砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系     

In-Situ Observation of Fluid Mud in the North Passage of Yangtze Estuary, China

Observations of fluid mud were made in the lower North Passage of the Yangtze Estuary in February 2000, on 10 -11 August 2000, on 30 - 31 August 2000 (after two strong typhoons), on 21 - 24 August 2000 (neap tide) and on 3 -6 September 2000 (mean tide) respectively. In situ data show that the fluid mud in this area consists of fine cohesive sediment (median size 7.23 μm). The formation and movement of fluid mud varied during the neap-spring and flood-ebb tidal cycle. Observations suggest that fluid mud phenomena in this area may be categorised in a three-fold manner as slack water, storm and saltwedge features. The thickness of the fluid mud layer of slack water during the neap tide ranged from 0.2 to 0.96 m, whereas during the mean tide, the thickness ranged from 0.17 to 0.73 m, and the thickness of the fluid mud layer was larger during slack water than at the flood peak. Shoals cover an area of 800 km^2 with a water depth smaller than 5 m. Erosion of these extensive intertidal mudflats due to storm action provides an abundant sediment source. This is particularly significant in this estuary when the tidal level is lower than 5 m. The lower North Passage is a typical zone of saltwater wedging, so the saltwedge fluid mud has the most extensive spatial range in the estuary.     

碳水化合物的组合合成

碳水化合物的组合合成是一项新兴技术，该技术可以在短时间内合成大量用于进行生物活性筛选的寡糖及拟糖物。液相与固相合成技术可以极大地加快药物研究与开发进程。作者针对该技术在碳水化合物合成方面的研究进展情况进行讨论。     

The Effect of Internal Fluid on the Response of Vortex-Induced Vibration of Marine Risers

Based on Iwan‘s wake oseillator model developed with the classical van der Pol equalion, the differential equation for the response of the vortex-induced vihration (VIV) of the riser considering the effect of the internal flowing fluid and the external marine environmental condition is derived. The effect of the intermal flowing fluid on the response of VIV of the riser is studied by means of the Finite Element Method. The results show that the effect of the internal fluid velocity on the VIV of the riser is strong when the natural frequency of the riser is close to the vortex shedding frequency. In addition, the increase of the top tension can decrease the sensitivity of the riser to the internal fluid velocity.     

Salt Diapirs, Salt Brine Seeps, Pockmarks and Surficial Sediment Creep and Slides in the Canary Channel off NW Africa

Circular to elliptical mounds in the Canary Channel with reliefs of 75 to 375 m and diameters of 4 to 8 km partially surrounded by moats with reliefs of 25 to 75 m, were formed by piercement of the seafloor by Mesozoic evaporites. Several long gullies, < 1km wide, with abrupt terminations and pockmarks associated with these mounds were probably eroded by dense brine and hydrocarbon seeps. The salt brines that eroded the gullies were formed where salt diapirs intersect the seafloor, or in the subsurface by circulating ground water heated by igneous activity along the Canary Ridge. If the brines originated in the subsurface they reached the seafloor along faults. Displacement of the surficial sediments by sliding and creep is probably the result of the expulsion of hydrocarbons and/or vertical motion of the Mesozoic evaporites. Microtopographic features along or near the east flank of the Canary Ridge are the creation of uplift of the ridge, hydrothermal activity, mass wasting processes and turbidity currents.     

现代黄河三角洲粉土触变性研究及其应用

通过对现代黄河三角洲砂质粉土和粉质粘土触变性的对比试验研究，阐述了黄河口粉土的触变性。试验结果对解释粉土的失稳机制、解决工程地基的稳定性和防止地质灾害等具有重要的现实意义。     

Experimental Investigation of Instantaneous Properties of Wave Slamming on the Plate

The purpose of this paper is to investigate the instantaneous properties of wave slamming on the plate structure of an open structure.The advanced instantaneous measuring technique-Particle Image Velocimetry(PIV) is applied to acquire the instantaneous velocity field of wave slamming.From the cross-correlation analysis results of the images captured by the CCD camera,the flow fields of wave impacting on the structure are displayed visually,and the instantaneous whole-field fluid velocity vectors are obtained.The relation between the instantaneous peak impacting pressures and the instantaneous velocities of water particles is studied by probability analysis.     

The Structure of A Turbulent Jet in A Crossflow-Effect of Jet-Crossflow Velocity

A comprehensive numerical study on the three-dimensional structure of a turbulent jet in crossflow is performed. The jet-to-crossflow velocity ratio (R) varies in the range of 2 - 16; both vertical jets and inclined jets without excess streamwise momentum are considered. The numerical results of the Standard two-equation k-ε model show that the turbulent structure can be broadly categorised according to the jet-to-crossflow velocity ratio. For strong to moderate jet discharges, i.e. R> 4, the jet is characterized by a longitudinal transition through a bent-over phase during which the jet becomes almost parallel with the main freestream, to a sectional vortex-pair flow with double concentration maxima; the computed flow details and scalar mixing characteristics can be described by self-similar relations beyond a dimensionless distance of around 20-60. The similarity coefficients are only weakly dependent on R. The cross-section scalar field is kidney-shaped and bifurcated, vvith distinct double concentr     

层结流体中的非线性惯性重力内波

根据地球流体力学基本方程组,在密度垂直层结的情况下,引进行波坐标,研究非线性定形波在相平面上的几何拓扑结构。严格论证了不存在定形孤立波,并通过Ｈａｍｉｌｔｏｎ函数及其角作用变把行波系统化成最简形式,由此而得到非线性惯性重力内波的解析解。     

海洋环境荷载下输液立管的静、动力特性研究

考虑管内流动流体和管外海洋环境荷载共同作用 ,建立海洋立管侧向运动微分方程。用Hermite插值函数离散 ,在微机上编写海洋立管静、动力分析程序 ,通过计算分析研究管内流体对立管侧向变形和应力的作用 ;另外 ,探讨管内流体的流动速度和立管顶端的预张力对立管动力特性的影响。结果表明 ,立管变形和应力均随管内流体流动速度增加而增大 ,同时内流速度的增大会降低立管的固有频率 ,但适当增大立管顶端预张力会抵消内流流速增加引起的固有频率下降。