海洋沉积物中烃类化合物预处理条件优化及应用

运用分辨率高、稳定性好的ＨＰ６８９０ 毛细管气相色谱仪定性、定量测定海洋沉积物中的正构烷烃和多环芳烃。对沉积物样品的预处理中抽提、蒸发、柱层析、萃取等步骤条件进行优化。优化方法中,正构烷烃系列化合物回收率为６５ ％ ～７６ ％ ,多环芳烃系列化合物为８８ ％ ～９５％ ,标准偏差是２．７％ ～２０．２％ （ｎ＝ ３）     

Taxonomic revision of Cylindroporella ? lusitanica Ramalho, 1970: In search for the origins of the Family Dasycladaceae

A study of new material of Cylindroporella ? lusitanica Ramalho, 1970, from the Upper Jurassic (Oxfordian) strata of Portugal identified features not observed previously. This includes the pattern of its laterals, including the gametophores. The algal body plan is unique and justifies the taxonomic reassessment of this species and the introduction of Barattoloporellopsis n. gen. Furthermore this species is most likely a primitive Dasycladaceae, a “missing link” between the modern ones (starting from the Cretaceous times) and their Jurassic ancestors.     

Brazil’s Financial Centers in the Twenty-first Century: Hierarchy,Specialization, and Concentration

The purpose of this article is to examine how the geography of Brazil’s financial centers changed since 2000 in terms of financial center hierarchy, specialization, and spatial concentration. To address these questions, we use data on employment and mergers and acquisitions in financial and business services, complemented with data on remuneration and bank assets. Our results show that São Paulo has consolidated its dominance as Brazil’s primary financial center, with market for corporate control as an important channel of this process. Rio’s decline as a financial center, which started more than fifty years ago, has continued into this century. At the same time, Brasília has emerged as the third most important financial center of Brazil. We document the recent dynamic of this territorial division of labor, with Rio’s specialization in insurance and Brasília’s dependence on government-owned banks. Finally, we show signs that Brazil’s financial center activities might be following an inverse U-shaped pattern whereby increasing geographical concentration is followed by its slow decline. Key Words: Brazil, concentration, financial centers, São Paulo, territorial division of labor.     

AVOA techniques for fracture characterization

Different aspects of computational techniques for AVOA analysis (Amplitude Versus Offset and Azimuth) for fracture characterization are considered, in particular: using amplitudes instead of reflection coefficients, smoothing seismic data, and numerical methods for estimation of fracture directions. A new computational method and a new filter for smoothing are suggested. The different computational methods are compared in synthetic reflection surface data with noise, and without noise. Properties of the numerical methods in dependence on different sets of azimuths and offsets are obtained. It is shown a superiority of the new method.     

Delineation of the northern limit of the Congo Craton based on spectral analysis and 2.5D modeling of aeromagnetic data in the Akonolinga-Mbama area,Cameroon

Aeromagnetic data of the Akonolinga-Mbama region are analyzed in order to elucidate the subsurface geology of the area. The available data in the form of a residual aeromagnetic map is interpreted as a vast magnetically quiet region, and complex zones which do not correlate with the surface geology of the region.Within the magnetically quiet zone, a high negative circular elongated anomaly zone seems to represent an intrusion of a plutonic rock into the metamorphic formations of the region. Spectral analysis and two-and-a-half dimensional (2½-D) modeling are used to estimate the depth of the causative bodies and determine the source rocks along three profiles crossing the suspected areas. Models from various zones of granitic intrusions are obtained, thereby proposing some shallow fault lines along zones of contact. This permits us to mark out the northern margin of the Congo Craton, thus enabling us to distinguish the cratonic formations from the Pan African fold belt. Part of the belt has been thrust over the northern portion of the Congo Craton in Cameroon.     

Sensitivity of the surface temperature to changes in total solar irradiance calculated with the WRF model

The temperature sensitivity of the WRF model to changes in Total Solar Irradiance (TSI). The simulations were performed for a region centered over the North Atlantic Ocean, including portions of Eastern North America, Western Europe and Northwest Africa. Four simulations were run with different TSI values. Also, a fifth simulation was performed in which we varied the initial atmospheric conditions, in order to compare the effect on the temperature of both, changes in the TSI and initial atmospheric conditions. Comparing temperature monthly averages we found that changes in TSI and in the initial conditions have a measurable impact on temperature in the region of study. The sensitivity of the model using non-dimensional parameters was also estimated. The numerical experiments show some features that might allow to distinguish between the effects on the temperature due to changes in TSI from those caused by initial conditions. However, TSI changes are of the same order of magnitude than those of disturbances in the initial conditions. We also found that the mean monthly values of temperature over the full grid, did not present significant variations due to changes of either initial conditions or TSI.     

Crustal structure of eastern Cuba,derived by constrained 3D gravity inversion

A three-dimensional crustal model for Eastern Cuba, obtained through a process of gravity data inversion is presented. The study area cover a rectangular area of 64 600 km². The initial model for the inversion was constrained by surface geology, seismic and drilling data. The inversion algorithm uses gravity data to estimate 3-D topographies from the main geological units. The model provides quantitative information on the depths and thicknesses of the geological formations. The resulting model provides new information about the regional composition of the crust. Alien sequences are observed with different compositions and origin over the basement of Bahamas carbonate platform. Most of the maximum gravity anomalies are associated with presence of dense shallow ophiolite sheets. The most remarkable detail is the gravity “southwest” maximum, related to the presence of denser oceanic crust generated in the Cayman spreading center.     

The accuracy of methods used to estimate the whole-lake accumulation rate of organic carbon, major cations, phosphorus and heavy metals in sediment

The accuracy of three methods used to estimate the whole-lake accumulation rate of chemicals in sediment, the simple mean accumulation rate, regression against water depth and the mean accumulation rate in sedimentation zones, was assessed. The concentrations and accumulation rates of organic carbon, four major cations, phosphorus and four heavy metals in the 1902 to 1988 sediment layer at 43 sites in Kassjön were used and the three methods gave identical results. The accuracy of the simple mean accumulation rate method using 5 or 10 sites was investigated using Monte Carlo simulation and both versions gave accurate results. If the method used the dry sediment accumulation rate at 5 or 10 sites, along with chemical concentration at one central site, then the errors were less than ±10% for five of the chemicals and larger for the others (?20 or 20–40%), although the direction of the bias was predictable. If chemical accumulation rate at the central site only was used to estimate the whole-lake value, the bias increased to 25% for the major cations, 50% for the heavy metals and P, and 85% for organic carbon. Having 43 sites in Kassjön meant that the true whole-lake chemical accumulation rate was known and so the accuracy of the methods and their variants could be assessed for the first time. These findings allow the particulars of the simple mean accumulation rate method to be chosen to suit the accuracy needed for a palaeolimnological investigation.