典型内陆湖泊沉积物氮、磷和重金属分布特征及生态风险评价——以武汉市武湖为例

城市内陆型湖泊湿地对城市生态系统具有重要的作用。以武汉市武湖为例,采用数理统计、营养盐指数、地累积指数和潜在生态风险指数等方法,对武湖表层沉积物中的氮、磷、有机质和重金属的平面分布特征、影响因素、富集污染程度、生态风险进行评价。结果表明: 武湖西北部表层沉积物中总氮、总磷和有机质的含量明显高于东南部,武湖周边地表径流和农田是营养元素的主要来源,旱地较水田有利于沉积物中总磷的富集; 武湖沉积物中有机质为内源水生植物和外源陆生植物的混合来源,与总氮具显著正相关关系; 沉积物中重金属含量总体较低,局部呈现高镉,平面上总体北部高于南部; 沉积物中重金属富集程度和潜在风险较低,局部地区镉和铅为轻微富集,镉和汞具中等潜在风险; 沉积物的潜在生态风险为低至中等,潜在生态风险与沉积物中镉的分布高度一致。     

液氮应用于干热岩钻探的可行性探讨

干热岩是一种清洁、可再生的地热资源,其开发需通过钻井实现。分析了目前干热岩常规钻探技术面临机械钻速慢、井下工具和钻井液性能不稳定、易发生复杂井下事故等挑战,讨论了液氮在干热岩钻探中的应用前景。认为液氮在干热岩钻探过程中具有破岩效率高、有效提高干热岩热能提取效果、解决钻井液不耐高温和井漏问题等优势,并提出了液氮在干热岩钻探过程中的工具耐低温性能、液氮携岩规律和效果、井筒压力控制、钻进参数优化、井壁稳定性等关键技术问题。     

Molecular characterization of dissolved black nitrogen via electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Combustion produces a complex mixture of polycondensed aromatic compounds known as black carbon (BC). Such products can become remobilized from char and soil in the form of dissolved BC (DBC). Ultra-high resolution Fourier transform ion cyclotron resonance mass spectrometry (ESI–FT-ICRMS) analysis of a variety of soil and char leachates showed that a significant proportion of DBC compounds contained one or more nitrogen atoms. While the presence of black nitrogen (DBN) in dissolved organic matter (DOM) has been reported, its molecular features were uncharacterized. Here we present results of FT-ICRMS characterization of DBN, where assigned formulae were validated on the basis on their ¹³C isotope signatures and fragmentation patterns obtained via collision induced dissociation. Possible chemical structures were assigned for several DBN formulae and suggest that nitrogen was incorporated into the core ring system as a pyrrole-type moiety. Most DBN compounds existed as part of homologous series where homologs differed by a mass corresponding to CO₂, suggesting that they were polysubstituted with carboxylic acid groups. The environmental contribution of such novel, aromatic, combustion-derived nitrogen compounds with respect to global nitrogen cycling remains elusive. The biogeochemical implications of the input of such fire-derived products to aquatic ecosystems as part of climate change therefore need to be assessed.     

滁州花山水文实验流域径流与氮素耦合模拟研究

采用SWAT模型方法对滁州花山水文实验流域进行了径流与氮素耦合模拟,探讨了流域土地利用对氮素输移的影响。构建了花山水文实验流域SWAT模型,采用2008年1月~2013年12月的降雨、径流等数据对径流模型进行率定和验证,以2012年5月~2013年12月的氮浓度监测数据对氮负荷模型进行验证。利用所建立的模型对现状土地利用情形和土地利用变化情景假设下进行了径流与氮素耦合模拟,计算了现状和不同土地利用情景假设下流域的径流深和氮负荷。结果表明:汛期的氮流失量占全年氮流失的比重较大,每年的汛期是控制氮流失的关键时期;旱地的氮流失潜力较水田大,林地的增加对氮负荷具有一定的消减作用;控制氮肥的使用,加强水土保持能力,可以有效减少流域氮负荷。     

碳氮源对P.Fluorescens吸附和还原U(Ⅵ)的影响研究

为探讨不同碳氮源对培养基中铀酰离子的络合形态及荧光假单胞菌对铀吸附和还原作用的影响,本文以查氏培养基为基础,将蔗糖替换为葡萄糖或将硝酸钠替代为氯化铵,采用Visual MINTEQ分析研究铀酰离子络合形态。研究结果表明,碳氮源的种类对微生物生长无影响。U(Ⅵ)浓度为10 mg/L时,3种培养基中铀酰离子的主要络合形态均为UO2PO-4。U(Ⅵ)浓度为50~200 mg/L,查氏和葡萄糖碳源培养基中铀酰离子主要络合形态均为UO2(SO4)2-2。氯化铵氮源培养基中,U(Ⅵ)浓度为50 mg/L时铀酰离子的主要络合形态为UO2HPO4(aq),浓度为100~200 mg/L时主要是UO2Cl2(aq)。荧光假单胞菌对U(Ⅵ)耐受浓度高达100 mg/L,当U(Ⅵ)浓度达到200 mg/L时,菌体失活。荧光假单胞菌为活体时,对U(Ⅵ)的吸附率为84.02%~92.59%,还原率为3.32%~10.94%,不同碳氮源对铀吸附和还原的影响较小。荧光假单胞菌为死体时,对铀的吸附率为24.33%~39.05%;非葡萄糖碳源培养基中,对铀的还原率为37.50%~44.58%,含还原性葡萄糖的培养基条件下U(Ⅵ)的还原率为53.12%。还原性葡萄糖与荧光假单胞菌对铀的还原为协同作用。荧光假单胞菌为活体时,培养基成分被微生物充分利用,两者协同作用不明显。     

Prediction of the presence of topsoil nitrogen from spaceborne hyperspectral data

Conventional methods of soil nitrogen extraction are time consuming, expensive and tedious. Remote sensing and Geographical Information System technologies can be used for the rapid and efficient prediction of the presence of soil nitrogen. However, studies are limited by and large to fields of larger and homogeneous units. This research concentrates on the prediction of topsoil nitrogen from harvested, scattered and small-sized agricultural fields of India using hyperspectral data. Spaceborne hyperspectral Hyperion data are used for the prediction of the presence of nitrogen. Multivariate partial least square regression method was used to predict the presence of nitrogen from reflectance. Reflectance data were pretreated using moving average and Savitzky–Golay filters which resulted in moderate prediction of R² 0.65 and 0.63 for calibration and validation, respectively. It can be inferred that Hyperion data can be effectively used for the prediction of the presence of soil nitrogen with a moderate level of accuracy even in case of scattered fields and fields of sizes approximately equal to the spatial resolution of the satellite.     

塔克拉玛干沙漠公路人工防护林植被的C, N化学计量特征及其固存能力研究

本研究以塔克拉玛干沙漠公路沿线生物防护林为研究对象,研究防护林三种主要建林植物不同器官的C,N含量及其生物量,进而估算其C, N固存能力及固碳释氧价值。结果显示：沙拐枣每个器官的生物量均显著高于梭梭和柽柳(P<0.05),个体的总生物量是梭梭和柽柳的2-3倍。整个防护林在建林8年后的总生物量达到116786.4 t。C,N含量在不同器官中的含量不尽相同,三种植物均表现为凋落物C含量最低。而植物叶中的N含量均显著高于枝,凋落物和根系(P<0.05)。建林8年后梭梭单株的固碳量为1404.6g,固氮量为201.5g,柽柳单株的固碳量为1449.7g,固氮量为195.4g,沙拐枣单株的固碳量和固氮量显著高于其他两种,分别为3979.8g,为520.9g,(P<0.05)。建林8年后整个防护林的总固碳植为35886.3 t,总固氮值为4917.7 t。整个防护林的固碳总价值为22555.3万元,释氧价值为50320万元,总的固碳释氧价值达72875.3万元。     

基于稳定同位素的六指马鲅(Polynemus sextarius)食性特征

利用稳定同位素方法对南海大鹏湾海域六指马鲅(Polynemus sextarius)及其食物的碳和氮稳定同位素比值(δ13C和δ15N值)进行分析,定量研究了不同食物对六指马鲅的贡献比率,研究结果表明:六指马鲅的δ13C值在–16.9‰—–16.1‰间,δ15N值的范围为14.0‰—15.4‰,δ13C和δ15N值的变化范围均较小,表明六指马鲅的食物来源较为单一。六指马鲅的食物主要由近缘新对虾(Metapenaeus affinis)、口虾蛄(Oratosquilla oratoria)、桡足类和蟹类组成,它们的营养位置分别为2.97±0.21、3.18±0.08、1.82±0.08和2.53±0.66,均低于六指马鲅的3.34±0.13。其中蟹类为六指马鲅的主要食物,平均贡献率为50.8%;其次为口虾蛄和近缘新对虾,平均贡献率分别为24.9%和17.0%;桡足类的平均贡献率最低,仅为7.3%。相关分析显示,六指马鲅的δ13C和δ15N值与其个体体长间均存在显著的正相关关系,说明不同大小的六指马鲅食物组成有差异。     

Advanced vegetation indices for sensing paddy growth via hyperspectral measurements

In this study, field-based spectroradiometer measurements were carried out in 72 plots with eight rice varieties along with three nitrogen applications. The critical wavelengths for the studied rice varieties at which the effects of nitrogen applications on spectral reflectance response were found significant, are ρ₅₅₀, ρ₅₆₀, ρ₆₅₅, ρ₇₅₀, ρ₇₅₅, ρ₇₈₀, ρ₈₁₀, ρ₈₄₀, ρ₉₀₀, ρ₉₂₀, ρ₁₀₀₀, ρ₁₀₁₀, ρ₁₀₂₀. Using the critical wavelengths, three derived vegetation indices were compared with established indices (VI and GRI) sensitive to nitrogen. VI₁ and VI₂ were efficiently able to discriminate the level of nitrogen treatments for most of the rice genotypes whereas VI and GRI were unable to find significant difference in nitrogen treatments for rice genotypes except two. Furthermore, nitrogen difference plots exhibited that the paddy crop growth has started earlier with N₃ (150 kg/ha) than N₂ (100 kg/ha) application. Quantitative analysis of rice genotypes revealed that VI₂ can be applied functionally for the assessment of nitrogen stress in rice agriculture system.     

Spatial and temporal variations of nutrient concentration in the groundwater of a floodplain: effect of hydrology,vegetation and substrate

Spatio‐temporal variations in nitrogen and phosphorus concentrations in groundwater were analysed and related to the variations in hydrological conditions, vegetation type and substrate in an alluvial ecosystem. This study was conducted in the Illwald forest in the Rhine Plain (eastern France) to assess the removal of nutrients from groundwater in a regularly flooded area. We compared both forest and meadow ecosystems on clayey‐silty soils with an anoxic horizon (pseudogley) at 1·5–2 m depth (eutric gley soil) and a forest ecosystem on a clayey‐silty fluviosoil rich in organic matter with a gley at 0·5 m depth (calcaric gley soil). Piezometers were used to measure the nutrient concentrations in the groundwater at 2 m depth in the root layer and at 4·5 m depth, below the root layer. Lower concentrations of nitrate and phosphate in groundwater were observed under forest than under meadow, which could be explained by more efficient plant uptake by woody species than herbaceous plants. Thus NO₃‐N inputs by river floods were reduced by 73% in the shallow groundwater of the forested ecosystem, and only by 37% in the meadow. Compared with the superficial groundwater layer, the lowest level of nitrate nitrogen (NO₃‐N) and the highest level of ammonium nitrogen (NH₄‐N) were measured in the deep layer (under the gley horizon at 2·5 m depth), which suggests that the reducing potential of the anoxic horizon in the gley soils contributes to the reduction of nitrate. Nitrate concentrations were higher in the groundwater of the parcel rich in organic matter than in the one poorer in organic matter. Phosphate (PO₄‐P) concentrations in both shallow and deep groundwater are less than 62 to 76% of those found in surface water which can be related to the retention capacity of the clay colloids of these soils. Moreover, the temporal variations in nutrient concentrations in groundwater are directly related to variations in groundwater level during an annual hydrological cycle. Our results suggest that variations in groundwater level regulate spatio‐temporal variations in nutrient concentrations in groundwater as a result of the oxidation–reduction status of soil, which creates favourable or unfavourable conditions for nutrient bioavailability. The hydrological variations are much more important than those concerning substrate and type of vegetation. Copyright © 1999 John Wiley & Sons, Ltd.