地下水浅埋区土壤水的矿化度变化规律及其影响因素浅析

土壤水的研究对农田水利、水文地质、生态与环境等都具有很重要的意义 ,本文概略介绍了在黄河三角洲地区开展包气带水分运移试验研究过程中 ,野外获取土壤水的方法及设备。在对水样分析结果进行总结的基础上 ,对试验点土壤水的矿化度变化规律及其影响因素进行了初步的分析。主要结论为 ,在地下水浅埋区 ,地下水与土壤水矿化度变化关系密切 ;蒸发作用与蒸腾作用对土壤水矿化度的影响效果是不同的 ,蒸发作用使上层土壤水的矿化度加大 ,而植被在其生长期降低土壤水的矿化度 ;地下水、植被和土壤性质是影响土壤水矿化度的重要因素     

陆相断陷盆地深部碎屑岩成岩演化及控制因素:以东营断陷盆地古近系孔店组为例

通过岩石薄片、扫描电镜、镜质体反射率、X衍射、物性分析等资料,对东营断陷盆地古近系孔店组成岩演化及控制因素进行详细研究。研究结果表明:东营断陷盆地孔店组典型成岩现象有强烈压实作用、硬石膏胶结、多期次碳酸盐胶结、多期次粘土矿物胶结、硅质强烈胶结、矿物强烈穿插交代、碎屑颗粒和胶结物的溶解作用;其中,压实作用是引起深部碎屑岩强烈致密化的主要原因;硬石膏胶结、碳酸盐胶结、硅质胶结是引起致密化的又一重要原因;长石、碳酸盐胶结物的溶解作用是引起该地区储层改善的主要成岩因素;成岩演化经历了准同生期-中成岩B期,部分达到晚成岩期的演化过程,成岩演化过程控制了深部碎屑岩孔隙演化;并推断原始干旱-半干旱沉积环境、基准面变化、深埋藏环境、构造-岩浆活动是控制成岩及孔隙演化的主要因素。     

江西武山花岗闪长斑岩中黑云母成分特征及其成岩成矿意义

江西武山花岗闪长斑岩与矽卡岩铜矿在成因上密切相关,通过对其中的黑云母进行的岩相学观察和详细的矿物化学分析来探讨黑云母的形成条件及其成岩成矿意义。电子探针分析结果表明,武山花岗闪长斑岩中的黑云母富镁贫铁低铝高钛,属镁质黑云母。其AlⅥ为0.03~0.19,w(ΣFeO)/w(ΣFeO+MgO)为0.531~0.567,w(MgO)为12.80%~14.06%,指示武山花岗闪长斑岩属壳幔混源的I型花岗岩。黑云母结晶的温度为720℃~750℃,logfO2为-11.6~-12.5,压力为86 MPa~103 MPa,对应的侵位深度为2.84 km~3.39 km,表明该岩体形成于相对高温较浅环境,具有较大成矿潜力,有利于武山铜矿的形成。     

(斜长石 + 黑云母 + 石英 ) NaCl(NaHCO3) H2O 矿物蚀变与金矿化反应研究 : 450～ 250 ℃和 50 MPa

采用（斜长石＋黑云母＋石英）这三种单矿物组合与1mol/L NaCl或0．5mol/L NaCl 0.5mol/L NaHCO3溶液在450－250℃和50MPa条件下反应7d。实验表明，反应后流体pH值发生了变化，NaCl介质向酸性变化，N aCl NaHCO3介质向中性转化。溶液中K,Ca,Mg,Fe和Au量也随之发生变化。矿物表面发生溶解和离子置换等反应。斜长石表面形成钠长石反应边，黑云母变色，石英重结晶，反应器皿金管中的金被溶解后在金管壁和黑云母表面重结晶，黑云母周边出现红色Fe2O3，在450℃的NaCl介质中，金含量可达1070μg/g，但随温度下降迅速减低，在NaCl NaHCO3介质中，金含量较低，显著，金的活化迁移和富集与Cl,pH,Fe^3 /Fe^2 密切相关，这中金起到示踪作用，显示出金在水／岩反应中的原电池效应。     

泌阳凹陷地质流体对砂岩储集层中黏土矿物形成和分布的控制作用

运用扫描电镜观察和X射线衍射分析等技术,在对泌阳凹陷核桃园组砂岩储集层中黏土矿物分布特征研究的基础上,从黏土矿物的形成条件和形成过程入手,详细分析了地质流体的性质、组成、流动方式、迁移速度等对砂岩储集层中黏土矿物形成和分布的影响,指出砂岩储集层中参与成岩反应的碎屑活性组分和地质流体对砂岩储集层中黏土矿物的形成和分布具有控制作用,并讨论了它们的形成机理.研究表明,黏土矿物的形成和分布能够不同程度地影响砂岩储集层的孔渗性和含油气性;高岭石发育层段与次生孔隙的发育和渗透率的增加以及油气的富集层段具有良好的对应关系.     

Differential subduction and exhumation of crustal slices in the Sulu HP-UHP metamorphic terrane: insights from mineral inclusions, trace elements, U-Pb and Lu-Hf isotope analyses of zircon in orthogneiss

Based on new evidence the Sulu orogen is divided from south‐east to north‐west into high‐pressure (HP) crustal slice I and ultrahigh‐pressure (UHP) crustal slices II and III. A combined set of mineral inclusions, cathodoluminescence images, U‐Pb SHRIMP dating and in situ trace element and Lu‐Hf isotope analyses was obtained on zircon from orthogneisses of the different slices. Zircon grains typically have three distinct domains that formed during crystallization of the magmatic protolith, HP or UHP metamorphism and late‐amphibolite facies retrogression, respectively: (i) oscillatory zoned cores, with low‐pressure (LP) mineral inclusions and Th/U > 0.38; (ii) high‐luminescent mantles (Th/U < 0.10), with HP mineral inclusions of Qtz + Grt + Arg + Phe + Ap for slice I zircon and Coe + Grt + Phe + Kfs + Ap for both slices II and III zircon; (iii) low‐luminescent rims, with LP mineral inclusions and Th/U < 0.08. Zircon U‐Pb SHRIMP analyses of inherited cores point to protolith ages of 785–770 Ma in all seven orthogneisses. The ages recorded for UHP metamorphism and subsequent retrogression in slice II zircon (c. 228 and c. 215 Ma, respectively) are significantly older than those of slice III zircon (c. 218 and c. 202 Ma, respectively), while slice I zircon recorded even older ages for HP metamorphism and subsequent retrogression (c. 245 and c. 231 Ma, respectively). Moreover, Ar‐Ar biotite ages from six paragneisses, interpreted as dating amphibolite facies retrogression, gradually decrease from HP slice I (c. 232 Ma) to UHP slice II (c. 215 Ma) and UHP slice III (c. 203 Ma). The combined data set suggests decreasing ages for HP or UHP metamorphism and late retrogression in the Sulu orogen from south‐east to north‐west. Thus, the HP‐UHP units are interpreted to represent three crustal slices, which underwent different subduction and exhumation histories. Slice I was detached from the continental lithosphere at ～55–65 km depth and subsequently exhumed while subduction of the underlying slice II continued to ～100–120 km depth (UHP) before detachment and exhumation. Slice III experienced a similar geodynamic evolution as slice II, however, both UHP metamorphism and subsequent exhumation took place c. 10 Myr later. Magmatic zircon cores from two types of orthogneiss in UHP slices II and III show similar mid‐Neoproterozoic crystallization ages, but have contrasting Hf isotope compositions (εHf_(～785) = ?2.7 to +2.2 and ?17.3 to ?11.1, respectively), suggesting their formation from distinct crustal units (Mesoproterozoic and Paleoproterozoic to Archean, respectively) during the breakup of Rodinia. The UHP and the retrograde zircon domains are characterized by lower Th/U and ¹⁷⁶Lu/¹⁷⁷Hf but higher ¹⁷⁶Hf/¹⁷⁷Hf(t) than the Neoproterozoic igneous cores. The similarity between UHP and retrograde domains indicates that late retrogression did not significantly modify chemical and isotopic composition of the UHP metamorphic system.     

中国"东部高原"东北部黏土矿物特征研究

通过对"东部高原"东北部地区中侏罗统—白垩系中黏土矿物分析,结果显示黏土矿物的组合及含量变化能够较好反映当时的气候、物源以及古地理变化;同时,伊利石结晶度不具有随地层深度发生变化的规律。黏土矿物组合以及伊利石结晶度在东部高原隆升与消亡前后,发生了比较明显的变化,这从另一方面反映了东部高原的存在。     

Characteristics of Clay Minerals in the Northern South China Sea and Its Implications for Evolution of East Asian Monsoon since Miocene

Clay mineral assemblages, crystallinity, chemistry, and micromorphology of clay particles in sediments from ODP Site 1146 in the northern South China Sea (SCS) were analyzed, and used to trace sediment sources and obtain proxy records of the past changes in the East Asian monsoon climate since the Miocene, based on a multi-approach, including X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray spectrometry (SEM-EDS). Clay minerals consist mainly of illite and smectite, with associated chlorite and kaolinite. The illite at ODP Site 1146 has very well-to-well crystallinity, and smectite has moderate-to-poor crystallinity. In SEM the smectite particles at ODP Site 1146 often appear cauliflower-like, a typical micromorphology of volcanic smecites. The smectite at ODP Site 1146 is relatively rich in Si element, but poor in Fe, very similar to the smectite from the West Philippine Sea. In contrast, the chemical composition of illite at ODP Site 1146 has no obvious differences from those of the Loess plateau, Yellow River, Yangtze River, and Pearl River. A further study on sediment source indicates that smectite originates mainly from Luzon, kaolinite from the Pearl River, and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The clay mineral assemblages at ODP Site 1146 were not only controlled by continental eathering regimes surrounding the SCS, but also by the changing strength of the transport processes. The ratios of (illite+chlorite)/smectite at ODP Site 1146 were adopted as proxies for the East Asian monsoon evolution. Relatively higher ratios reflect strongly intensified winter monsoon relative to summer monsoon, in contrast, lower ratios indicate a strengthened summer monsoon relative to winter monsoon. The consistent variation of this clay proxy from those of Loess plateau, eolian deposition in the North Pacific, planktonic, benthic foraminifera, and black carbon in the SCS since 20 Ma shows that three profound shifts of the East Asian winter monsoon intensity, and aridity in the Asian inland and the intensity of winter monsoon relative to summer monsoon, occurred at about 15 Ma, 8 Ma, and the younger at about 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at 15 Ma, 8 Ma, and 3 Ma.     

新疆巴州且末县、若羌县南部山区地质矿产特征及找矿靶区选择

新一轮国土资源大调查工作开展以来,东昆仑地区新发现了一系列矿床和找矿新线索,特别是白干湖钨锡矿床、肯德可克钴金铋多金属矿床和骆驼沟大型钴金矿床的发现,成为东昆仑地区地质找矿方面新的重大突破,同时,还发现了具大型远景规模的大场蚀变岩型金矿床,使得东昆仑地区成为我国又一重要的铜钴金多金属成矿带,已成为我国重点支持的铜钴金多金属矿产勘查地区之一。结合且末县、若羌县南部山区地质矿产特征、化探异常及区域内矿床实例,为新疆紫金地质勘查院2010年优选找矿靶区,指导登记探矿权。     

郑家-王庄地区沙一段粘土矿物特征及对储层敏感性影响

东营凹陷郑家—王庄地区沙一段砂岩储集层中蕴藏大量稠油油藏,但开发过程中粘土矿物的敏感性严重制约了该油类藏的有效开发。定向X射线衍射分析结果表明,本区沙一段砂岩储层中粘土矿物组成类型为伊/蒙无序间层矿物(S/I)、高岭石、伊利石和绿泥石,其中以伊/蒙无序间层矿物的相对含量居多。这就决定了研究区储层敏感性以水敏性为主,其余敏感性无或较弱。据定向X射线衍射谱图上S/I主峰d值大小,进一步识别出钙型S/I、钠型S/I及钙钠过渡型S/I。扫描电镜观察表明,S/I具有丝状、网状和蜂窝状三种形态,且大都包裹在岩石骨架颗粒的表面作为孔隙衬里而存在。阳离子交换容量和膨胀率研究结果显示,二者与样品中S/I含量和层间阳离子类型相关。膨胀率和阳离子交换量与S/I含量都呈较好的正相关关系。在S/I中蒙皂石层含量相当的情况下,钠型S/I的膨胀率和阳离子交换量值偏大,钙型偏小,钙钠过渡型居中。此外,粘土总量以及S/I产状对储层损害也有较大的影响。