川滇西部地区钾质煌斑岩特征及其成因

川滇西部地区钾质煌斑岩带产物扬子板块西缘与三江褶皱带之间的过渡地带，侵位于老第三系地层。岩石化学特点具有中等含量钾、钛和钠、铝弱饱和，属岛弧环境的钙碱性煌斑岩与板内环境的钾镁煌斑岩（超钾）之间的过渡类型。微量元素Sr相对于Rb,Ba,K等元素具有明显的负异常，是地幔交代作用的产物。区域上与其伴生的壳源型花岗岩侵位在前，分布于西侧；碱性岩层中；钾质煌斑岩侵位在后，分布于东侧，属反序侵位序列，为喜山期陆壳碰撞、褶皱造山运动所触发的被动地幔作用产物。     

A variationally consistent hyperstatic reaction method for tunnel lining design

In this technical note, a consistent finite element formulation of the Hyperstatic Reaction Method (HRM) for tunnel linings design is proposed by introducing a variational consistently linearized formulation. It permits to consider a nonlinear interaction between a lining structure and the surrounding ground. Recent advances of the HRM in regard to the consideration of the nonlinear response of the segmented tunnel lining exposed to design loads use an iterative algorithm for solving the nonlinear system of equations. In the proposed Variationally consistent Hyperstatic Reaction Method (VHRM), a distributed nonlinear spring model representing the interaction between the lining and the ground soils is considered in a variationally consistent format. Computing the tangential spring stiffness via consistent linearization, and using Newton-Raphson iteration, requires significantly smaller number of iterations as compared to the original HRM model based on nodal springs. Furthermore, the method is applicable for simulations using solid finite elements (2D and 3D), as well as beam or finite shell elements, respectively.     

近平衡状态海水中方解石和文石沉淀速率及动力学研究

利用"freedrift"开放反应系统,研究人工海水中近沉淀平衡状态时二氧化碳分压(p(CO2))的变化对方解石、文石沉淀速率及其动力学方程的影响.反应在恒定的温度(25.0℃±0.2℃)、p(CO2)环境下进行,通过实验得到了不同p(CO2)环境下,方解石和丈石的沉淀速率及动力学方程.研究发现:(1)晶体类型和碳酸盐...     

氧气反应模式-电感耦合等离子体串联质谱法测定土壤中的镉

应用电感耦合等离子体质谱法(ICP-MS)分析土壤中的镉元素时,锆的氢氧化物、钼的氧化物、锡的同位素会对镉造成严重的干扰,导致准确测定土壤中镉的难度较大.本文采用电感耦合等离子体串接质谱法(ICP-MS/MS),选取无同质异位素干扰的111 Cd为分析谱线,在MS/MS模式下碰撞反应池中通入的氧气可以与94Zr16O1...