Large-sample hydrology: recent progress,guidelines for new datasets and grand challenges

ABSTRACT

Large-sample hydrology (LSH) relies on data from large sets (tens to thousands) of catchments to go beyond individual case studies and derive robust conclusions on hydrological processes and models. Numerous LSH datasets have recently been released, covering a wide range of regions and relying on increasingly diverse data sources to characterize catchment behaviour. These datasets offer novel opportunities, yet they are also limited by their lack of comparability, uncertainty estimates and characterization of human impacts. This article (i) underscores the key role of LSH datasets in hydrological studies, (ii) provides a review of currently available LSH datasets, (iii) highlights current limitations of LSH datasets and (iv) proposes guidelines and coordinated actions to overcome these limitations. These guidelines and actions aim to standardize and automatize the creation of LSH datasets worldwide, and to enhance the reproducibility and comparability of hydrological studies.     

地下管网健康档案管理平台的设计与实现

针对地下管网隐患数据管理的应用需求,本文基于三维平台设计实现了地下管网健康档案管理平台,在三维场景加载地上精细模型和地下管网数据,以三维可视化的手段对管网各类隐患问题进行信息管理,结合二维GIS操作,实现了净距分析、覆土分析、占压分析等管线隐患分析功能,通过本平台建立的地下管网健康档案数据库,方便用户对各类管网隐患数据进行信息管理和统计,为管道病害修复、管网改造提升提供数据支撑,保证地下管网的安全运行。     

Comparing palaeolimnological and instrumental evidence of climate change for remote mountain lakes over the last 200 years

This paper compares the palaeolimnological evidence for climate change over the last 200 years with instrumental climate data for the same period at seven European remote mountain lakes. The sites are Øvre Neådalsvatn (Norway), Saanajärvi (Finland), Gossenköllesee (Austria), Hagelseewli (Switzerland), Jezero v Ledvici (Slovenia), Estany Redó (Spain, Pyrenees), and Niné Terianske Pleso (Slovakia). We used multiple regression analysis to transfer homogenised lowland air temperature records to each of the sites, and these reconstructions were validated using data from on-site automatic weather stations. These data showed that mean annual temperature has varied over the last 200 years at each site by between 1 and 2 °C, typical of the high frequency variability found throughout the Holocene, and appropriate, therefore, to test the sensitivity of the various proxy methods used. Sediment cores from each site were radiometrically dated using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am and analysed for loss-on-ignition, C, N, S, pigments, diatoms, chrysophytes, Cladocera and chironomids. Comparisons between the proxy data and the instrumental data were based on linear regression analysis with the proxy data treated as response variables and the instrumental data (after smoothing using LOESS regressions) as predictor variables. The results showed few clear or consistent patterns with generally low or very low r² values. Highest values were found when the data were compared after smoothing using a broad span, indicating that some of the proxy data were capturing climate variability but only at a relatively coarse time resolution. Probable reasons for the weak performance of the methods used include inaccurate dating, especially for earlier time periods, the influence of confounding forcing factors at some sites e.g., air pollution, earthquakes, and the insensitivity of some methods to low amplitude climate forcing. Nevertheless, there were trends in some proxy records at a number of sites that had a relatively unambiguous correspondence with the instrumental climate records. These included organic matter and associated variables (C and N) and planktonic diatom assemblages at the majority of sites and chrysophytes and chironomids at a few sites. Overall for longer term studies of the Holocene, these results indicate the need to be cautious in the interpretation of proxy records, the importance of proxy method validation, the continuing need to use reinforcing multi-proxy approaches, and the need for careful site and method selection.     

参考文献著录规则应用及注意的问题

通过对《文后参考文献著录规则》的学习和理解,阐明参考文献著录方法,列举了有关著录事例和著录时应注意的问题。为著者撰写学术论文提供参考,以便提高学术论文和科技期刊质量。     

Brest sea level record: a time series construction back to the early eighteenth century

The completeness and the accuracy of the Brest sea level time series dating from 1807 make it suitable for long-term sea level trend studies. New data sets were recently discovered in the form of handwritten tabulations, including several decades of the eighteenth century. Sea level observations have been made in Brest since 1679. This paper presents the historical data sets which have been assembled so far. These data sets span approximately 300 years and together constitute the longest, near-continuous set of sea level information in France. However, an important question arises: Can we relate the past and the present-day records? We partially provide an answer to this question by analysing the documents of several historical libraries with the tidal data using a ‘data archaeology’ approach advocated by Woodworth (Geophys Res Lett 26:1589–1592, 1999b). A second question arises concerning the accuracy of such records. Careful editing was undertaken by examining the residuals between tidal predictions and observations. It proved useful to remove the worst effects of timing errors, in particular the sundial correction to be applied prior to August 1, 1714. A refined correction based on sundial literature [Savoie, La gnomique, Editions Les Belles Lettres, Paris, 2001] is proposed, which eliminates the systematic offsets seen in the discrepancies in timing of the sea level measurements. The tidal analysis has also shown that shallow-water tidal harmonics at Brest causes a systematic difference of 0.023 m between mean sea level (MSL) and mean tide level (MTL). Thus, MTL should not be mixed with the time series of MSL because of this systematic offset. The study of the trends in MTL and MSL however indicates that MTL can be used as a proxy for MSL. Three linear trend periods are distinguished in the Brest MTL time series over the period 1807–2004. Our results support the recent findings of Holgate and Woodworth (Geophys Res Lett) of an enhanced coastal sea level rise during the last decade compared to the global estimations of about 1.8 mm/year over longer periods (Douglas, J Geophys Res 96:6981–6992, 1991). The onset of the relatively large global sea level trends observed in the twentieth century is an important question in the science of climate change. Our findings point out to an ‘inflexion point’ at around 1890, which is remarkably close to that in 1880 found in the Liverpool record by Woodworth (Geophys Res Lett 26:1589–1592, 1999b).     

半微量凯氏法测定土壤全氮量的不确定度评定

以半微量凯氏法测定土壤中全氮量为例，对测定结果的不确定度来源进行了详细分析，对测定过程中的主要不确定度分量进行了合理评定，包括样品和标准物质硼砂的称量引入的不确定度，硼砂的纯度引入的不确定度，容量瓶、移液管和滴定管的体积引入的不确定度．相关元素的摩尔质量引入的不确定度以及测量的重复性引入的不确定度。最后合成标准不确定度．通过乘以95％置信概率下的扩展因子2获得测量结果的扩展不确定度。     

多目标地球化学调查土壤样品中氮和碳的快速测定

详细研究了元素分析仪的工作条件，建立了直接固体进样同时测定多目标地球化学调查土壤样苎支氮、碳的方法。方法简便、快速，检出限为氮14．5μg／g、碳0．013％。经土壤国家一级标准物质分析验证，测定值与标准值相符，精密度（RSD，n=12）为氮1．49％-3．27％、碳0.64％～3.63％。     

Trace变换的基本理论及其在地震勘探中的应用

Trace变换是一种新的图象重建工具,在图象重建方面已取得很好的效果。推导了Trace变换公式中的一个公式:∫(ε(t))rdtq的反变换公式,并结合τ-p变换中坐标系的转换关系,讨论了它在地震勘探中应用的可能性。对80道单一理论水平合成记录作了正、反变换的分析。从原记录和反变换记录中分别取道分析,分析结果表明对80道理论水平记录能很好的恢复。     

The Atmospheric Oxidation of the HS Radical: Reaction with NO2

The atmospheric reaction between HS and NO₂ was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO₂ or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO₂ can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO₂, and new investigations focusing on the atmospheric fate of HSNO₂ are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO₂, O₂ and N₂O should be the most important oxidants of HS, while the O₃ influence will not be significant.