铁同位素的MC-ICP-MS测定方法与地质标准物质的铁同位素组成

详细报道了在低分辨和高分辨模式下运用MC-ICP-MS进行Fe同位素比值高精度测试的方法,对Fe同位素测定过程中谱峰干扰、基质效应、浓度效应、仪器测试的长期重现性等问题进行了评估,并对两种运行模式的测试结果进行了对比.在95%的可信度范围内,所建方法的外部精度优于0.5ε/ainu,达到国际同类实验室的先进水平,并且低分辨和高分辨两种模式下获得的Fe同位素测试结果是一致的.在此基础上对国家地质标准物质GBW07105(玄武岩)和GBW 07111(花岗闪长岩)进行了Fe同位素测定.相对于Fe同位素国际标样IRMM-014,GBW07105的Fe同位素成分为:ε57Fe=1.9±0.3(20),ε56Fe=1.3±0.2(2σ),ε57/56Fe=0.6±0.1(2σ);GBW 07111的Fe同位素成分为:ε57Fe=1.8±0.4(2σ),ε56Fe=1.2±0.2(2σ),ε57/56Fe=0.6±0.1(2σ).     

沸石强化过滤的中试及生产性试验研究

对新型水处理材料沸石强化常规给水处理工艺进行了中试和生产性试验,并与石英砂滤料做了对比.中试结果表明粒径为0.80-1.20mm沸石对浊度、氨氮、有机物都表现出良好的去除效果,过滤时的水头损失、反冲洗强度明显小于石英砂,不仅能满足反冲洗要求,还可节省反冲洗水量,降低运行成本.在生产性试验条件下,沸石对浊度、氨氮、耗氧量的去除率分别为95%、83%和39%.因此,在当前水源水遭到污染的情况下,用沸石替代石英砂滤料可明显改善水质,在不增加处理构筑物的情况下,对给水处理工艺可起到强化作用     

采用碳氮稳定同位素技术对黄海中南部鳗鱼食性的研究

根据2005年4～5月在黄海和长江口海域进行的春季底拖网调查，应用稳定同位素方法研究了黄海中南部鯷鱼（Engraulis　japonicus）及其可能摄食饵料的碳氮稳定同位素比值，结果表明：（1）黄海中南部鯷鱼的食物组成为不同粒径的浮游动物、太平洋磷虾（Euphausia pacifuca）和仔稚鱼，其中以粒径为500-900μm的浮游动物为主，贡献比例占61％～84％；仔稚鱼贡献比例占16％～21％，较传统胃含物方法分析的结果小；（2）黄海中部海域鯷鱼的碳氮稳定同位素比值平均值较南部海域高，原因可能与各海域的能量来源不同或存在微食物环有关，也可能与不同海域鯷鱼的能量转换途径不一样，即与食物链长短不一有关．     

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.     

Management of a shallow temperate estuary to control eutrophication: The effect of hydrodynamics on the system’s nutrient loading

The Mondego estuary, a shallow warm-temperate intertidal system located on the west coast of Portugal, has for some decades been under severe ecological stress, mainly caused by eutrophication. Water circulation in this system was, until 1998, mainly dependent on tides and on the freshwater input of a small tributary artificially controlled by a sluice. After 1998, the sluice opening was effectively minimised to reduce the nutrient loading, and the system hydrodynamics improved due to engineering work in the upstream areas. The objective of the present study was to evaluate the effect of the mitigation measures implemented in 1998. Changes to the hydrodynamics of the system were assessed using precipitation and salinity data in relation to the concentrations of dissolved inorganic nutrients, as well as the linkage between dissolved N:P ratios and the biological parameters (phytoplankton chlorophyll a concentrations, green macroalgal biomass and seagrass biomass). Two distinctive periods were compared, over a ten year period: from January 1993 to January 1997 and from January 1999 until January 2003. The effective reduction in the dissolved N:P atomic ratio from 37.7 to 13.2 after 1998 is a result of lowered ammonia, but not the oxidised forms of nitrogen (nitrate plus nitrite), or increased concentrations of dissolved inorganic phosphorus. Results suggest that the phytoplankton is not nutrient limited, yet maximum and mean biomass of green macroalgae was reduced by one order of magnitude after the mitigation measures. This suggests that besides lowering the water residence time of the system, macroalgal growth became nitrogen limited. In parallel to these changes the seagrass-covered area and biomass of Zostera noltii showed signs of recovery.     

Remote Sensing Analysis of the Suspended Sediment Transport in Lingdingyang

- The data of landsat TM of multi-temporal for Lingdingyang Estuary, Pearl River in China is firstly used with suspended sediment concentration of field measurement to establish a correlative model equation. After the ratio processing of TM data and atmospheric correction, the images of suspended sediment concentration of different temporals are exported from the image processing systems AREIS II and III. These images express the characteristics of suspended sediment distribution, the mode of sediment transport and the extent of dispersion under the actions of tidal current and wind condition of different seasons.     

海洋生物-光学算法研究──南黄海叶绿素浓度的估算

根据１９９５年９月中日合作南黄海现场观测资料，对南黄海生物－光学算法进行研究。首先对南黄海现场多光谱反射比数据进行因子分析，解反射比协方差矩阵的特征问题；解出特征值和对应的特征向量，求出主因子，然后建立叶绿素α对主因子的多元线性回归方程，并对算法进行回报和预报检验。计算结果表明，该算法具有较高精度，同时也显示出天气条件对估算精度产生较大影响。     

海水叶绿素α浓度遥感测量的实验研究

本文描述了1989年11月在青岛即墨岙山养殖基地所做的海水叶绿素σ浓度遥感测量的基础实验。该实验获得了高浓度叶绿素α含量的海水反射光谱。该反射光谱的特征波段为:波谷在485nm;波峰在450nm 和535nm;“节点”在572nm.根据该实验数据选取了叶绿素α浓度两种双波段估算模式.分析结果表明;两种模式的精度都在50%以上,且双波段反射率的差值法优于双波段反射率比值法.     

Simulations of Annual Cycle of Phytoplankton Production and the Utilization of Nitrogen in the Yellow Sea

A nutrient dynamic model coupled with a 3D physical model has been developed to study the annual cycle of phytoplankton production in the Yellow Sea. The biological model involves interactions between inorganic nitrogen (nitrate and ammonium), phosphate and phytoplankton biomass. The model successfully reproduces the main features of phytoplankton-nutrient variation and dynamics of production. 1. The well-mixed coastal water is characterized by high primary production, as well as high new production. 2. In summer, the convergence of tidal front is an important hydrodynamic process, which contributes to high biomass at frontal areas. 3. The evolution of phytoplankton blooms and thermocline in the central region demonstrate that mixing is a dominant factor to the production in the Yellow Sea. In this simulation, nitrate- and ammonium-based productions are estimated regionally and temporally. The northern Yellow Sea is one of the highly ranked regions in the Yellow Sea for the capability of fixing carbon and nitrogen. The annual averaged f-ratio of 0.37 indicates that regenerated production prevails over the Yellow Sea. The result also shows that phosphate is the major nutrient, limiting phytoplankton growth throughout the year and it can be an indicator to predict the bloom magnitude. Finally, the relative roles of external nutrient sources have been evaluated, and benthic fluxes might play a significant role in compensating 54.6% of new nitrogen for new production consumption.     

Seasonal Variations in Benthic Community Metabolism and Nitrogen Dynamics in a Shallow, Organic-Poor Danish Lagoon

The dynamics of benthic primary production and community respiration in a shallow oligotrophic, marine lagoon (Fællestrand, Denmark) was followed for 1·5 years. The shape of the annual primary production cycle was explained primarily by seasonal changes in temperature (r² = 0·67-0·72) and daylength (r² = 0·63), whereas temperature almost explained all variation in benthic community respiration (r² = 0·83-0·87). On a daily basis the benthic system was autotrophic during spring and summer supplied by 'new' and 'regenerated' nitrogen and predominantly heterotrophic during fall and winter caused by light and nutrient limitation. The linear depth-relationship between porewater alkalinity and ammonium indicated that the C:N ratio of mineralized organic matter is low in spring and summer (3-6) and high in fall and winter (9-16). This is inversely related to net primary production and thus the input of labile, nitrogen-rich algal cells. Accordingly, mineralization occurred predominantly in the upper 2-5 cm of the sediment. The pool of reactive material (microalgal cells) was estimated to account for 12% of total organic carbon in the upper 3 cm, and had an average turnover time of less than 1 month in summer. Assimilation of organic carbon by benthic animals was equivalent to about 30% of the annual gross primary production. Grazing reduced chlorophyll a concentration in the sediment during summer and spring to values 30-40% lower than in winter, but maintained a 3-4 times higher specific microalgal productivity. The rapid turnover of organic carbon and nitrogen, and important role of benthic microalgae showed that the benthic community in this oligotrophic lagoon is of a very dynamic nature.