A study on the reaction kinetics of mineral surface adsorption in mix system

The experimental results on adsorption of ions pb²⁺, Zn²⁺ and Ag⁺ onto mineral surfaces in a mix system show that the reaction kinetics of adions adsorbed onto mineral surfaces was mainly controlled by their diffusion rates in solution. The concentration variations can be fit for the second-order rate equation with good determined coefficients r = 0.800 5—0.979 7. In the near neutral solution, the concentration of exchanged ions K⁺ and Na⁺ related to reaction time can be described by the fint-order rate equation with r = 0.855 7–0.997 7. Meanwhile, the complex diffusionexchange rate equation is suitable for describing the ca^{2 +} concentration variation, as ions Pb^{2 +} and Zn²⁺ were adions. Experimental data show that the amount of ions K⁺, Na⁺and Ca²⁺ release is much more than that of adion decrement in solution. This fact may suggest that the complexstion reaction of adions Pb²⁺, Z²⁺ and Ag⁺ with the mineral surfaces was the major reaction process while adions were not entering the phyllosilicate interlayers or CaCO₃ lattice to exchange the ions K⁺, Na⁺ and Ca²⁺ at room temperature. Project supported by the National Natural Science Foundation of China (Grant No. 49773206) and the Natural Science Foundation of Guangdong Province (Grant No. 960504)     

Generation of rhyolite magmas by melting of subducting sediments in Shodo-Shima island, Southwest Japan, and its bearing on the origin of high-Mg andesites

Abstract Geochemical characteristics of rhyolites from the Miocene Setouchi volcanic belt in the Southwest Japan arc were examined. The following observations may be best explained by the derivation of rhyolite magmas by melting of subducting sediments as follows. (i) Sr-Nd-Pb isotope compositions of Setouchi rhyolites are close to those of the local trench-fill sediments; (ii) major element compositions of rhyolites are identical to those of experimentally produced sediment melts; and (iii) concentrations of incompatible elements in rhyolites are consistent with partial melting of the local trench-fill sediments in the presence of residual garnet. Furthermore, trace element and isotope signatures of Setouchi high-Mg andesites can be also rationalized by interaction of such rhyolitic sediment melts with overlying mantle peridotites.     

基于小比例缩尺模型结构试验的小型钢架反力墙优化设计与力学性能分析

为了降低模型制作加工成本和节约试验空间,开展结构缩尺比例小于1:10的小模型结构抗震试验。目前,国内相关的试验设备较少,本文将参考大型反力墙的结构形式,研究小型钢架反力墙,并对其进行优化设计和力学性能分析,为后续的制作加工提供理论依据。     

强震下高层建筑横向晃动反应过程模拟分析

传统的静力弹塑性分析方法对强震作用下的高层建筑的横向晃动反应过程模拟时,存在计算结果不准确、计算用时较长的问题。提出新的强震下高层建筑横向晃动反应过程模拟分析方法,其基于直接积分法的三种方法实施模拟分析。分别是隐式方法、显式方法以及KK模型方法。其中隐式方法和显式方法均能够对不同自由度下的高层建筑的横向晃动位移作出准确的计算,KK模型通过高层建筑Von Mises屈服面,分析高层建筑钢材Bauschinger反应基础上,精确模拟出高层建筑在横向晃动反应中的变形过程。实验结果说明,所提方法对强震作用下的高层建筑的横向晃动反应的运算准确率和效率较高。     

Analytical design of an underwater construction robot on the slope with an up-cutting mode operation of a cutter bar

In this paper, the movements of the analytical models of complete underwater tracked vehicle (UTV) and cutter bar (CB) tool systems on a surface as well as their movements up and down a slope in the up-cutting mode operation are fully studied and analyzed. First, the mathematical expression of the mechanics, for which the forces, moments, and energy from the CB to the UTV are analyzed, is related. Next, analyses on the systemic parameters and their sensitivity are conducted to observe the variations of the operational and geometric parameters, as well as the cutter-tool and material-condition effects on the force, moment, and power components. Also, a design process composed of seven typical steps is proposed as the reference of a trencher-machine design. The important design parameters of the trenching machine such as the length of the CB, the nose radius of the CB, and the height of the pivot point are designed according to the proposed design process; furthermore, these parameters are used for the estimation of the slope-angle range when the trencher system is working on the slope. To demonstrate the application of derived equations to practical problems of the machine design, a number of numerical simulations are performed. Through the numerical simulations, the important parameters of the system such as the tangential force, F_t, the tractive thrust, H, the normal reaction, V, the cutting moment, M_c, the maximum carrier weight, W, and the available power are analyzed. From these, as a reference data for the designing of a trencher machine, the previous design of the system can be improved.     

广东省和江苏省大气甲醛时空变化对比分析

利用Aura/OMI月均甲醛对流层垂直柱浓度数据对2005年—2016年中国广东省和江苏省的大气甲醛的时空变化规律、不同排放源的前体物的潜在贡献进行了分析。甲醛在广东省主要集中在珠三角地区,在江苏省分布则相对较为均匀。2005年—2010年,随着经济发展,在两省都发现了大面积的甲醛增加趋势;相应的,在2011年—2016年,由于减排等治理措施的实施,在两省都有大面积的甲醛减少现象。广东省的甲醛主要呈现出春季、秋季高于冬季再高于夏季的特征;而江苏地区夏季甲醛浓度远高于其他季节,并与光照强度的季节性特征较为一致。此外,由于广东省甲醛分布的均一性较差,因此区域性因素(如地形等)对广东省甲醛分布可能有着较大的影响。各个排放源中,工业源、交通源对珠三角潜在贡献可能较大;自然源对梅州等林地覆盖地区可能有相对较高的影响;在江苏省,各个排放源对甲醛的贡献相对均衡,但夏季较为频繁的生物质燃烧可能对夏季高值甲醛有着相对较高的贡献。     

一类有限隐非齐次马尔可夫模型的混合性

研究了隐非齐次马尔可夫模型的混合性,首先给出并证明了非齐次马尔可夫链满足混合性的充分条件,然后将所得结果推广到了隐非齐次马尔可夫模型上,对进一步研究隐马尔可大模型提供了理论基础,且能为实际问题如弱相依随机变量的建模、发音过程、神经生理学和生物遗传学等领域的研究提供理论依据.     

慢速扩张脊下的复杂熔-岩相互作用：来自大西洋北纬14°97′区段洋中脊含铬铁矿纯橄岩的记录

在大西洋洋中脊北纬14°97′附近贫岩浆型慢速扩张脊区段的洋底岩石调查中,拖网取样及洋底钻探均发现蛇纹石化地幔岩石中有脉状纯橄岩。纯橄岩中的铬铁矿粒度以毫米级为主,个别颗粒直径接近厘米级别,成分上显示中等程度的铬值与镁值(Cr^#=52.2～56.1;Mg^#=44.6～51.5)较高的TiO₂含量(0.60%～0.91%)。铬铁矿内部包裹体中大量出现韭闪石+金云母组合,并发现自形磷灰石包裹体。这些特征与“俯冲带型铬铁矿”的成分特征及矿物包裹体组合非常类似。本文的样品观察说明在洋中脊下方的熔体通道内,高度演化的熔体可以形成小体积的富水岩浆并参与铬铁矿的形成。拖网调查与钻探研究证实,研究区的纯橄岩、异剥橄榄岩、富橄榄石橄长岩、辉石岩、辉长岩及橄榄辉长岩等均以脉体形式产于难熔的大洋岩石圈橄榄岩质地幔中。这些脉状岩石共同记录了洋中脊玄武质熔体向上迁移过程中与围岩方辉橄榄岩间的熔-岩反应,属于“交代橄榄岩”的范畴,揭示了慢速扩张洋脊之下熔体迁移诱发的复杂熔-岩相互作用。     

虾蟹壳氨基葡萄糖-半胱氨酸美拉德反应产物对酪氨酸酶的抑制作用

为了探讨半胱氨酸-氨糖美拉德反应产物(GCMRPs)对酪氨酸酶催化活性的影响及其在对虾冷藏保鲜中的作用,以半胱氨酸及虾蟹壳氨基葡萄糖盐酸盐为原料,在碱性条件下(pH=10)制备美拉德反应产物,并分别测定其酪氨酸酶二酚酶活抑制能力及对南美白对虾黑变腐败的影响。结果显示,GCMRPs具有很强的二酚酶活抑制能力,对酪氨酸酶二酚酶活的抑制类型为不可逆的竞争性抑制。通过比较,在同浓度下,其抑制酪氨酸酶二酚酶活能力比半胱氨酸、曲酸更为优越,可做为一种有效的酶抑制剂。同时,鲜虾保鲜实验显示该产物有很好的防止黑变的能力,且有一定的防腐能力。     

南极冰藻 Chlamydomonas sp.ICE-L的 cDNA文库构建及品质检测

为构建南极冰藻Chlamydomonassp.ICE-L的cDNA文库,提取对数生长期南极冰藻ICE-L的总RNA,以此为模板,通过PowerScript逆转录酶逆转录合成第一链cDNA;再以第一链cDNA产物为模板,用LD-PCR合成第二链cDNA。该cDNA产物经分级分离转入大肠杆菌中,即获得南极冰藻ICE-L的cDNA原始文库,其滴度为1.6×106cfu/mL。扩增后的cDNA文库的滴度为1.0×1010cfu/mL。用PCR方法测得文库的重组率大于97%,插入cDNA的长度为0.5~1.8 kb,0.9 kb以上插入片段占50%以上。取适量扩增文库稀释并铺平板,挑取72个独立菌落,对其中22个独立菌落所插入的cDNA进行测序,克隆到了一个具有5′和3′非编码区的40S ribosomalprotein S5全长基因序列,GenBank收录号为AM167929。