Exploring hyperspectral bands and estimation indices for leaf nitrogen accumulation in wheat

Hyperspectral sensing can provide an effective means for fast and non-destructive estimation of leaf nitrogen (N) status in crop plants. The objectives of this study were to design a new method to extract hyperspectral spectrum information, to explore sensitive spectral bands, suitable bandwidth and best vegetation indices based on precise analysis of ground-based hyperspectral information, and to develop regression models for estimating leaf N accumulation per unit soil area (LNA, g N m⁻²) in winter wheat (Triticum aestivum L.). Three field experiments were conducted with different N rates and cultivar types in three consecutive growing seasons, and time-course measurements were taken on canopy hyperspectral reflectance and LNA under the various treatments. Then, normalized difference spectral indices (NDSI) and ratio spectral indices (RSI) based on the original spectrum and the first derivative spectrum were constructed within the range of 350–2500 nm, and their relationships with LNA were quantified. The results showed that both LNA and canopy hyperspectral reflectance in wheat changed with varied N rates, with consistent patterns across different cultivars and seasons. The sensitive spectral bands for LNA existed mainly within visible and near infrared regions. The best spectral indices for estimating LNA in wheat were found to be NDSI (R₈₆₀, R₇₂₀), RSI (R₉₉₀, R₇₂₀), NDSI (FD₇₃₆, FD₅₂₆) and RSI (FD₇₂₅, FD₅₁₆), and the regression models based on the above four spectral indices were formulated as Y = 26.34x^1.887, Y = 5.095x − 6.040, Y = 0.609 e^3.008x and Y = 0.388x^1.260, respectively, with R² greater than 0.81. Furthermore, expanding the bandwidth of NDSI (R₈₆₀, R₇₂₀) and RSI (R₉₉₀, R₇₂₀) from 1 nm to 100 nm at 1 nm interval produced the LNA monitoring models with similar performance within about 33 nm and 23 nm bandwidth, respectively, over which the statistical parameters of the models became less stable. From testing of the derived equations, the model for LNA estimation on NDSI (R₈₆₀, R₇₂₀), RSI (R₉₉₀, R₇₂₀), NDSI (FD₇₃₆, FD₅₂₆) and RSI (FD₇₂₅, FD₅₁₆) gave R² over 0.79 with more satisfactory performance than previously reported models and physical models in wheat. It can be concluded that the present hyperspectral parameters of NDSI (R₈₆₀, R₇₂₀), RSI (R₉₉₀, R₇₂₀), NDSI (FD₇₃₆, FD₅₂₆) and RSI (FD₇₂₅, FD₅₁₆) can be reliably used for estimating LNA in winter wheat.     

The composition of nutrient fluxes from contrasting UK river basins

Accurate estimates of N and P loads were obtained for four contrasting UK river basins over a complete annual cycle. The fractionation of these loads into dissolved and particulate, and inorganic and organic components allowed a detailed examination of the nutrient load composition and of the factors influencing both the relative and absolute magnitude of these components. The particulate phosphorus (TPP) loads account for 26–75% of the annual total phosphorus (TP) transport and are predominantly inorganic. The inorganic (PIP) and organic (POP) fractions of the TPP loads represent 20–47% and 6–28% of the annual TP transport, respectively. In contrast, the particulate nitrogen loads (TPN) represent 8% or less of the annual total nitrogen (TN) loads and are predominately organic. For dissolved P transport, the dissolved inorganic fraction (DIP) is more important, representing 15–70% of the TP loads, whereas the dissolved organic fraction (DOP) represents only 3–9% of the TP loads. The TN loads are dominated by the dissolved component and more particularly the total oxidized fraction (TON), which is composed of nitrate and nitrite and represents 76–82% of the annual TN transport. The remaining dissolved N species, ammonium (NH₄-N) and organic N (DON) account for 0·3–1·2% and 13–16% of the annual TN transport, respectively. The TPN and TPP fluxes closely reflect the suspended sediment dynamics of the study basins, which are in turn controlled by basin size and morphology. The dissolved inorganic nutrient fluxes are influenced by point source inputs to the study basins, especially for P, although the TON flux is primarily influenced by diffuse source contributions and the hydrological connectivity between the river and its catchment area. The dissolved organic fractions are closely related to the dissolved organic carbon (DOC) dynamics, which are in turn influenced by land use and basin size. The magnitude of the NH₄-N fraction was dependent on the proximity of the monitoring station to point source discharges, because of rapid nitrification within the water column. However, during storm events, desorption from suspended sediment may be temporarily important. Both the magnitude and relative contribution of the different nutrient fractions exhibit significant seasonal variability in response to the hydrological regime, sediment mobilization, the degree of dilution of point source inputs and biological processes. © 1998 John Wiley & Sons, Ltd.     

有机化学物质碳氮稳定同位素系列标准物质研制

实验室和研究人员所使用的碳、氮同位素标准物质一般由国际原子能机构(IAEA)获得,然而近年来,随着碳氮同位素在实验室质量监控、方法评价、仪器校准等方面的广泛应用,市场需求量不断增加, IAEA研制的碳、氮同位素标准物质的种类与数量逐渐不能满足科学研究快速发展的需求。我国急需研制适应当今分析技术水平的有机质碳氮同位素国家标准物质用以进行质量监控、方法评价、仪器校准。为保证量值传递精度,本文研制了4个有机化学物质的碳氮稳定同位素标准物质,其中3个为尿素样品,1个为L-谷氨酸。经检验4种标准物质的均匀性通过F值检验,标准物质的δ~(13)C和δ~(15)N值经过一年的稳定性检验,特征量值变化在测量方法允许的不确定度范围内,由此判定δ~(13)C和δ~(15)N值稳定性良好。由包括研制单位实验室在内的12家实验室协同定值,采用高温燃烧-气体同位素质谱法测定了δ~(13)C和δ~(15)N值,系列标准物质δ~(13)C和δ~(15)N认定值区间呈梯度分布,δ~(13)C值为-40‰～0‰,δ~(15)N值为-10‰～30‰,涵盖了我国天然样品中有机质碳氮稳定同位素组成范围;研制的系列标准物质δ~(13)C的定值扩展不确定度不大于0.08‰,δ~(15)N的定值扩展不确定度不大于0.09‰,定值水平与国际标准物质相当。该系列标准物质已被国家质检总局批准为国家一级标准物质,批准号为GBW04494～GBW04497。可被用于地质、生态、环境等多种样品δ~(13)C和δ~(15)N比值测定时的分析监控、仪器校准、方法评价、质量保证和质量监控。     

青藏高原高寒草地小流域水体碳氮输出特征及其影响因素

以青藏高原长江源区典型高寒草地小流域为研究对象,基于2012年小流域气象监测数据和小流域径流水样分析,探讨了小流域水体碳氮输出特征,分析了气象因子和土壤水热对小流域水体碳氮输出的影响。结果表明,径流水体碳氮质量浓度均较低,其中可溶性有机碳(DOC)、可溶性有机氮(DON)、铵态氮(NH4+-N)和硝态氮(NO3--N)含量分别在2.95~6.96mg.L-1、0.45~1.15mg.L-1、0.02~0.88mg.L-1和0.16~0.36mg.L-1之间;DOC、DON、NO3--N在8~10月份之间随时间逐渐升高,9月中旬达到峰值后波动下降,NH4+-N无显著的季节变化特征,溶解氮中DONNO3--NNH4+-N;DOC和DON的输出量与降水、不同土层(20、40、60、90、120cm)地温和不同深度(10、20、40、60cm)土壤水分、水温呈极显著正相关(P0.001),与90、120cm土壤水分呈极显著负相关(P0.001);NH4+-N的输出量与降水、气温、水温呈显著正相关(P0.05);NO3--N与降水呈极显著正相关(P0.001)。     

Chemistry of throughfall,stemfall and litterfall in fertilized and irrigated Pinus radiata

The chemical inputs by rainfall, throughfall and stemflow were studied in a pine plantation located in Pierces Creek Forest, Canberra, Australia. Three treatments were included in the study: a control (C) and two fertilizer treatments. The first fertilizer treatment (F) involved two applications of mixed fertilizers at high rates, the second (IL) involved application of a complete liquid fertilizer with irrigation, so as to remove nutrient and water restrictions to growth. The application rates of nutrients were higher for IL than F. Net inputs of elements in throughfall and stemflow, obtained by subtracting the amounts in the rainfall, were compared for different treatments. For cations (the sum of Ca, Mg, Na and K), the treatment effect on leaching by throughfall and stemflow was IL > F > C; but the F to C differences were greater for throughfall than stemflow. The effects were almost entirely due to increases in concentration, rather than the amount of rainfall becoming throughfall or stemflow. The concentration of nitrogen (as NH₄ or NO₃) in throughfall or stemflow could be lower or higher than in rainfall, indicating net removal or leaching, respectively. Net removal occurred for most rainfall events for the control treatment, for a substantial number of events for treatment F, but for few events for treatment IL. The ammonium ion was preferentially removed from throughfall, and nitrate from stemflow. Transfers of potassium and total nitrogen by litterfall, throughfall and stemflow were also studied. The proportions of potassium and nitrogen being transferred by these processes showed little difference between treatments; the overall values for potassium being 60% by throughfall, 4% by stemflow and 36% by litterfall. In contrast the transfer of nitrogen was dominated by litterfall (81%), with 18% by throughfall and 1% by stemflow. © 1997 John Wiley & Sons, Ltd.     

Efficient strong motion duration of pulse-like records for nonlinear structural analyses

The special interest produced by near-field directivity records and their effect on structural response has given a new significance in the velocity time history, its pulse-like content, and relevant parameters and indices. Recent research has shown that directivity pulses inherent in these records govern the linear and the nonlinear response of a wide range of structures. Based on this observation, it is suggested in this paper that a truncated ground motion, limited to the duration of the predominant velocity pulse, can be efficiently used to predict the structural response, instead of the base motion with the total duration, reducing significantly the required runtimes. The proposed methodology is verified for a series of medium to high rise reinforced concrete buildings, for which nonlinear time-history analyses are performed for a vast suite of pulse-like near-field records applied as base excitations with their total duration and the proposed truncated one. Comparison of the results for the response displacements and forces shows very good agreement, permitting the acceptance of the pulse duration as the efficient strong motion time interval of the original record, which determines the response and, thus, it can be used for nonlinear structural analyses.     

2020年云南省巧家县M_S 5.0地震强震动记录初步分析

2020年5月18日云南省巧家县发生M_S5.0地震,中国数字强震动台网的13个强震台站和昭通简易烈度计示范项目建设的43个烈度计台站,共接收168条强震动记录,经常规处理,绘制震区加速度峰值等值线图,并与云南地区常用地震动衰减关系进行对比,分析加速度峰值较大的几个台站频谱特性,计算地震动能量持时,讨论中小地震中高加速度峰值/低震害现象的成因,得到以下结论:(1) PGA等值线图形状较为平滑,其长轴呈NW—SE向展布;(2)云南地区常用地震动衰减关系预测值总体衰减趋势与观测值一致,但在近场(0—30 km)时,预测值基本偏小;(3)加速度峰值较大的几个台站记录主频集中在1—5 Hz;(4)小河镇台记录的能量持时较短,说明能量衰减较快,属脉冲型记录,不会对建筑物造成较大破坏。     

三峡水库消落区典型草本植物氮、磷养分计量特征

为明确消落区土壤养分对植物生长的影响,通过室内栽培试验,研究三峡库区秭归消落区土壤3种氮磷水平下4种草本植物—鬼针草(Bidens pilosa)、苍耳(Xanthium sibiricum)、水蓼(Polygonum hydropiper)、藜(Chenopodium album)长势及氮、磷计量特征.结果表明,消落区土壤中生长的植物氮含量为7.98~19.4 mg/g,磷含量为0.740~3.880 mg/g,氮磷比为3.48~13.70,判别植物生长受氮限制.外源氮磷的添加促进植物氮、磷含量明显升高,但氮磷比没有明显变化;外源氮磷添加解除植物受氮的限制作用.4种植物对消落区土壤低氮环境具有一定的适应能力.比较消落区土壤中4种植物长势,鬼针草生物量、相对生长率、根茎生物量比最高,氮磷养分丰富对鬼针草生长促进作用最明显,表明鬼针草更易于在氮、磷贫乏的三峡库区消落区形成优势群落.     

双向环形水槽模拟变化水位和流速下洞庭湖沉积物氮释放特征

浅水湖泊生态系统中的沉积物—水界面是湖泊内源氮释放的重要界面,而水动力因素是改变沉积物氮释放的重要因素.三峡大坝修建以后,长江中下游通江湖泊的水动力条件发生了明显的变化.通过采集洞庭湖湖口区域的沉积物和水样,在双向环形水槽动力模拟装置内模拟湖泊水位和流速的变化,探讨湖泊沉积物氮在沉积物和水系统中的二次释放特征.结果表明,随着扰动强度的增加,上覆水悬浮物浓度增大,上覆水中总氮浓度增加,沉积物向上覆水释放氮的强度增强,水动力条件的改变所引起的沉积物内源氮释放不容忽视.在该模拟实验条件下,沉积物存在最适扰动水位(20cm),此水位下上覆水中悬浮物浓度最低,总氮浓度最小.水动力条件的改变对上覆水和沉积物—水界面处铵态氮和硝态氮浓度的影响并不明显,孔隙水中铵态氮与硝态氮之间发生形态的转化.     

2012年唐山4.8级地震强震动记录特征及场地相关特性分析

2012年5月28日河北省唐山市古冶区与滦县交界发生4.8级地震, 国家强震动台网中心在河北、 天津和北京的94个强震动台站记录到了本次地震的加速度。 本文给出了获取记录的强震动台站分布及强震动记录结果, 统计了强震动记录数量随震中距的变化, 给出了3个较小震中距台站记录到的加速度时程; 绘制了空间地震动峰值加速度等值线图及周期0.2 s、 2.0 s加速度反应谱值的等值线, 发现峰值加速度等值线与长周期加速度反应谱等值线极值分布具有明显地域差异, 分析认为是由于厚沉积层对长周期地震动具有放大作用造成的。 通过强震动记录与适用于本区的三个衰减关系对比, 分析了此次地震的峰值加速度衰减特征, 同时研究了周期0.2 s、 2.0 s加速度反应谱值的衰减特征, 周期2.0 s反应谱值随震中距的衰减与衰减关系能较好地对应, 然而在震中距100～130 km沉积层较厚的集中地区, 表现出了实际记录较衰减关系值偏大的现象, 认为同样是由于厚沉积层对地震动加速度反应谱长周期的放大作用导致的。 研究了震中距差别不大的情况下, 场地类型与沉积层厚度对反应谱特征周期的影响, 对比基岩台站与软弱地基土层台站的强震动记录反应谱, 发现软弱土层台站的土层对地震动有一定的放大作用, 导致中长周期地震动被放大, 对比位于沉积层较薄的隆起区台站与位于沉积层较厚的凹陷区台站强震动记录反应谱, 发现厚的沉积层不仅对反应谱长周期有放大的作用, 同时也会使得反应谱特征周期值变大。