Microwave-assisted extraction of organochlorine pesticides from sediments and determination by gas chromatograph with electron capture detection

A simple and rapid procedure to extract organochlorine pesticides （OCPs） from sediments by means of microwave energy is proposed. Sediment samples were irradiated with microwaves in a closed vessel system while immersed in hexane-acetone （1 ： 1, v/v）. The sample extracts were cleaned up using solid phase extraction with Florisil as adsorbent. Pesticides were eluted with hexane-ethyl acetate （80 ： 20, v/v） and determined by gas chromatographic separation with electron capture detection. Three oven programs were assayed with two different solvent mixtures in order to achieve adequate experimental conditions for the complete extraction of organochlorine pesticides from the matrix. Different variables such as the composition of extraction solvent,     

Rock fracturing by explosive energy: review of state-of-the-art

A study of the dynamic rock fracture initiation and propagation due to explosive energy is presented through a detailed state-of-the-art review. Explosive energy dissipation in crushing and fracturing is examined and the various means to enhance the explosive energy utilization for dynamic rock fracturing are reviewed. The study highlights the need for a better understanding of the dynamic fracturing process particularly in the presence of in situ stresses in the rock mass.     

Deformation-induced garnet zoning

Compositional zoning patterns in garnet porphyroblasts from kyanite-bearing samples of the Devonian Littleton Formation, north-central Massachusetts, reveal complex patterns of growth that are related to multiple deformation and metamorphic events. Garnet porphyroblasts exhibit asymmetrical and irregular zoning patterns in X_Mn, X_Ca and Fe/(Fe + Mg). Zoning reversals in Mn and Fe/(Fe + Mg) and patch distribution in Ca appear to occur around the boundaries of the textural zones. Also, the compositions of the garnet at the textural boundaries are variable for all traverses. These observations suggest that the garnet zoning was not only modified from diffusion processes, but was also influenced by pre-existing microfabrics through the effects of preferential dissolution and resorption in partial disequilibrium. Relationships between chemical and textural truncations indicate that the zoning patterns of garnet were strongly modified from preferential dissolution and precipitation during the development of successive foliations that occurred in zones of high strain/stress (cleavage seams) and zones of low strain/stress, respectively.     

Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used

Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view, this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is also important.     

Damage Survey of Water Supply Systems and Fragility Curve of PVC Water Pipelines in the Chi–Chi Taiwan Earthquake

Substantial damage to water supply systems, including water delivery pipelines, water treatment plants, reservoirs, and water storage tanks, was reported after the 1999 Chi–Chi Taiwan Earthquake. This paper first summarizes the damage survey and then presents the results of seismic fragility analysis for underground pipelines. Construction blueprints of the water delivery pipelines and repair work orders of 11 townships and cities in the disastrous area were digitized into a Geographical Information System (GIS) for analysis and assessment. With the aid of the GIS system, we found that PVC pipes made up 86% of water delivery pipelines while steel, cast iron, ductile iron, PE and others took the rest. Therefore, this paper focuses on the fragility analysis of PVC pipes. Three different methods were applied to derive the fragility relations between the PVC water pipes having nominal diameters (approximately inner diameters) greater than or equal to 65 mm and earthquake intensity parameters such as peak ground acceleration and peak ground velocity. The results were then examined with those of other countries. The discrepancy between our results and the empirical equation used by HAZUS, an earthquake loss estimation software developed by the Federal Emergency Management Agency was not significant.     

The geography of suicide terrorism in Israel

Palestinian suicide terrorism has been a key feature in the latest phase of the Israeli–Palestinian conflict. During the past decade, and particularly since September 2000, there has been a substantial increase in the use of this type of warfare. Recent studies suggest that, contrary to common belief, suicide terrorism is highly rational and driven by strategic considerations. This article explores the rationality of Palestinian suicide terrorism from a geographical perspective. It is argued that suicide terrorism works along two parallel paths: rationality and randomness. It complies with geographical fundamentals, and target selection is highly rational, subject to spatial considerations such as distance, agglomeration, and accessibility. As the permeability to Israel became more difficult, suicide bombers and their organizers had to adopt more flexible practices which emphasized other spatial considerations. Timing is of importance both for strategic and tactical reasoning. Obstructing negotiations and peace talks has been a salient objective, but the exact timing of suicide bombings has been influenced by tactical considerations, which aim at maximizing casualties.     

Deterioration of the volcanic kerb and pavement stones in a humid environment in the city centre of Izmir, Turkey

?zmir is the third largest city in Turkey and has being the centre of art, culture, tourism and trade activities throughout the 5,000 years of its history. Natural stones brought from different parts of the world have been widely used for construction of the prestigious buildings, monuments and roads etc., in the past in the city. Renovation of the street pavements and public gathering areas in the city centre has been undertaken by the Metropolitan Municipality in 2000 and continued through the year of 2001. These renovation activities have mainly been carried out in the streets running parallel to the sea shore. Volcanic rocks brought from the Central Anatolia Ankara-Gölba?? (andesites) and Kayseri-?ncesu (tuffs) have been used in the renovation works. These rocks have shown extensive deteriorations within 4 years of their usage between 2001 and 2005 under the influence of different environmental factors. In this study, the deteriorations developed in the recently placed volcanic rocks used as kerb and pavement stones in the city centre of ?zmir in the light of their mineralogical, chemical, physical and mechanical properties, used locations and the environmental factors are presented.     

福建平潭虎潮山滑坡成因机理分析与评价

虎潮山滑坡位于平宏公路12k 704~12k 884段北侧山坡体上,是平潭海岛通往陆地的唯一公路通道。论文通过定性的工程地质分析和定量计算评价了虎潮山坡体稳定性的变化趋势,提出改建公路超挖深切坡脚和持续长时间强降雨导致的孔隙水压力作用是边坡发生滑动破坏的主要因素。     

浅谈省级地震系统如何做到开发富局

作为公益性财政拨款事业单位,省级地震系统实现开发富局,应该要从稳定项目收入,拓展自营收入,培育和发展生产点,推进制度创新着手。本文试图从预算和管理的角度对其作一点简单分析。