宁夏中卫县沙坡头地区黑色泥质页岩固沙性能研究

我国西北干旱半干旱地区，生态环境极为脆弱，土地沙漠化问题十分突出。防风固沙，恢复植被，遏制沙漠化，改善生态环境，是我国西部大开发战略和加快西部经济腾飞的主要任务之一。防风治沙首先要解决的问题是固沙保水。文章提出了利用宁夏腾格里沙漠东南缘中卫县沙坡头地区香山北麓的黑色泥质页岩在自然条件下天然胶结成壳作用于固沙的可能性。这类黑色泥质页岩具有遇水则吸水软化，风干则形成薄硬壳之特点。在斜坡坡面上或坡脚风化破碎或构造破碎或人工开挖的黑色泥质页岩碎块堆积的表面常形成1层1～5cm的硬壳。这类黑色泥质页岩在500℃时灼减量高达17．56％，说明具有很高的有机质含量，同时P2O5，和K2O含量也较高，有利于成壤和植物生长。黑色泥质页岩的天然胶结成壳作用与地表破碎的黑色泥质页岩堆积和特定的干旱半干旱气候以及本身成分、结构有关。这一硬壳层不但具有一定的强度和抗风蚀能力，而且还具有一定的吸水性和保水性。因此，借鉴草方格固沙方法，就地取材，充分利用黑色泥质页岩在自然条件下的天然胶结成壳性能，用于沙漠治理中的固沙。进一步对黑色泥质页岩天然胶结成壳的机理进行深入研究，并开展黑色泥质页岩固沙试验研究，有可能为腾格里沙漠治理开辟新的途径。     

石英脉型辉钼矿矿床多建造地球化学异常特征

通过对石英脉型辉钼矿床水系沉积物和区域成矿带多建造地球化学异常特征的研究,为寻找石英脉型钼矿床提供地球化学论据。     

长江三峡深槽沉积的研究

文章研究长江三峡两个基岩深槽沉积岩砾的岩性组成与粒度特征,深槽底部的砾石成分以深槽基岩崩落蚀余物质为主,深槽的中上部则以长江底流搬运沉积物为主。¹⁴C测年数据显示,深槽的发育在3.5万年以前,以侵蚀深切为主,没有留下蚀余堆积;3.5万年以后,仍以侵蚀为主,但已有蚀余为主的岩块堆积;大约2.4万年以来,逐渐有缓慢的冲积砾石堆积;至葛洲坝建成以后,该地发育了比较稳定的冲积砾石层和砂层。看来大约35kaB.P.前后,该地水动力强度发生过重大变化,与施雅风等关于3～4万年前长江上游多雨期研究成果相吻合。     

晚更新世晚期以来的长江上游古洪水记录

长江上游三峡河段主要的古洪水记录有:1)三峡深槽的蚀积变化;2)长江阶地粗粒沉积;3)长江的泛滥沉积;4)长江的古洪水平流沉积。不同时间跨度不同类型古洪水记录的精度有较大的差别。古洪水记录显示,晚更新世晚期的40～30kaB.P.,长江上游大洪水比30kaB.P.以来的长江上游大洪水大得多;全新世以来,以3983aB.P.前后的大洪水为相对最大;公元1870年大洪水为3000aB.P.以来最大洪水;近百年来的实测洪水以公元1981年洪水为最大。     

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan

The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column.     

Significance of transition between Talchir Formation and Karharbari Formation in Lower Gondwana basin evolution — A study in West Bokaro Coal basin, Jharkhand, India

Basal part of the Gondwana Supergroup represented by Talchir and Karharbari Formations (Permo-Carboniferous) records an abrupt change-over from glacio-marine to terrestrial fluviolacustrine depositional environment. The contact between the two is an unconformity. Facies analysis of the glacio-marine Talchir Formation reveals that basal glaciogenic and reworked glaciogenic sediments are buried under storm influenced inner and outer shelf sediments. Facies associations of the Karharbari Formation suggest deposition as fluvio-lacustrine deposits in fault-controlled troughs. An attempt has been made in this paper to explain the sedimentation pattern in Talchir and Karharbari basins, and the abrupt change-over from glacio-marine to terrestrial fluviolacustrine depositional environment in terms of glacio-isostacy.     

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.