ICP—AES法同时测定高纯氧化钇中稀土及非稀土杂质元素方法研究

本文提出了用ＩＣＰ－ＡＥＳ法直接同时测定高纯氧化钇中１４个稀土和１６个非稀土杂质元素的分析方法，对被测元素的 谱线、氧化钇基本及背景影响进行了研究，用标准加入法测出氧化钇基准中的微量杂质元素，消除了由于忽略基准中的杂质元素含量给高纯氧化钇分析测定带来的误差，同时对工作条件进行了优化。方法中各被测元素的检出限为0.003～1.31ug/g，能够满足生产过程中的质量控制及进出口商品检验     

Toxic Cyanobacteria in Greek Freshwaters, 1987—2000: Occurrence,Toxicity, and Impacts in the Mediterranean Region

In a survey in Greece from 1987 to 2000 hepatotoxic cyanobacterial blooms were observed in 9 out of 33 freshwaters. Microcystins (MCYSTs) were detected by HPLC in 7 of these lakes, and the total MCYST concentration per scum dry weight ranged from 50.3 to 1638 ± 464 μg g^—1. Cyanobacterial genera (Microcystis, Anabaena, Anabaenopsis, Aphanizomenon, Cylindrospermopsis) with known toxin producing taxa were present in 31 freshwaters. From our data and a review of the literature, it would appear that Mediterranean countries are more likely 1) to have toxic cyanobacterial blooms consisting of Microcystis spp. and 2) to have higher intracellular MCYST concentrations. A case study in Lake Kastoria is used to highlight seasonal patterns of cyanobacterial and MCYST‐LR occurrence and to assess cyanotoxin risk. Cyanobacterial biovolume was high (> 11 μL L^—1) throughout the year and was in excess of Guidance Level 2 (10 μL L^—1) proposed by WHO for recreational waters and Alert Level 2 for drinking water. Further, surface water samples from April to November exceeded Guidance Level 3, with the potential for acute cyanobacterial poisoning. Intracellular MCYST‐LR concentrations (max 3186 μg L^—1) exceeded the WHO guideline for drinking water (1 μg L^—1) from September to November with a high risk of adverse health effects. Preliminary evidence indicates that in 3 lakes microcystins are accumulated in some aquatic organisms. Generally, a high risk level can be deduced from the data for the Mediterranean region.     

Bedload transport resistance in rough open‐channel flows

During bedload movement by saltation, streamwise momentum is transferred from the ?ow to the saltating grains. When the grains collide with other grains on the bed or in the ?ow, streamwise momentum is reduced, and there is a decrease in streamwise ?ow velocity and an increase in ?ow resistance, herein termed bedload transport resistance f_bt. Based on experiments in two ?umes with ?xed and mobile plane beds and previously published data, an equation is developed that may be used to predict f_bt for both capacity and non‐capacity ?ows. The variables in this equation are identi?ed by dimensional analysis and the coef?cients are determined by non‐linear regression. This equation applies to rough turbulent open‐channel ?ows, where the relative submergence is between 1 and 20 and the entire sediment load moves by saltation. An investigation of the relative magnitudes of f_bt and grain resistance f_c suggests that where dimensionless shear stress θ is less than 1 and saltation is the dominant mode of bedload transport, f_bt/f_c increases with θ but never exceeds 1. Copyright © 2004 John Wiley & Sons, Ltd.     

Hydrological connectivity of soil pipes determined by ground‐penetrating radar tracer detection

Soil pipes are common and important features of many catchments, particularly in semi‐arid and humid areas, and can contribute a large proportion of runoff to river systems. They may also signi?cantly in?uence catchment sediment and solute yield. However, there are often problems in ?nding and de?ning soil pipe networks which are located deep below the surface. Ground‐penetrating radar (GPR) has been used for non‐destructive identi?cation and mapping of soil pipes in blanket peat catchments. While GPR can identify subsurface cavities, it cannot alone determine hydrological connectivity between one cavity and another. This paper presents results from an experiment to test the ability of GPR to establish hydrological connectivity between pipes through use of a tracer solution. Sodium chloride was injected into pipe cavities previously detected by the radar. The GPR was placed downslope of the injection points and positioned on the ground directly above detected soil pipes. The resultant radargrams showed signi?cant changes in re?ectance from some cavities and no change from others. Pipe waters were sampled in order to check the radar results. Changes in electrical conductivity of the pipe water could be detected by the GPR, without data post‐processing, when background levels were increased by more than approximately twofold. It was thus possible to rapidly determine hydrological connectivity of soil pipes within dense pipe networks across hillslopes without ground disturbance. It was also possible to remotely measure travel times through pipe systems; the passing of the salt wave below the GPR produced an easily detectable signal on the radargram which required no post‐processing. The technique should allow remote sensing of water sources and sinks for soil pipes below the surface. The improved understanding of ?owpath connectivity will be important for understanding water delivery, solutional and particulate denudation, and hydrological and geomorphological model development. Copyright © 2004 John Wiley & Sons, Ltd.     

A hybrid method for size characterization of coarse subsurface fluvial sediments

This paper introduces and evaluates a novel method for ascertaining the grain‐size distribution of subsurface sediments that involves profoundly less sampling effort than standard methods. It is based on hybrid sampling principles previously applied to the construction of synthetic surface grain‐size distributions. The method is developed from an empirical demonstration of the approximate similarity of surface and subsurface grain‐size distributions when compared over a common range of sizes. Subsurface hybrid models are found to provide good facsimiles of grain‐size distributions de?ned using standard criteria and to yield distribution percentiles with millimetre accuracy. The technique is presented as an expedient alternative to standard methods for large, perennial gravel‐bed rivers. As this is a new technique, prudent application is advised in lieu of further investigation. Copyright © 2004 John Wiley & Sons, Ltd.     

Comparison of hydraulic geometry between sand‐ and gravel‐bed rivers in relation to channel pattern discrimination

A comparison has been made between the hydraulic geometry of sand‐ and gravel‐bed rivers, based on data from alluvial rivers around the world. The results indicate a signi?cant difference in hydraulic geometry among sand‐ and gravel‐bed rivers with different channel patterns. On this basis, some diagrams for discrimination of meandering and braided channel patterns have been established. The relationships between channel width and water discharge, between channel depth and water discharge, between width–depth ratio and water discharge and between channel slope and water discharge can all be used for channel pattern discrimination. The relationship between channel width and channel depth can also be used for channel pattern discrimination. However, the accuracy of these relationships for channel pattern discrimination varies, and the depth–discharge relationship is a better discriminator of pattern type than the classic slope–discharge function. The cause for this difference has been explained qualitatively. To predict the development of channel patterns under different natural conditions, the pattern discriminator should be searched on the basis of independent or at least semi‐independent variables. The relationship between stream power and bed material grain size can be used to discriminate channel patterns, which shows a better result than the discriminator using the slope–discharge relationship. Copyright © 2004 John Wiley & Sons, Ltd.     

An experimental study on seismic responses of multifunctional vibration‐absorption reinforced concrete megaframe structures

Two models are tested on a shake‐table. One of the models is a normal reinforced concrete megaframe structure and the other is a multifunctional vibration‐absorption reinforced concrete megaframe structure in which the laminated rubber bearings are placed between the major frame and the minor frames. Two earthquake motions (the El Centro wave and the Taft wave) are used during the test. This paper presents the dynamic characteristic, the seismic responses and the failure mechanism of these two models under varying peak acceleration levels for each of the earthquake motions. The test results demonstrate that the aseismic behavior of a multifunctional vibration‐absorption reinforced concrete megaframe structure is much better than that of a normal reinforced concrete megaframe structure. Copyright © 2003 John Wiley & Sons, Ltd.     

Dynamic performance of twin curved cable‐stayed bridges

The dynamic behaviour of two curved cable‐stayed bridges, recently constructed in northern Italy, has been investigated by full‐scale testing and theoretical models. Two different excitation techniques were employed in the dynamic tests: traffic‐induced ambient vibrations and free vibrations. Since the modal behaviour identified from the two types of test are very well correlated and a greater number of normal modes was detected during ambient vibration tests, the validity of the ambient vibration survey is assessed in view of future monitoring. For both bridges, 11 vibration modes were identified in the frequency range of 0ndash;10Hz, being a one‐to‐one correspondence between the observed modes of the two bridges. Successively, the information obtained from the field tests was used to validate and improve 3D finite elements so that the dynamic performance of the two systems were assessed and compared based on both the experimental results and the updated theoretical models. Copyright © 2003 John Wiley & Sons, Ltd.     

The effect of an interface boundary layer on the resonance properties of a buried structure

This paper presents a model for the analysis of the diffraction of plane waves at a cavity in an infinite homogeneous linear elastic medium supported by a segmented lining. An elastic boundary layer is introduced between the cavity lining and the infinite medium. The boundary layer is simulated by ‘elastic boundary conditions’ in which the stress is proportional to the relative displacement of the lining and of the surrounding medium boundary. A closed‐form analytical solution of the problem was obtained using the Fourier–Bessel series, the convergence of which was proven. It was shown that the number of series terms required to obtain a desired level of accuracy can be determined in advance. Using amplitude–frequency response analysis it was shown that the boundary layer produces additional ‘pseudo‐resonance’ frequencies that depend on the layer properties. These frequencies are almost identical to the eigenvalues obtained from the simple analysis of a segmented elastically supported lining. Copyright © 2003 John Wiley & Sons, Ltd.