Geochemical Characteristics and Genetic Significance of Datangpo‐Type Manganese Ore Deposits during the Cryogenian Period

The Datangpo‐type manganese ore deposits, which formed during the Nanhuan (Cryogenian) period and are located in northeastern Guizhou and adjacent areas, are one of the most important manganese resources in China, showing good prospecting potential. Many middle‐to‐large deposits, and even super‐large mineral deposits, have been discovered. However, the genesis of manganese ore deposits is still controversial and remains a long‐standing source of debate; there are several viewpoints including biogenesis, hydrothermal sedimentation, gravity flows, cold‐spring carbonates, etc. Geochemical data from several manganese ore deposits show that there are positive correlations between Al₂O₃ and TiO₂, SiO₂, K₂O, and Na₂O, and strong negative correlations between Al₂O₃ and CaO, MgO, and MnO in black shales and manganese ores. U, Mo, and V show distinct enrichment in black shales and inconspicuous enrichment in Mn ores. Ba and Rb show strong positive correlations with K₂O in manganese ores. Cu, Ni, and Zn show clear correlations with total iron in both manganese ores and black shales. ∑REE of manganese ores has a large range with evident positive Ce anomalies and positive Eu anomalies. The Post Archean Australian Shale (PAAS) normalized rare earth element (REE) distribution patterns of manganese ores present pronounced middle rare earth element (MREE) enrichment, producing “hat‐shaped” REE plots. ∑REE of black shales is more variable compared with PAAS, and the PAAS‐normalized REE distribution patterns appear as “flat‐shaped” REE plots, lacking evident anomaly characteristics. δ¹³C values of carbonate in both manganese ores and the black shales show observable negative excursions. The comprehensive analysis suggests that the black shales formed in a reducing and quiet water column, while the manganese ores formed in oxic muddy seawater, which resulted from periodic transgressions. There was an oxidation–reduction cycle of manganese between the top water body and the bottom water body caused by the transgressions during the early Datangpo, which resulted in the dissolution of manganese. Through the exchange of the euphotic zone water and the bottom water, and episodic inflow of oxygenated water, the manganese in the bottom water was oxidized to Mn‐oxyhydroxides and rapidly buried along with algae. In the early diagenetic stage, Mn‐oxyhydroxides were reduced and dissolved in the anoxic pore water and then transformed into Mn‐carbonates by reacting with HCO₃^? from the degradation of organic matter or from seawater. In the intervals between transgressions, continuous supplies of terrigenous clastics and the high productive rates of organic matter in the euphotic zone resulted in the deposition of the black shales enriched in organic matter.     

From a river valley to a ria: Evolution of an incised valley (Ría de Ferrol,north‐west Spain) since the Last Glacial Maximum

The evolution of incised valleys is an important area of research due to the invaluable data it provides on sea‐level variations and depositional environments. In this article the sedimentary evolution of the Ría de Ferrol (north‐west Spain) from the Last Glacial Maximum to the present is reconstructed using a multidisciplinary approach, combining seismic and sedimentary facies, and supported by radiocarbon data and geochemical proxies to distinguish the elements of sedimentary architecture within the ria infill. The main objectives are: (i) to analyse the ria environment as a type of incised valley to evaluate the response of the system to the different drivers; (ii) to investigate the major controlling factors; and (iii) to explore the differentiation between rias and estuaries. As a consequence of the sea‐level rise subsequent to the Last Glacial Maximum (ca 20 kyr bp ), an extensive basin, drained by a braided palaeoriver, evolved into a tide‐dominated estuary and finally into a ria environment. Late Pleistocene and Holocene high‐frequency sea‐level variations were major factors that modulated the type of depositional environments and their evolution. Another major modulating factor was the antecedent morphology of the ria, with a rock‐incised narrow channel in the middle of the basin (the Ferrol Strait), which influenced the evolution of the ria as it became flooded during Holocene transgression. The strait acted as a rock‐bounded ‘tidal inlet’ enhancing the tidal erosion and deposition at both ends, i.e. with an ebb‐tidal delta in the outer sector and tidal sandbanks in the inner sector. The final step in the evolution of the incised valley into the modern‐defined ria system was driven by the last relative sea‐level rise (after 4 kyr bp ) when the river mouths retreated landward and a single palaeoriver was converted into minor rivers and streams with scattered mouths in an extensive coastal area.     

Topographical controls on small‐volume pyroclastic flows

Emplacement of small‐volume (<0·1 km³) pyroclastic flows is significantly influenced by topography. The Arico ignimbrite on Tenerife (Canary Islands) is a characteristic small‐volume pyroclastic flow deposit emplaced on high relief topography. The pyroclastic flow flowed down pre‐existing valleys on the southern slopes of the island. In proximal areas deep (up to 100 m) valleys acted as efficient conduits for the pyroclastic flow, which was mostly channelled; in this particular area the ignimbrite corresponds to a homogeneous, moderately welded deposit, consisting of flattened pumices in an abundant ashy matrix with a relatively low lithic fragment content. In intermediate zones significant changes occur in the steepness of the slope and, although still channelled, here the pyroclastic flow was influenced by hydraulic jumps. In this area, two different units can be clearly distinguished in the ignimbrite: the lower unit is composed of a lithic‐rich ground‐layer deposit that formed at the turbulent, highly concentrated head of the flow; the upper unit consists of a well welded pumice‐rich deposit that occasionally reveals a basal layer formed by shearing with the lower part. This division into two units is maintained as far as distal areas near the present‐day coastline, where the slope is very gentle or null and the ignimbrite is not channelled. The ground layer is not found in distal areas. The ignimbrite here only consists of the upper unit, which is occasionally repeated due to a surging process provoked by the lower flow speed, as the pyroclastic flow spread out of the channelled zone. A theoretical model on how topography controlled the deposition of the Arico ignimbrite is derived by interpreting the observed lithological and sedimentological variations in terms of changes in topography and bedrock morphology. This new model is of general applicability and will help to explain other deposits of similar characteristics.     

山地丘陵地区物探爆破孔钻机及配套机具的研究与开发

为满足我国山地丘陵地区物探爆破孔施工技术的要求，研究适合土层、岩层钻进用的钻机及工具，对钻机的配套设备进行了开发研究。分析了国内山地丘陵地区物探爆破孔施工技术现状，并着重介绍了研制设计内容及生产试验情况。     

ANALYSIS OF PILES USED FOR SLOPE STABILIZATION

Piles used for the stabilization of slopes have to be adequately designed to resist the induced lateral loads due to the movement of the unstable slope. In this paper, a numerical method is presented for the analysis of this problem. In this approach, the piles are modelled using beam finite elements. The soil response at the individual piles is modelled using the modulus of subgrade reaction and pile–soil–pile interaction considered using the theory of elasticity. Two case histories, one for single pile and the other for pile group, are analysed which show that the numerical model can predict the general characteristics of the piles reasonably well. The study suggests that the design of the piles based on the computed response from single pile analysis, ignoring group effects, may be unduly conservative.     

Guandishan Granitoids of the Paleoproterozoic Lüliang Metamorphic Complex in the Trans-North China Orogen: SHRIMP Zircon Ages, Petrogenesis and Tectonic Implications

Abstract: The Paleoproterozoic Lüliang Metamorphic Complex (PLMC) is situated in the middle segment of the western margin of the Trans-North China Orogen (TNCO), North China Craton (NCC). As the most important lithological assemblages in the southern part of the PLMC, Guandishan granitoids consist of early gneissic tonalities, granodiorites and gneissic monzogranites, and younger gneissic to massive monzogranites. Petrochemical features reveal that the early gneissic tonalities and granodiorites belong to the medium-K calc-alkaline series; the early gneissic monzogranites are transitional from high-K calc-alkaline to the shoshonite series; the younger gneissic to massive monzogranites belong to the high-k calc-alkaline series, and all rocks are characterized by right-declined REE patterns and negative Nb, Ta, Sr, P, and Ti anomalies in the primitive mantle normalized spidergrams. SHRIMP zircon U–Pb isotopic dating reveals that the early gneissic tonalities and granodiorites formed at ~2.17 Ga, the early gneissic monzogranites at ~2.06 Ga, and the younger gneissic to massive monzogranites at ~1.84 Ga. Sm–Nd isotopic data show that the early gneissic tonalities and granodiorites have εNd(t) values of +0.48 to ?3.19 with Nd-depleted mantle model ages (TDM) of 2.76–2.47 Ga, and early gneissic monzogranites have εNd(t) values of ?0.53 to ?2.51 with TDM of 2.61–2.43 Ga, and the younger gneissic monzogranites have εNd(t) values of ?6.41 to ?2.78 with a TDM of 2.69–2.52 Ga.These geochemical and isotopic data indicate that the early gneissic tonalities, granodiorites, and monzogranites were derived from the partial melting of metamorphosed basaltic and pelitic rocks, respectively, in a continental arc setting. The younger gneissic to massive monzogranites were derived by partial melting of metamorphosed greywackes within the continental crust. Combined with previously regional data, we suggest that the Paleoproterozoic granitoid magmatism in the Guandishan granitoids of the PLMC may provide the best geological signature for the complete spectrum of Paleoproterozoic geodynamic processes in the Trans-North China Orogen from oceanic subduction, through collisional orogenesis, to post-orogenic extension and uplift.     

宜良地热田水化学特征分析与研究

水化学特征不仅应用于分析地下水水质的时空变化规律,而且还提供地下水水动力环境信息。水化学分析方法已成为对探索地热田成因、地下水补给来源等常用的研究方法。基于近些年的研究资料,综合分析热储层结构特征和水化学特征,认为宜良地热田为层状热储型中低温地热田,其热储层为震旦系灯影组。研究热储层流体的化学分布特征以及热流体的化学成分与温度的关系等,用化学温标核算了热储层温度,认为K-Mg温标更适用于中低温地热田热储温度的估算。地热水水化学特征等基本地质特征可作为地热田规划和开发的理论基础。     

Thermodynamic Modelling of Ore-Forming Mechanism of the Changkeng Gold-Silver Deposits in Guangdong Province

The Changkeng gold-silver deposits consist of a sediment-hosted, disseminated gold deposit and a replacement-type silver deposit. The mineralizations of gold and silver are zoned and closely related to the silicification of carbonate and clastic rocks, so that siliceous ores dominate in the deposit. The mineralizing temperature ranges mainly from 300 to 170℃, and K+, Na+, Ca2+, Mg2+, and Cl- are the major ions in the ore-forming fluid. Calculations of distribution of metal complexes show that gold is mainly transported by hydrosulphide complexes, but chloride complexes of silver, iron, lead, and zinc, which are transformed into hydroxyl and hydrosulphide complexes under neutral to weak-alkaline circumstances in the late stage, predominate in the ore-forming solutions. Water-rock interaction is confirmed to be the effective mechanism for the formation of silver ores by computer modelling of reaction of hydrothermal solution with carbonate rocks. The solubility analyses demonstrate that the precipitation     

East Asia winter monsoon variations on a millennial time‐scale before the last glacial–interglacial cycle

Grain size and magnetic susceptibility measurements on samples from a typical loess–palaeosol sequence on the central Chinese Loess Plateau are used to reconstruct the Pleistocene East Asian monsoon climate. The coarse‐grained fraction, i.e. the weight percentage > 30 μm of the bulk grain‐size distribution, is used as a sensitive proxy index of the East Asia winter monsoon strength. On the basis of an absolute time‐scale, time‐series variations of this proxy show that winter monsoon strengths varied on millennial time‐scales during the periods 145–165, 240–280, 320–350, 390–440, 600–640, 860–890, 900–930 and 1330–1400 kyr BP. The wavelength of these climatic oscillations varied between 1.89 and 4.0 kyr, as is shown by spectral analysis using the multitaper method. Although numerical simulation experiments show that high frequencies also can arise from measurement errors in the grain‐size analysis, the frequencies prove to be sufficiently stable when the spectral analysis is repeated with a different number of tapers. For the time being, we do not correlate these climatic oscillations with palaeoclimatic records in the North Atlantic deep‐sea sediments because both time‐scales need to be further improved. Our data, however, certainly demonstrate that millennial‐scale East Asian winter monsoon variations in the last 1.4 million years can be detected from terrestrial loess records. Copyright © 1999 John Wiley & Sons, Ltd.     

瑞雷波勘探在地下洞穴探测中的应用

利用瑞雷波勘探方法进行地下洞穴探测，在实际处理过程中，对场地所测得的面波频散曲线进行分类、归纳，并利用动力触探曲线对各种特征曲线所反映的地下洞穴情况进行标定，从而确定整个测区洞穴的空间分布规律。