氮气、氧气和空气水合物的合成及其拉曼光谱特征

在-20℃和不同的压力下,在实验室内分别合成了氮气水合物(16MPa)、氧气水合物(13MPa)和空气水合物(15MPa),并对其N—N和O—O键伸缩振动的拉曼光谱特征进行了研究。结果表明,人工合成的水合物中的N—N和O—O键的拉曼位移与天然的空气水合物中的数据十分接近。在氮气水合物和空气水合物中,N—N键的拉曼峰值均为2322.4cm-1;O—O键的拉曼峰值在氧气水合物和空气水合物保持一致,均为1547.8cm-1。空气水合物分解的拉曼谱图表明,它不是氮气水合物和氧气水合物组成的混合物,而是由氮分子和氧分子共同生成的单一水合物,氮分子和氧分子同时进入水合物的大笼和小笼中。与空气中的氮、氧比例相比,水合物中氧分子明显富集,氮分子和氧分子的比例为2.4∶1。     

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..     

Petroleum Migration Direction of the Silurian Paleo-pools in the Tarim Basin, Northwest China

The results obtained in this paper indicate that carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has a high concentration and complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in studying petroleum migration of paleo-pool. During the basin＇s first-stage of oil-gas pool formation in the Silurian in Tazhong and Tabei areas of Tarim Basin （at the end of Silurian period） and the second-stage in the Awati area （in Permian）, the petroleum experienced a long-distance migration. During the formation of the Silurian paleo-pools in Tazhong Uplift at the end of Silurian, the petroleum mainly came from the lower and middle Cambrian source rocks in the Manjiaer sag. The petroleum migrated towards the southwest-south entering the Silurian reservoir beds in Tazhong first. Then, it further migrated within Silurian from northwest to southeast along the highs of the Structural Belts to the region of the Silurian pinchout boundary in Tazhong. In Tabei Uplift, during the first-stage of pool formation, the petroleum was also from the lower and middle Cambrian source rocks in the Manjiaer sag. It migrated northwest entering the Silurian reservoir beds in the Tabei Uplift firstly, and then the migration continued in the same direction within the Silurian reservoirs and finally the petroleum was trapped in higher positions. During the second-stage pool formation in the Silurian beds in the areas around Awati sag, the petroleum mainly came from the lower-middle Cambrian source rocks in the Awati sag. The petroleum migrated from the generation center to Silurian reservoirs in all directions around the sag through major paths, and the petroleum was finally trapped in higher locations.     

Nutrient-chlorophyll trajectories across trophic gradients

We estimate the response of chl-a (mg · m^–3) to changes in concentrations of total phosphorus (TP) by calculating the slopeS = chl-a/TP in chl-a =f(TP) graphs. Results show that in years where algae are P-limited oligotrophic lakes respond less (median slope 0.21) to changes in nutrient concentrations than eutrophic lakes, (median slope 0.31) and these again less than hypereutrophic lakes, (median slope 1.02). We find no saturation value for the slope within the TP range considered (6–480 mg · m^–3). Chl-a in eutrophic lakes responds more frequently to non-nutrient factors than oligotrophic and hypereutrophic lakes. Results obtained by replacing TP with a new nutrient parameter, TP = 0.056 · TP · IN^0.226, in which inorganic nitrogen, IN, is factored in, suggest that nitrogen has an influence on chl-a in oligotrophic lakes. Blue-green algae respond less to changes in TP than other algal species, e.g., diatoms.     

Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients

A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO₃ (0.01), N₂O₅ (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.     

Measurement of the total nitrogen in lake sediments： Comparison and its environmental significance

Nitrogen cycle is an important bio-geochemical process in the environment. Measurement of the total nitrogen （TN） is a routine experiment in agriculture, biology and environmental sciences. The Kjeldahl method （KM） and elemental analyzer method （EA） are both commonly used to determine TN. Total nitrogen by EA is the sum of nitrate （NO3）, nitrite （NO2）, organic nitrogen and ammonia. Total nitrogen by KM （TKN） is made up of both organic nitrogen and ammonia. A comparative study focused on the two methods is conducted by analysis of TN in 97 samples from the sediment sequence of Gouchi, a salt lake in North China. KM presents a higher degree of accuracy than EA with a standard deviation of 0.007 vs. 0.024. With the presence of nitrate and/or nitrite nitrogen, however, measurement by KM is considerably lower than that by EA. Therefore, for samples from lake sediment sequences or soils in North China, KM is inapplicable to determining TN because of usually high contents of nitrous salt. Despite the inconsistency, use of both methods to the same samples makes sense in reconstructions of climatic and environmental changes from lake sediments. In Lake Gouchi, the contents of nitrate and nitrite nitrogen vary from 1.40% in the lower part of the sequence to 14.77% in the uppermost part, suggesting a gradual evolution process from a fresh water lake to the present-day salt lake.     

SPATIAL DISTRIBUTION OF NUTRIENTS OF SHALLOW LAKE IN THE ZHALONG WETLAND

1 INTRODUCTIONNitrogen and phosphorus in the water are the nu-trients limited in natural wetlands,which seriously in-fluence on the ecosystem production and the biodiver-sity(Mitsch,Grosselin,2000).Nitrogen and phos-phorus recycles have been interrupted b…     

长白山圆池泥炭氮元素分布特征及其影响因素分析

通过对长白山圆池4个泥炭剖面样品的分析,揭示了其氮元素分布规律。在圆池选取4个具有代表性的采样点,利用泥炭采样器采取新鲜泥炭样品。分析结果表明,4个泥炭剖面氮元素含量在0.014%~3.353%之间;剖面间相比较,其中贫营养泥炭整体含氮量较低;4个泥炭剖面的氮元素分布呈现明显规律,受泥炭上层不同植物、泥炭水分和有机质含量等因素的影响,泥炭剖面中氮元素累积峰可能出现在剖面的表层(0~5cm)或中间层(10~20cm);泥炭剖面氮元素与有机质呈极显著的正相关;泥炭剖面C/N比值变化在9.51~66.98之间,部分剖面层位C/N比值异常高,表明该层位碳的累积速度显著高于氮元素。     

Water chemistry and water quality variation in the Danjiangkou Reservoir, as a function of water management for the Middle Route of South to North Water Divert Project, China

As the diversion dike of the Middle Route of the South to North Water Transfer Project （MRSNWTP）, the water quality and water quantity of Danjiangkou Reservoir is critical to the project. At present, the rates of industrial wastewater treatment and sewage discharge, which belongs to Chinese State Standard in the districts near the reservoir except Shiyan city, are less than 60% and 40% respectively. The point source pollutants will be controlled because of the project after some time, but the non-point source pollutants caused by vegetation degradation and water-soil erosion will not be controlled effectively in a long time. Water samples were collected from the Danjiangkou Reservoir during 2004 and 2005 and analyzed for trace metals, i.e., silver （Ag）, aluminum （Al）, arsenic （As）, barium （Ba）, bismuth （Bi）, calcium （Ca）, cadmium （Cd）, cobalt （Co）, chromium （Cr）, copper （Cu）, iron （Fe）, mercury （Hg）, potassium （K）, lithium （Li）, magnesium （Mg）, manganese （Mn）, molybdenum （Mo）, sodium （Na）, nickel （Ni）, lead （Pb）, antimony （Sb）, selenium （Se）, silicon （Si）, strontium （Sr）, vanadium （V）, zinc （Zn）, chemicophysical parameters and nutrients, i.e., temperature （T）, pH, dissolved oxygen （DO）, turbidity, total suspended solid （TSS）, nitrate/ammonia/ammonium-nitrogen （NO3^-/NH3/NH4^＋-N）, total nitrogen （TN）, dissolved inorganic nitrogen （DIN）, total phosphorus （TP）, potassium permanganate index （IMn）, biochemical oxygen demand （BOD）, dissolved inorganic carbon （HCO3^-）. Our results are water quality belongs to Chinese standard level II, trace metals are low, but they are accumulating, and many of which, i.e., As, Pb, will endanger reservoir water security.     

环溪河流域土壤氮素含量及影响因素分析

根据67个随机格网样点和分层抽样样点的耕层土壤氮素含量，在ArcGIS9．0平台上运用地统计学等方法研究了环溪河流域土壤氮素含量及其影响因素。结果表明，环溪河流域土壤全氮和碱解氮的平均含量分别为0．60g／kg和53．31mg／kg。研究区土壤全氮含量总体上呈条带状和团块状分布，其低值中心区（〈0．5g／kg）位于团结村不规则三角形区域，并以此为中心向四周增加；高值中心区（〉0．8g／kg）主要位于走马村椭圆状区域。区内土壤碱解氮其高值区（〉75mg／kg）主要分布在深弯村以西，低值区（〈33mg／kg）主要分布于窝窝店村和杨柳村一带。影响区内土壤氮素含量空间分布的因素主要是成土母质、土壤质地、土地利用方式、地貌和坡度。