自燃煤有机地球化学特征研究

通过有机地球化学研究，发现神府、焦坪、灵武三种自燃煤的ＣＨ２Ｃｌ２抽提率、族组分组成、有机地球化学参数有较大的差别。色谱曲线表现为两种类型，即单峰型和双峰型。生物标志物组合也有较大的差别。由于这种有机地球化学特征的不同，导致了自燃煤的自燃属性的不同。因而，有机地球化学方法可以用于自燃煤的研究。     

Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.     

油气资源遥感勘查新方法

地下深处的油气藏中的烃类物质,在压力梯度下会向地表产生微渗漏,导致地表物质产生一系列理化异常,在地表形成吸附烃异常、红层退色、粘土化、碳酸盐化、放射性异常和地植物异常等标志。根据这些地表标志的地物波谱特征,选择出油气资源遥感勘查的最佳工作波段,在此基础上,以机载遥感信息为主,以星载遥感信息为辅,以地表地球化学、地植物学、地面遥感勘查作为验证手段,最终施行多元信息复合分析,可达到寻找油气藏的目的。     

Earthquake prediction in northeast India—A review

A multidimensional geophysical approach is made to study earthquake precursors in northeast India. Resistivity, gravity and seismological precursor anomalies for the two recent damaging earthquakes, one on December 30, 1984, magnitude 5.8, and the other on August 6, 1988, magnitude 7.5, are very encouraging to intensify these studies in the region. Improved methods of magnetic and geohydrological precursor studies are suggested.     

On the scavenging of SO2 by cloud and rain drops: IV. A wind tunnel and theoretical study of the absorption of SO2 in the ppb(v) range by water drops in the presence of H2O2

An experimental study involving the Mainz vertical wind tunnel is described where the rate of SO₂ removed from the air by freely suspended water drops was measured for SO₂ concentrations in the gas phase ranging between 50 and 500 ppb, and for various H₂O₂ concentrations in the liquid phase. In a first set of experiments, the pH inside the SO₂ absorbing drops was monitored by means of colour pH indicators added to the drops. In a second set of experiments, the amount of SO₂ scavenged by the drops was determined as sulfate by an ionchromatograph after the drops had been removed from the vertical air stream of the wind tunnel after various times of exposure to SO₂. The results of our experimental study were compared with the theoretical gas diffusion model of Walcek and Pruppacher which was reformulated for the case of SO₂ concentrations in the ppbv(v) range for which the main resistance to diffusion lies in the gas phase surrounding the drop. Excellent agreement between experiment and theory was obtained. Encouraged by this agreement, the theory was used to investigate the rate of sulfate production inside a drop as a function of pH. The sulfate production rate, which includes transport and oxidation, was compared with the production rate based on bulk equilibrium, as cited in the literature.     

四川威远气田烃流体包裹体的研究

通过烃流体包裹体的类型、均一化温度、气相及液相成分、盐度以及同位素的研究,可以认为威远气田的天然气主要是由白云岩中有机质形成。由于从80～160℃到200～240℃的热解作用,有机物质已演化到过成热阶段。这一过程可由白云岩中存在液态烃及含沥青烃流体包裹体得到证明。威远气田的特征是:震旦系白云岩中天然气的自产自储,以CH_4为主;油田水为古海水,盐度(4.3～17.2)wt%NaCl,pH>8,(CO+CH_4)/CO_2比值指示还原条件。在基底花岗岩石英中发现有气态烃包裹体,其成分及δ~(13)C‰与花岗岩储气层中产出的天然气一致,为部分天然气可能来自深部地壳或地幔提供了新的证据。因而,威远气田天然气的成因主要由有机物质形成,部分甲烷气可能经基底断裂来自地球深处。     

A numerical simulation of gas flow during coal/gas outbursts

Summary A model of the gas flow in airways during an instantaneous outburst of coal and gas is formulated and solved numerically using MacCormack's explicit finite-difference scheme. This model is based on the assumption that geological structures, in-situ stresses and high-gas-pressure gradients play important roles in initiating an outburst, with the gas content and gas-pressure gradients being the most dominant factors. The fluid-dynamic processes that occur after an outburst are computed by the numerical integration of the complete time-dependent Navier-Stokes equations. The mixture velocity, the density and the gas-concentration profiles in both time and space domains (immediately after an outburst) are presented. The global results are useful in gaining an improved understanding of gas-flow patterns during coal/gas outbursts and in determining the range of the disturbance so that effective methods of control can be developed.Nomenclature a speed of sound - C gas concentration (mass) - C _v specific heat at constant volume - C _p specific heat at constant pressure - CFL Courant-Friedrichs-Lewy number - E total energy of the mixture - F the vector defined in Equation 27 - G the vector defined in Equation 28 - h entropy - h _i entropy at inlet - J _xi diffusion flux in the i-direction - k thermal conductivity of a gas - M Mach number - P pressure of a mixture (the partial pressure of gas) - P gas pressure - P _a atmospheric pressure     

21世纪能源与环境的前沿问题——天然气水合物

天然气水合物资源极为丰富。据国外专家估算，水合物中的天然气总资源超过了包括煤炭、石油与常规天然气在内的所有已知可燃矿产的储量。天然气水合物层是油气聚集的极好盖层，可以作为勘探油气藏的标志。天然气水合物还是影响全球气候变化的重要温室气体之一的甲烷的重要源和汇。因此，进行天然气水合物研究对开拓２１世纪能源、完善油气成藏理论、解决天然气工业生产和输送过程的管进堵塞问题，以及探讨其与全球气候变化的关系问题均有重大意义。目前应开展的研究内容与重点课题包括：天然气水合物的成因机制与油气成藏演化规律；分布规律及有利蕴藏地区；物化特性及其生成与消除的方法；天然气水合物与全球气候变化的关系等。     

A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.