较大厚度的油层分布在水下分流河道的中心部位,即该区沉积微相带的主体部位起着油层控制作用。在复杂断块高含水开发中后期,微突起、微断层、微断鼻等圈闭和储集层的有利配置区,尤其是中心微相带与有利的微构造部位叠合区将是有利高产井区。     

关于敦化盆地下白垩统的讨论

前人根据敦化盆地的地层的地层,认为该盆地下白垩统为河流—湖泊相碎屑岩。通过对新钻的敦参1井岩屑录井资料的分析、对16条二维地震资料的层位标定与追踪,以及对敦化盆地早白垩世盆地演化阶段的分析,得到了以下主要结论:1)敦化盆地下白垩统可能有两种分布形态,在盆地的主体部位,以浅变质岩形态存在,而在其他部位则以正常沉积岩形态零星存在;2)敦化盆地白垩系的分布规模不大,夹持于一个北北东向的狭窄长槽内;3)敦化盆地早白垩世处于裂谷盆地发展的初始张裂阶段;4)敦化盆地下白垩统不宜作为勘探目的层。     

豫西熊耳山寨凹钼矿床辉钼矿铼-锇年龄及其地质意义

寨凹钼矿床位于河南熊耳山地区,是新近发现的穿插于太古宙太华岩群深变质岩中的辉钼矿石英脉型钼矿床.为了获得该钼矿床的成矿年龄,从10件采自辉钼矿石英脉的样品中挑选出辉钼矿单矿物进行Re-Os同位素年龄测定.10件辉钼矿样品22次测定结果的年龄最小值为(1 680±24)Ma,最大值为(1 831±29)Ma.其中10件辉钼矿粗粒(自然粒度)状态下13次测定结果的等时线年龄为(1 686±67)Ma,MSWD=16;4件研磨后粉末状辉钼矿9次测定结果的等时线年龄为(1 804±12)Ma,MSWD=1.09.两条等时线的仞始<'187>Os值在误差范围内接近于0,表明<'187>Os全部由Re衰变而来.上述结果表明,寨凹钼矿床形成于17～18亿年的中元古代早期,是目前中国已知最老的钼矿床,为中元古代早期华北克拉通伸展-裂解环境中构造-岩浆热事件所伴随的热液成矿作用的产物,与熊耳群火山岩浆活动有密切的时空和成因联系;辉钼矿的Re含量为4.832×10<'-6>～0.665×10<'6>,平均3.045×10<'-6>,表明成矿物质可能来自围岩地层.东秦岭地区从元古宙到印支期、燕山期的铜矿化构成该区的钼成矿谱系,寨凹钼矿床可能是该谱系中最早的端员.     

西藏班公湖岛弧带含硫化镍超基性岩的源区性质与基底背景

青藏高原班公湖一怒江成矿带上的超基性岩型硫化镍矿化是近年来在西藏地区发现的矿化新类型.文章根据成矿带西段班公湖地区含镍超基性岩体的岩石地球化学和Sr、Pb同位素分析结果,论述了含镍超基性岩浆的源区性质及生成条件,并根据锆石U-Pb LA-ICP-MS年龄测定结果,探讨了藏西北地区的基底背景.研究发现,班公湖地区的含镍超基性岩体以富集大离子不相容元素Rb、Th、U、Sr、Pb,亏损Ba、K为特点,高场强元素亏损Nb、Ti,富集Ta;稀士元素相对球粒陨石亏损强烈,但轻稀土元素相对富集.这些特点一致反映出含矿岩浆产生于受俯冲沉积物熔体交代的富集型岩石圈地幔源区.岩浆的生成深度较浅,为尖晶石二辉橄榄岩相,源区部分熔融程度较低,大体在10%左右.岩石中集中出现一批24.79亿年的残留锆石年龄,标志着当时班公湖中特斯洋盆沉积物的物源区较为单一,主要来自太古代末-元古代初的古老基底,并且推测太古代与元古代之交(25亿年)有可能是藏西北的一个古陆壳快速生长期.     

珞珈一号夜间灯光数据的福建省人为热通量估算

夜间灯光数据是估算人为热通量（AHF）的重要数据,但当前应用最广的DMSP/OLS和Suomi-NPP/VIIRS夜间灯光数据由于受限于粗糙的空间分辨率,而无法刻画城市内部的AHF分布细节。中国2018年6月发射的Luojia 1-01卫星所获取的130 m高空间分辨率夜间灯光数据,则有望解决这一问题。因此本文利用Luojia 1-01夜间灯光数据,通过将统计年鉴中的能源统计数据细化至福建省84个县（市、区）,然后与3个夜间灯光指数（NTL_nor、HSI、VANUI）进行回归分析,分别构建了基于这3个指数的福建省AHF空间估算模型,并采用交叉验证法对其进行筛选。结果显示：（1）在3个指数中,基于VANUI的乘幂估算模型的R²最高,且RMSE最小,因此精度最高;（2）利用VANUI乘幂估算模型反演得到的2018年福建省年均AHF为0.88 W/m²,其中厦门市的年均AHF最高,达10.98 W/m²,泉州、莆田、福州、漳州等沿海城市次之,年均值在0.98—1.95 W/m²,而宁德、龙岩、三明、南平等城市的AHF则较低,均值在0.38—0.46 W/m²;（3）Luojia 1-01夜间灯光数据可以揭示城市内部的AHF分异细节。根据用地属性和功能的不同,AHF数值表现为：城市集中商业区>大型市政公共设施区>城市主干道>城市住宅区>近郊住宅区。研究表明,基于Luojia 1-01夜间灯光数据建立的AHF估算模型可以较好地揭示城市尺度AHF的空间分异情况。     

同构造沉积分析反演逆冲构造变形过程--燕山东段凌源南部中生代逆冲构造变形过程研究

介绍了同构造沉积分析的基本概念、研究思路、主要研究方法及其在区域构造变形过程研究中的重要作用。基于对辽西凌源南部区域构造变形、晚侏罗世土城子组同构造沉积粗碎屑沉积物成分变化规律的研究 ,获得如下主要认识 :( 1)同构造沉积始于髫髻山组火山活动之后 ;沉积物成分变化及古水动力特征表明 ,同构造沉积物源区主体位于盆地西侧褶皱隆起区 ,而不是来自南东方向的大型逆冲断层上盘的前渊沉积 ;而且显示了正常层序的物源区倾斜岩层的剥蚀和揭顶过程 ;当时的剥蚀作用已达中元古界蓟县系雾迷山组上部。 ( 2 )分布于郭家店盆地和邓杖子盆地之间的中元古界长城系地层“残片” ,与其东侧北票组间为向SEE逆冲的断层接触 ,而西侧与土城子组 (原邓杖子组 )之间为不整合接触 ;在老虎沟东南长城系地层“残片”不复存在的区域 ,土城子组不整合于北票组之上。该“残片”很可能是髫髻山组火山活动之前指向SEE的逆冲构造变形形成的飞来峰构造的残余部分。( 3 )凌源南部中生代逆冲构造变形可以区分为 :早侏罗世北票组之前 (印支期 )由北向南的逆冲作用、北票组之后髫髻山组之前向SEE的冲断推覆、髫髻山组之后的逆冲褶皱变形与同构造沉积作用以及九佛堂组之后局部的逆冲作用。指向SEE的主要逆冲作用以及伴生褶皱变形     

Giant Mineral Deposits and Their Geodynamic Setting in the Lanping Basin, Yunnan, China

There are giant mineral deposits, including the Jinding Zn-Pb and Baiyangping Ag-Co-Cu, and otherimportant mineral deposits (e.g., Baiyangchang Ag-Cu, Jinman Cu deposits, etc.) in the Lanping Mesozoic-Cenozoic Basin, Yunnan Province, China. The tabular ore-bodies and some veins hosted in terrestrial clastic rocks of the Mesozoic-Cenozoic age and no outcropping of igneous rocks in the giant deposits lead to the proposal of syngenetic origin, but the giant mineral deposits are not stratabound (e.g. MVT, sandstone- and Sedex-type). They formed in a continental red basin with intense crust movement. The mineralization is controlled by structures and lithology and occurs in different strata, and no sedimentary nature and no exhalative sediments are identified in the deposits. The deposits show some relations with organic matter (now asphalt and petroleum) and evaporates (gypsum). The middle-low-temperature (mainly 110℃ to 280℃) mineralization took place at a depth of about 0.9 km to 3.1 km during the early